Generation and Reactivity of a One-Electron-Oxidized Manganese(V) Imido Complex with a Tetraamido Macrocyclic Ligand.
Chemistry
; 25(56): 12895-12899, 2019 Oct 08.
Article
em En
| MEDLINE
| ID: mdl-31325369
ABSTRACT
The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV (TAML)(N-Mes)]- (1), are reported. Compound 1 is oxidized by [(p-BrC6 H4 )3 N]+. [SbCl6 ]- and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions.
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1
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemistry
Assunto da revista:
QUIMICA
Ano de publicação:
2019
Tipo de documento:
Article