Data on synthesis of oligomeric and polymeric poly(butylene adipate-co-butylene terephthalate) model substrates for the investigation of enzymatic hydrolysis.
Data Brief
; 7: 291-8, 2016 Jun.
Article
em En
| MEDLINE
| ID: mdl-26981550
ABSTRACT
The aliphatic-aromatic copolyester poly(butylene adipate-co-butylene terephthalate) (PBAT), also known as ecoflex, contains adipic acid, 1,4-butanediol and terephthalic acid and is proven to be compostable [1], [2], [3]). We describe here data for the synthesis and analysis of poly(butylene adipate-co-butylene terephthalate variants with different adipic acidterephatalic acid ratios and 6 oligomeric PBAT model substrates. Data for the synthesis of the following oligomeric model substrates are described mono(4-hydroxybutyl) terephthalate (BTa), bis(4-(hexanoyloxy)butyl) terephthalate (HaBTaBHa), bis(4-(decanoyloxy)butyl) terephthalate (DaBTaBDa), bis(4-(tetradecanoyloxy)butyl) terephthalate (TdaBTaBTda), bis(4-hydroxyhexyl) terephthalate (HTaH) and bis(4-(benzoyloxy)butyl) terephthalate (BaBTaBBa). Polymeric PBAT variants were synthesized with adipic acidterephatalic acid ratios of 1000, 9010, 8020, 7030, 6040 and 5050. These polymeric and oligomeric substances were used as ecoflex model substrates in enzymatic hydrolysis experiments in the article "Substrate specificities of cutinases on aliphatic-aromatic polyesters and on their model substrates" [4].
Ada, adipic acid; BTa, mono(4-hydroxybutyl) terephthalate; BTaB, bis(4-hydroxybutyl) terephthalate; Ba, benzoic acid; BaBTaBBa, bis(4-(benzoyloxy)butyl) terephthalate; Da, decanoic acid; DaBTaBDa, bis(4-(decanoyloxy)butyl) terephthalate; H, 1,6-hexanediol; HTaH, bis(4-hydroxyhexyl) terephthalate; Ha, hexanoic acid; HaBTaBHa, bis(4-(hexanoyloxy)butyl) terephthalate; Oligomer analysis; Oligomer synthesis; PBAT, (poly(butylene adipate-co-butylene terephthalate); Polyester model substrates; THF, tetrahydrofuran.; Ta, terephthalic acid; Tda, tetradecanoic acid; TdaBTaBTda, bis(4-(tetradecanoyloxy)butyl) terephthalate
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MEDLINE
Idioma:
En
Revista:
Data Brief
Ano de publicação:
2016
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Article
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Áustria