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Synthesis and Viscosimetric Behavior of Poly(acrylamide-co-2-acrylamido-2-methylpropanesulfonate) Obtained by Conventional and Adiabatic Gel Process via RAFT/MADIX Polymerization.
Mejia, Aurora; Rodriguez, Laurent; Schmitt, Charlène; Andreu, Nathalie; Favéro, Cedrick; Braun, Olivier; Dupuis, Guillaume; Deniau, Elise; Reynaud, Stéphanie; Grassl, Bruno.
Afiliação
  • Mejia A; CNRS/UNIV PAU & PAYS ADOUR/E2S UPPA, Institut des sciences analytiques et de physicochimie pour l'environnement et les matériaux (IPREM), UMR 5254, 64000 Pau, France.
  • Rodriguez L; CNRS/UNIV PAU & PAYS ADOUR/E2S UPPA, Institut des sciences analytiques et de physicochimie pour l'environnement et les matériaux (IPREM), UMR 5254, 64000 Pau, France.
  • Schmitt C; SNF S.A.S., ZAC de Milieux, 42163 Andrézieux Cedex, France.
  • Andreu N; CNRS/UNIV PAU & PAYS ADOUR/E2S UPPA, Institut des sciences analytiques et de physicochimie pour l'environnement et les matériaux (IPREM), UMR 5254, 64000 Pau, France.
  • Favéro C; CNRS/UNIV PAU & PAYS ADOUR/E2S UPPA, Institut des sciences analytiques et de physicochimie pour l'environnement et les matériaux (IPREM), UMR 5254, 64000 Pau, France.
  • Braun O; SNF S.A.S., ZAC de Milieux, 42163 Andrézieux Cedex, France.
  • Dupuis G; SNF S.A.S., ZAC de Milieux, 42163 Andrézieux Cedex, France.
  • Deniau E; SNF S.A.S., ZAC de Milieux, 42163 Andrézieux Cedex, France.
  • Reynaud S; Poweltec, ZAC RUEIL 2000, 3 Rue Paul Heroult, 92500 Rueil Malmaison, France.
  • Grassl B; CNRS/UNIV PAU & PAYS ADOUR/E2S UPPA, Institut des sciences analytiques et de physicochimie pour l'environnement et les matériaux (IPREM), UMR 5254, 64000 Pau, France.
ACS Omega ; 4(6): 11119-11125, 2019 Jun 30.
Article em En | MEDLINE | ID: mdl-31460210
ABSTRACT
High molar masses homopolymers of both acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonate (AMPS) as well as poly(AM-stat-AMPS) exhibiting a large range copolymer composition has been obtained via the optimization of a purely adiabatic gel process. Monomer concentrations ranging from 2.0 to 3.47 M have been successfully tested while keeping the control of the molar masses up to 5 × 106 g mol-1. The products have been characterized in terms of molecular mass and viscosimetric properties.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: ACS Omega Ano de publicação: 2019 Tipo de documento: Article País de afiliação: França

Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: ACS Omega Ano de publicação: 2019 Tipo de documento: Article País de afiliação: França