Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals.
Angew Chem Int Ed Engl
; 56(48): 15267-15273, 2017 11 27.
Article
em En
| MEDLINE
| ID: mdl-28980764
ABSTRACT
Black phosphorus intercalation compounds (BPICs) with alkali metals (namely K and Na) have been synthesized in bulk by solid-state as well as vapor-phase reactions. By means of a combination of inâ
situ X-ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2017
Tipo de documento:
Article
País de afiliação:
Alemanha