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1.
Environ Res ; 232: 116271, 2023 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-37286124

RESUMO

In this study, an advanced oxidation process with E/Ce(IV) synergistic PMS (E/Ce(IV)/PMS) was established for the efficient removal of Reactive Blue 19 (RB19). The catalytic oxidation performance of different coupling systems was examined and the synergistic effect of E/Ce(IV) with PMS in the system was substantiated. The oxidative removal of RB19 in E/Ce(IV)/PMS was excellent, achieving a removal efficiency of 94.47% and a reasonable power consumption (EE/O value was 3.27 kWh·m-3). The effect of pH, current density, Ce(IV) concentration, PMS concentration, initial RB19 concentration and water matrix on the removal efficiency of RB19 were explored. Additionally, quenching and EPR experiments showed that the solution contains different radicals such as SO4·-, HO∙ and 1O2, where 1O2 and SO4·- played key roles, but HO∙ just acted a weaker role. Ce ion trapping experiment confirmed that Ce(IV) was involved in the reaction process and played a major role (29.91%). RB19 was subject to three possible degradation pathways, and the intermediate products displayed well biochemical properties. To conclude, the degradation mechanism of RB19 was explored and discussed. In the presence of current, E/Ce(IV)/PMS performed a rapid Ce(IV)/Ce(III) cycle, continuously generating strong catalytic oxidation Ce(IV), The reactive radicals derived from the decomposition of PMS, in conjunction with Ce(IV) and direct electro-oxidation, efficiently destroyed the molecular structure of RB19 and showed an efficient removal rate.


Assuntos
Antraquinonas , Peróxidos , Peróxidos/química , Oxirredução , Água
2.
Rev Environ Health ; 35(4): 311-321, 2020 Nov 18.
Artigo em Inglês | MEDLINE | ID: mdl-32598323

RESUMO

Indoor air pollutant is a serious problem due to its wide diversity and variability. The harmful substances from construction materials and decorative materials may make the indoor air pollution become more and more serious and cause serious health problems. In this paper, the review summarizes the advanced technologies for the removal of indoor air pollutants and the development in the treatment of indoor air pollution by catalytic oxidation technologies. Meanwhile, some catalytic oxidation mechanisms of indoor air pollutants are proposed in detail, and suggestions for the indoor air pollution treatment are also presented, in order to provide some reference for subsequent research.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar em Ambientes Fechados/prevenção & controle , Monitoramento Ambiental , Recuperação e Remediação Ambiental/métodos , Catálise , Recuperação e Remediação Ambiental/instrumentação , Oxirredução
3.
Artigo em Inglês | MEDLINE | ID: mdl-32224457

RESUMO

Existing enhancement methods are empirically expected to help the high-level end computer vision task: however, that is observed to not always be the case in practice. We focus on object or face detection in poor visibility enhancements caused by bad weathers (haze, rain) and low light conditions. To provide a more thorough examination and fair comparison, we introduce three benchmark sets collected in real-world hazy, rainy, and low-light conditions, respectively, with annotated objects/faces. We launched the UG2+ challenge Track 2 competition in IEEE CVPR 2019, aiming to evoke a comprehensive discussion and exploration about whether and how low-level vision techniques can benefit the high-level automatic visual recognition in various scenarios. To our best knowledge, this is the first and currently largest effort of its kind. Baseline results by cascading existing enhancement and detection models are reported, indicating the highly challenging nature of our new data as well as the large room for further technical innovations. Thanks to a large participation from the research community, we are able to analyze representative team solutions, striving to better identify the strengths and limitations of existing mindsets as well as the future directions.

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