Inducing effect of additive agents on coordination assembly of silver(I) nitrate with 3,5-bis(2-pyridyl)-4-amino-1,2,4-triazole: supramolecular isomerism and interconversion.
Inorg Chem
; 50(19): 9284-9, 2011 Oct 03.
Article
em En
| MEDLINE
| ID: mdl-21902177
By using different organic acids as additive agents, hydrothermal reactions of AgNO(3) with 3,5-bis(2-pyridyl)-4-amino-1,2,4-triazole (2-bpt) lead to formation of two conformational polymorphs of [Ag(2-bpt)](NO(3)) with bimetallocyclic and 1-D helical coordination patterns. Interconversion between the two supramolecular isomers can be achieved under proper conditions, which will pass through the same intermediate state.
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MEDLINE
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Inorg Chem
Ano de publicação:
2011
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Article