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Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals.
Abellán, Gonzalo; Neiss, Christian; Lloret, Vicent; Wild, Stefan; Chacón-Torres, Julio C; Werbach, Katharina; Fedi, Filippo; Shiozawa, Hidetsugu; Görling, Andreas; Peterlik, Herwig; Pichler, Thomas; Hauke, Frank; Hirsch, Andreas.
Afiliação
  • Abellán G; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Henkestrasse 42, 91054, Erlangen, Germany.
  • Neiss C; Lehrstuhl für Theoretische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 3, 91058, Erlangen, Germany.
  • Lloret V; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Henkestrasse 42, 91054, Erlangen, Germany.
  • Wild S; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Henkestrasse 42, 91054, Erlangen, Germany.
  • Chacón-Torres JC; Yachay Tech University, School of Physical Sciences and Nanotechnology, Urcuquí, 100119, Ecuador.
  • Werbach K; Institut für Experimental Physik, Freie Universität Berlin, Arnimallee 14, 14195, Berlin, Germany.
  • Fedi F; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Shiozawa H; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Görling A; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Peterlik H; Lehrstuhl für Theoretische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 3, 91058, Erlangen, Germany.
  • Pichler T; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Hauke F; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Hirsch A; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Henkestrasse 42, 91054, Erlangen, Germany.
Angew Chem Int Ed Engl ; 56(48): 15267-15273, 2017 11 27.
Article em En | MEDLINE | ID: mdl-28980764
ABSTRACT
Black phosphorus intercalation compounds (BPICs) with alkali metals (namely K and Na) have been synthesized in bulk by solid-state as well as vapor-phase reactions. By means of a combination of in situ X-ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Alemanha
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Alemanha