Adsorption Removal of Environmental Hormones of Dimethyl Phthalate Using Novel Magnetic Adsorbent.

Magnetic polyvinyl alcohol adsorbent M-PVAL was employed to remove and concentrate dimethyl phthalate DMP. The M-PVAL was prepared after sequential syntheses of magnetic Fe3O4 (M) and polyvinyl acetate (M-PVAC). The saturated magnetizations of M, M-PVAC, and M-PVAL are 57.2, 26.0, and 43.2 emu g(-1) with superparamagnetism, respectively. The average size of M-PVAL by number is 0.75 µm in micro size. Adsorption experiments include three cases: (1) adjustment of initial pH (pH0) of solution to 5, (2) no adjustment of pH0 with value in 6.04-6.64, and (3) adjusted pH0 = 7. The corresponding saturated amounts of adsorption of unimolecular layer of Langmuir isotherm are 4.01, 5.21, and 4.22 mg g(-1), respectively. Values of heterogeneity factor of Freundlich isotherm are 2.59, 2.19, and 2.59 which are greater than 1, revealing the favorable adsorption of DMP/M-PVAL system. Values of adsorption activation energy per mole of Dubinin-Radushkevich isotherm are, respectively, of low values of 7.04, 6.48, and 7.19 kJ mol(-1), indicating the natural occurring of the adsorption process studied. The tiny size of adsorbent makes the adsorption take place easily while its superparamagnetism is beneficial for the separation and recovery of micro adsorbent from liquid by applying magnetic field after completion of adsorption.

Decomposition and Mineralization of Dimethyl Phthalate in an Aqueous Solution by Wet Oxidation.

Dimethyl phthalate (DMP) was treated via wet oxygen oxidation process (WOP). The decomposition efficiency η DMP of DMP and mineralization efficiency η TOC of total organic carbons were measured to evaluate the effects of operation parameters on the performance of WOP. The results revealed that reaction temperature T is the most affecting factor, with a higher T offering higher η DMP and η TOC as expected. The η DMP increases as rotating speed increases from 300 to 500 rpm with stirring enhancement of gas liquid mass transfer. However, it exhibits reduction effect at 700 rpm due to purging of dissolved oxygen by overstirring. Regarding the effects of pressure P T, a higher P T provides more oxygen for the forward reaction with DMP, while overhigh P T increases the absorption of gaseous products such as CO2 and decomposes short-chain hydrocarbon fragments back into the solution thus hindering the forward reaction. For the tested P T of 2.41 to 3.45 MPa, the results indicated that 2.41 MPa is appropriate. A longer reaction time of course gives better performance. At 500 rpm, 483 K, 2.41 MPa, and 180 min, the η DMP and η TOC are 93 and 36%, respectively.

Catalytic destruction of vinyl chloride over an alumina-supported platinum catalyst.

In this study, vinyl chloride (VC), the primary material for manufacturing polyvinyl chloride (PVC), is decomposed via catalytic oxidation (C-OX) using Pt/γ-Al2O3 catalyst. The effects of related major factors such as reaction temperature (T) and gas hourly space velocity on the conversion of VC (X) were examined. The values of T for achieving conversions of 50% and 90% are 504 and 580 K with C-OX, respectively, whereas those without Pt/γ-Al2O3 (i.e., thermal oxidation, T-OX) are 900 and 983 K, respectively, thus indicating that C-OX significantly reduces T for effective oxidation of VC to form CO2, HCl, and Cl2 when compared with T-OX. The mineralizations of carbon in VC to form CO2 are 75.5% and 38% for C-OX and T-OX, respectively, at 90% X. The conversions of chlorine atom in 1,2-dichloroenane (DCEA) to Cl in HCl and Cl2 are approximately 42% and 50.8% for C-OX and T-OX, respectively, at 90% X. These results indicate that the Pt/γ-Al2O3 catalyst exhibits remarkable performance for the mineralizations to form CO2 even though a proportion of chlorine atoms are adsorbed on the Pt surface. The Eley-Rideal model can be used to describe the experimental results, thus yielding activation energy and frequency factor values of 49.0 kJ mol(-1) and 1.77 × 10(6) s(-1), respectively. The obtained information and kinetic parameters are useful for the rational design and operation of C-OX process for the abatement of VC.

Glow discharge plasma-assisted template removal of SBA-15 at ambient temperature for high surface area, high silanol density, and enhanced CO2 adsorption capacity.

Glow discharge plasma was successfully applied for effective removal of the organic template P-123 from SBA-15 ordered mesoporous silica at near-room-temperature (below 50 °C) and in a short operation time (2 h). The as-made SBA-15 treated with glow discharge exhibited a larger surface area of 1025 m(2) g(-1) with larger pores and microspore volume as compared with that of conventional calcination (550 °C and 5 h, 827 m(2) g(-1)). In addition to less structural shrinkage, the plasma-prepared SBA-15 showed significantly increased silanol density from 5.4 to 6.6-7.6 mmol g(-1), which led directly to higher amine loading from 1.8 to 3.0 mmol g(-1). Consequently, the plasma-treated sample showed 77% more CO2 capacity and 60% higher CO2/N2 selectivity than the conventionally treated sample at 0.15 bar and 25 °C. The advantage of using glow discharge plasma for low-temperature template removal for achieving enhanced performance for CO2 adsorption is clearly demonstrated.

A review of phyto- and microbial-remediation of indoor volatile organic compounds.

Volatile organic compounds (VOCs) are crucial air pollutants in indoor environments, emitted from building materials, furniture, consumer products, cleaning products, smoking, fuel combustion, cooking, and other sources. VOCs are also emitted from human beings via breath and whole-body skin. Some VOCs cause dermal/ocular irritation as well as gastrointestinal, neurological, cardiovascular, and/or carcinogenic damage to human health. Because people spend most of their time indoors, active control of indoor VOCs has garnered attention. Phytoremediation and microbial remediation, based on plant and microorganism activities, are deemed sustainable, cost-effective, and public-friendly technologies for mitigating indoor VOCs. This study presents the major sources of VOCs in indoor environments and their compositions. Various herbaceous and woody plants used to mitigate indoor VOCs are summarized and their VOCs removal performance is compared. Moreover, this paper reviews the current state of active phytoremediation and microbial remediation for the control of indoor VOCs, and discusses future directions.

Universal masking to prevent SARS-CoV-2 transmission from Taiwan's practices.

In the fight against the COVID-19 pandemic, Taiwan, with its universal masking policy, slowed down the spread of cases and flattened its epidemic curve without enforcing lockdown or mass quarantine in 2020. This study identifies the distinguishing features of Taiwan's universal masking policy practice, such as priority, continuous improvement, multi-stakeholder partnership, transparency and accountability, and altruism and social solidarity. By confronting uncertainty through the COVID-19 crisis, this study suggests that face masking, rather than being just a physical barrier of non-pharmacological intervention, can be adopted as an interactive policy platform to empower the public for stimulating cross-sector collaboration towards social innovation and creating spillover effects, such as acts of public trust, altruism, and solidarity.

Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant.

As cobalt (Co) has been the most useful element for activating Oxone to generate SO4•-, this study aims to develop a hierarchical catalyst with nanoscale functionality and macroscale convenience by decorating nanoscale Co-based oxides on macroscale supports. Specifically, a facile protocol is proposed by utilizing Cu mesh itself as a Cu source for fabricating CuCo2O4 on Cu mesh. By changing the dosages of the Co precursor and carbamide, various nanostructures of CuCo2O4 grown on a Cu mesh can be afforded, including nanoscale needles, flowers, and sheets. Even though the Cu mesh itself can be also transformed to a Cu-Oxide mesh, the growth of CuCo2O4 on the Cu mesh significantly improves its physical, chemical, and electrochemical properties, making these CuCo2O4@Cu meshes much more superior catalysts for activating Oxone to degrade the Azo toxicant, Acid Red 27. More interestingly, the flower-like CuCo2O4@Cu mesh exhibits a higher specific surface area and more superior electrochemical performance, enabling the flower-like CuCo2O4@Cu mesh to show the highest catalytic activity for Oxone activation to degrade Acid Red 27. The flower-like CuCo2O4@Cu mesh also exhibits a much lower Ea of Acid Red 27 degradation than the reported catalysts. These results demonstrate that CuCo2O4@Cu meshes are advantageous heterogeneous catalysts for Oxone activation, and especially, the flower-like CuCo2O4@Cu mesh appears as the most effective CuCo2O4@Cu mesh to eliminate the toxic Acid Red 27.

The emissions from co-firing of biomass and torrefied biomass with coal in a chain-grate steam boiler.

In this study, biomass of rice straw (RS) and wood (WD) and their torrefied biomass (RST and WDT) were used as solid biofuel (SBF) for co-firing individually with coal in a commercial continuous chain-grate steam boiler system, which was conducted at fixed input rate of heating value of mixture of SBF and coal and at fixed airflow rate. The effects of key system parameters on the gaseous and particulate pollutions and ash were examined. These include SBF type and blending ratio (RBL) of biomass (i.e., SBF) in the mixture of coal and biomass based on heating values for co-firing.The results indicated that wood, which possesses high heating value while less amount of ash, is more suitable for co-firing with coal than rice straw. Torrefaction can increase the heating value of biomass and homogenize its property, being beneficial to co-firing. Also, torrefaction can decompose the hydroxyl group of biomass, which makes biomass tending to possess hydrophobicity. This, in turn, helps the storage and transportation of biomass. Generally, adding the RS (with RBL = 5-10%), WD (2-15%), RST (2-10%) and WDT (2-20%), respectively, with coal decreases the emissions of NOx and SO2, but increases that of CO (except RST). The emission of HCl is little. The addition of biomass also increases the emission of fine particulate matters (PM) especially PM2.5 in the flue gases, raising PM2.5/PM100 from 34.87 to 78.35 wt.% (Case 50%WDT). These emissions for the Cases tested satisfy with Taiwanese emission standards of stationary sources which set limitations of NOx, SO2, CO and HCl < 350, 300, 2000 and 80 ppmv, while PM < 50 mg/m3, respectively. The results support the use of RS, WD, RST and WDT for co-firing with coal.Implications: This study examined the suitability of using solid bio-fuels to co-fire with coal in an industrial chain-grate steam boiler system with a capacity of 100 kW, in order to achieve carbon-free emissions. Both biomass and torrefied biomass of solid bio-fuel were tested. The findings would be useful for proper design and rational operation of solid bio-fuel/coal co-firing combustion matching the appeal of sustainable material management and circular economy of biomass, and of adaptation of global warming induced by greenhouse gases. It also provides information for policy-makers to promote the co-firing application of biomass and related bio-waste materials.

Effect of calcium oxide (CaO) and sawdust on adhesion and cohesion characteristics of sewage sludge under agitated and non-agitated drying conditions.

Stickiness phenomenon is widely observed in sewage sludge drying practices. This paper is aimed at demonstrating and comparing the sticky properties of sewage sludge through non-agitated and agitated drying tests specially designed for sewage sludge. Special attentions were paid to the effects of additives, i.e. CaO, fine sawdust (FSD) and coarse sawdust (CSD), on the adhesive and cohesive characteristics of sewage sludge. The results indicated that the sticky properties of the sludge were markedly different under the different testing methods, and was also greatly influenced by CaO or sawdust addition. For instance, in the non-agitated drying tests, CaO can significantly enhance the maximum adhesive and cohesive stresses of the sludge, whereas in the agitated drying tests, the torque of agitation, which strongly correlated with the cohesive stress of the sludge, was lowered by CaO addition. During agitated drying process, sludge lump with CaO addition started to break up at higher moisture content than that of original sludge. On the other hand, sawdust also affected the sticky properties of sludge in a way that was totally different with CaO. After sawdust addition (at 5-10%WS (wet sludge basis)), the cohesive stress of the sludge was markedly increased due to strengthening of mechanical interlocking inside the sludge, whereas the adhesiveness of the sludge was lowered by sawdust addition. The influencing mechanisms of CaO and sawdust under the different testing methods were detailedly discussed in the paper.

Co-pyrolysis of sunflower-oil cake with potassium carbonate and zinc oxide using plasma torch to produce bio-fuels.

This study examined the effects of additives of potassium carbonate (K2CO3) and zinc oxide (ZnO) on the pyrolysis of waste sunflower-oil cake using a 60 kW pilot-scale plasma torch reactor. The major gaseous products were CO and H2. The productions of CO and CH4 increased while that of H2 decreased with the addition of K2CO3. The use of ZnO reduced while enhanced the formation of CO and H2, respectively. In order to match the appeal of resource reutilization, one can use the waste K2CO3 resulted from the sorption of CO2 with KOH in greenhouse gas control and the waste ZnO obtained from the melting process as additives for the co-pyrolysis of sunflower-oil cake, yielding fuels rich in CO and H2, respectively.

DC water plasma at atmospheric pressure for the treatment of aqueous phenol.

This study investigated the decomposition of aqueous phenol by direct current (DC) water plasma. The operation of DC water plasma was carried out in the absence of inert gases or air injected and cooling-controlled and pressure-controlled devices. The results indicated that 1 mol.% (52.8 g L(-1)) phenol was drastically decomposed by DC water plasma touch with energy efficiencies of 1.9 x 10(-8)-2.2 x 10(-8) mol J(-1). Also, the value of chemical oxygen demand (COD) was reduced from 100 000 mg L(-1) down to 320 mg L(-1) over a short retention time. The maximum decomposition rate of the COD was 258 mg COD min(-1) for the arc power of 0.91 kW. In the effluent analysis, H(2) (63-68%), CO (3.6-6.3%), CO(2) (25.3-28.1%) were major products in the exhaust gas and CH(4), C(2)H(2), HCOOH and C(6)H(6) in trace level. Further, HCOOH and HCHO were observed in the liquid effluents. Within the current paper, the results indicated that the DC water plasma torch is capable of an alternative green technology for phenol wastewater containing high COD.

Destruction of naphthalene via ozone-catalytic oxidation process over Pt/Al2O3 catalyst.

This study investigated the application of ozone in conjunction with Pt/Al(2)O(3) catalysts, called ozone-catalytic oxidation (OZCO) process, to destruct gaseous naphthalene (Nap). The experiments were carried out at various constant reaction temperatures (T), space velocities (SV) and inlet concentrations of ozone (C(O3,in)). The results indicate that the required T for the effective decomposition of Nap decreases with the increase in inlet concentration of ozone (C(O3,in)) at the same conversion level of Nap (X(Nap)). Further, the values of X(Nap) and mineralization extent of Nap (M(Nap)) increase linearly with the increase of C(O3,in.) Regarding the T at X(Nap)=50% (T(50)), there is about 20K reduction at SV=100,000 h(-1) for the case of OZCO process with C(O3,in) of 1750 ppmv (T(50)=460 K) compared to the process without ozone (T(50)=480 K). Further, the power law can be applied to describe the data by using the second order expression with respect to ozone and Nap concentration. The observed activation energy and frequency factor are 68.3 kJ mol(-1) and 5.36 x 10(12)L(2)mol(-1)g(-1)-cat.s(-1), respectively. The information obtained is useful for the rational design and operation of the treatment of Nap via the OZCO process.