A <i>cis</i>-ß-iron(III) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings.

Ricca, Michael; Yao, Shaolei; Le, Tommy; White, Jonathan M; Donnelly, Paul S; Rizzacasa, Mark A

A cis-ß-iron(III) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings.

Ricca, Michael; Yao, Shaolei; Le, Tommy; White, Jonathan M; Donnelly, Paul S; Rizzacasa, Mark A.

Afiliação

Ricca M; School of Chemistry, The Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Victoria, 3010, Australia. masr@unimelb.edu.au.
Yao S; School of Chemistry, The Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Victoria, 3010, Australia. masr@unimelb.edu.au.
Le T; School of Chemistry, The Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Victoria, 3010, Australia. masr@unimelb.edu.au.
White JM; School of Chemistry, The Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Victoria, 3010, Australia. masr@unimelb.edu.au.
Donnelly PS; School of Chemistry, The Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Victoria, 3010, Australia. masr@unimelb.edu.au.
Rizzacasa MA; School of Chemistry, The Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Victoria, 3010, Australia. masr@unimelb.edu.au.

Org Biomol Chem ; 21(33): 6789-6793, 2023 Aug 23.

Article em En | MEDLINE | ID: mdl-37566401

ABSTRACT

ABSTRACT

An inexpensive Fe(III) SALPN catalyst for MHAT reactions such as reductions of α,ß-unsaturated carbonyl compounds and olefin cross couplings is reported. The majority of these reactions proceeded in good yields and high stereoselectivities with low catalyst loadings at room temperature.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Austrália

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