Dual-Valence Characteristics of Be11: Tin/Lead-like Superatom.

ABSTRACT

To enhance the superatom family, the new superatom analogue Be11 of group IVA elements has been developed. Be11 can exhibit multiple valence states (+2 and +4), similar to carbon-group elements, and is capable of forming stable ionic compounds with other atoms such as carbon, chalcogen, (super)halogen, and hydroxyl. This resembles how tin and lead atoms combine with these elements to form stable molecules. Their special stability can be rationalized from the perspective of a cluster shell model. Sn or Pb could be the nearest atomic analogue to Be11 in group IVA, as the +2 oxidation state is more stable than the +4 oxidation state. This comparative investigation highlights the resemblance between Be11 and carbon-group elements, which encourages additional exploration within the superatom family.