C-H and H-H activation at a di-titanium centre.
Chem Commun (Camb)
; 53(98): 13117-13120, 2017 Dec 07.
Article
em En
| MEDLINE
| ID: mdl-29083421
ABSTRACT
The reaction of the bis(pentalene)dititanium complex Ti2(µÎ·5,η5-Pn)2 (Pn = C8H4(1,4-SiiPr3)2) with the N-heterocyclic carbene 1,3,4,5-tetramethylimidazol-2-ylidene results in intramolecular C-H activation of one of the iPr methyl groups of a Pn ligand and formation of a "tucked-in" bridging hydride complex. The "tuck-in" process is reversed by the addition of hydrogen, which yields a dihydride featuring terminal and bridging hydrides.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2017
Tipo de documento:
Article
País de afiliação:
Reino Unido