Bis(di-2-pyridyl-methane-diol-κN,O,N')nickel(II) dibenzoate.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 10): m1281-2, 2010 Sep 18.
Article
em En
| MEDLINE
| ID: mdl-21587425
The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](C(7)H(5)O(2))(2), consists of an Ni(II) ion coordinated by two tridentate chelating (2-py)(2)C(OH)(2) ligands (py is pyrid-yl) and two benzoate anions. The Ni(II) ion is located on a twofold rotation axis, and its geometry is distorted octa-hedral. The gem-diol ligand (2-py)(2)C(OH)(2) adopts an η(1):η(1):η(1) coordination mode. There are O-Hâ¯O hydrogen bonds between the gem-diol ligands and benzoate anions.
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Acta Crystallogr Sect E Struct Rep Online
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2010
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Article