Interfacial Charge Transfer in Photoexcited QD-Molecule Composite of Tetrahedral CdSe Quantum Dot Coupled with Carbazole.
ACS Appl Mater Interfaces
; 16(24): 31045-31055, 2024 Jun 19.
Article
em En
| MEDLINE
| ID: mdl-38857441
ABSTRACT
Photoexcited charge transfer dynamics in CdSe quantum dots (QDs) coupled with carbazole were explored to model QD-molecule systems for light-harvesting applications. The absorption spectra of QDs with different sizes, i.e., Cd35Se20X30L30 (T1), Cd56Se35X42L42 (T2), and Cd84Se56X56L56 (T3) were simulated with quantum dynamical methods, which qualitatively match the reported experimental spectra. The carbazole is attached with a 3-amino group at the apex position of T1 (namely T1-3A-Cz), establishing proper electronic communication between T1 and carbazole. The spectra of T1-3A-Cz is 0.22 eV red-shifted compared to T1. A time-dependent perturbation was applied in tune with the lowest energy peak (3.63 eV) of T1-3A-Cz to investigate the charge transfer dynamics, which revealed an ultrafast charge separation within the femtosecond time scale. The electronic structure showed a favorable energy alignment between T1 and carbazole in T1-3A-Cz. The LUMO of carbazole was situated below the conduction band of the QD, while the HOMO of carbazole mixed perfectly with the top of the valence band of the QD, developing the interfacial charge transfer states. These states promoted the photoexcited electron transfer directly from the CdSe core to carbazole. A rapid and enhanced charge separation occurred with the laser field strength increasing from 0.001 to 0.005 V/Å. However, T1 connected to the other positions of carbazole did not show charge separation effectively. The photoinduced charge transfer is negligible in the case of T2-carbazole systems due to poor electronic coupling, and it is not observed in T3-carbazole systems. So, the T1-3A-Cz model acts as a perfect donor-acceptor QD-molecule nanocomposite that can harvest photon energy efficiently. Further enhancement of charge transfer can be achieved by coupling more carbazoles to the T1 QD (e.g., T1-3A-Cz2) due to the extension of hole delocalization between T1 and the carbazoles.
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Base de dados:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Assunto da revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Índia