Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus.
Angew Chem Int Ed Engl
; 58(17): 5763-5768, 2019 Apr 16.
Article
em En
| MEDLINE
| ID: mdl-30675972
ABSTRACT
The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
Alemanha