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Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus.
Wild, Stefan; Fickert, Michael; Mitrovic, Aleksandra; Lloret, Vicent; Neiss, Christian; Vidal-Moya, José Alejandro; Rivero-Crespo, Miguel Ángel; Leyva-Pérez, Antonio; Werbach, Katharina; Peterlik, Herwig; Grabau, Mathias; Wittkämper, Haiko; Papp, Christian; Steinrück, Hans-Peter; Pichler, Thomas; Görling, Andreas; Hauke, Frank; Abellán, Gonzalo; Hirsch, Andreas.
Afiliação
  • Wild S; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.
  • Fickert M; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.
  • Mitrovic A; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.
  • Lloret V; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.
  • Neiss C; Lehrstuhl für Theoretische Chemie and Interdisciplinary Center of Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 3, 91058, Erlangen, Germany.
  • Vidal-Moya JA; Instituto de Tecnología Química, Universidad Politécnica de Valencia-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022, Valencia, Spain.
  • Rivero-Crespo MÁ; Instituto de Tecnología Química, Universidad Politécnica de Valencia-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022, Valencia, Spain.
  • Leyva-Pérez A; Instituto de Tecnología Química, Universidad Politécnica de Valencia-Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos s/n, 46022, Valencia, Spain.
  • Werbach K; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Peterlik H; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Grabau M; Lehrstuhl für Physikalische Chemie II, FAU, Egerlandstraße 3, 91058, Erlangen, Germany.
  • Wittkämper H; Lehrstuhl für Physikalische Chemie II, FAU, Egerlandstraße 3, 91058, Erlangen, Germany.
  • Papp C; Lehrstuhl für Physikalische Chemie II, FAU, Egerlandstraße 3, 91058, Erlangen, Germany.
  • Steinrück HP; Lehrstuhl für Physikalische Chemie II, FAU, Egerlandstraße 3, 91058, Erlangen, Germany.
  • Pichler T; Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090, Vienna, Austria.
  • Görling A; Lehrstuhl für Theoretische Chemie and Interdisciplinary Center of Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 3, 91058, Erlangen, Germany.
  • Hauke F; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.
  • Abellán G; Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.
  • Hirsch A; Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Catedrático José Beltrán 2, 46980, Paterna, Valencia, Spain.
Angew Chem Int Ed Engl ; 58(17): 5763-5768, 2019 Apr 16.
Article em En | MEDLINE | ID: mdl-30675972
ABSTRACT
The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Alemanha
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Alemanha