Mechanistic Studies on the Insertion of Carbonyl Substrates into Cu-H: Different Rate-Limiting Steps as a Function of Electrophilicity.

Tran, Ba L; Neisen, Benjamin D; Speelman, Amy L; Gunasekara, Thilina; Wiedner, Eric S; Bullock, R Morris

Tran, Ba L; Neisen, Benjamin D; Speelman, Amy L; Gunasekara, Thilina; Wiedner, Eric S; Bullock, R Morris.

Afiliação

Tran BL; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
Neisen BD; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
Speelman AL; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
Gunasekara T; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
Wiedner ES; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.
Bullock RM; Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.

Angew Chem Int Ed Engl ; 59(22): 8645-8653, 2020 May 25.

Article em En | MEDLINE | ID: mdl-32022415

Palavras-chave

Cu hydride; Cu-H hydride transfer; Cu-H monomerization; Cu-hemiaminalate; carbonyls

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Estados Unidos

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