Analysis of the Inhomogeneous Growth of Sputtered Black TiO2 Thin Films.

Black titanium dioxide (B-TiO2) is a highly active photoelectrochemical material compared to pure titanium dioxide due to its increased light absorption properties. Recently, we presented the deposition of thin-film B-TiO2 using an asymmetric bipolar reactive magnetron sputter process. The resulting samples exhibit excellent photoelectrochemical properties, which can be fine-tuned by varying the process parameters. In this article, results of morphological, electrical, and photoelectrochemical measurements are discussed to better understand the surprisingly high electrochemical activity of the films. In order to study the influence of the dynamic process on film formation, we use static sputtering with a fixed substrate covering the entire chamber area in front of the two targets. This allows the material composition of the sputtered film to be analyzed depending on its relative position to the targets. The results lead to the conclusion that the asymmetric bipolar sputtering mainly produces two phases, a transparent, nonconductive crystalline phase and a black, conductive amorphous phase. As a consequence, the dynamically sputtered samples are multilayers of these two materials. We discuss that the significantly better electrical and photoelectrochemical properties emerge from the inhomogeneous nature of the laminates, like also found in core-shell nanoparticles of B-TiO2.

Efficient Thin Polymer Coating as a Selective Thermal Emitter for Passive Daytime Radiative Cooling.

Radiative cooling to subambient temperatures can be efficiently achieved through spectrally selective emission, which until now has only been realized by using complex nanoengineered structures. Here, a simple dip-coated planar polymer emitter derived from polysilazane, which exhibits strong selective emissivity in the atmospheric transparency window of 8-13 µm, is demonstrated. The 5 µm thin silicon oxycarbonitride coating has an emissivity of 0.86 in this spectral range because of alignment of the frequencies of bond vibrations arising from the polymer. Furthermore, atmospheric heat absorption is suppressed due to its low emissivity outside the atmospheric transparency window. The reported structure with the highly transparent polymer and underlying silver mirror reflects 97% of the incoming solar irradiation. A temperature reduction of 6.8 °C below ambient temperature was achieved by the structure under direct sunlight, yielding a cooling power of 93.7 W m-2. The structural simplicity, durability, easy applicability, and high selectivity make polysilazane a unique emitter for efficient prospective passive daytime radiative cooling structures.

Improved Metal Oxide Electrode for CIGS Solar Cells: The Application of an AgOX Wetting Layer.

Oxide/metal/oxide (OMO) layer stacks are used to replace transparent conductive oxides as front contact of thin-film solar cells. These multilayer structures not only reduce the overall thickness of the contact, but can be used for colouring of the cells utilizing interference effects. However, sheet resistance and parasitic absorption, both of which depend heavily on the metal layer, should be further reduced to reach higher efficiencies in the solar cells. In this publication, AgOX wetting layers were applied to OMO electrodes to improve the performance of Cu(In,Ga)Se2 (CIGS) thin-film solar cells. We show that an AgOX wetting layer is an effective measure to increase transmission and conductivity of the multilayer electrode. With the presented approach, we were able to improve the short-circuit current density by 18% from 28.8 to 33.9 mA/cm2 with a metal (Ag) film thickness as low as 6 nm. Our results highlight that OMO electrodes can be an effective replacement for conventional transparent conductive oxides like aluminium-doped zinc oxide on thin-film solar cells.

Time delay effects in the control of synchronous electricity grids.

The expansion of inverter-connected generation facilities (i.e., wind and photovoltaics) and the removal of conventional power plants is necessary to mitigate the impacts of climate change, whereas conventional generation with large rotating generator masses provides stabilizing inertia, inverter-connected generation does not. Since the underlying power system and the control mechanisms that keep it close to a desired reference state were not designed for such a low inertia system, this might make the system vulnerable to disturbances. In this paper, we will investigate whether the currently used control mechanisms are able to keep a low inertia system stable and how this is affected by the time delay between a frequency deviation and the onset of the control action. We integrate the control mechanisms used in Continental Europe into a model of coupled oscillators which resembles the second order Kuramoto model. This model is then used to investigate how the interplay of changing inertia, network topology, and delayed control affects the stability of the interconnected power system. To identify regions in the parameter space that make stable grid operation possible, the linearized system is analyzed to create the system's stability chart. We show that lower and distributed inertia could have a beneficial effect on the stability of the desired synchronous state.

Electrolyte Imbalance Determination of a Vanadium Redox Flow Battery by Potential-Step Analysis of the Initial Charging.

Vanadium redox flow batteries (VRFB) suffer from capacity fades owing to side reactions and crossover effects through the membrane. These processes lead to a deviation of the optimal initial average oxidation state (AOS=+3.5) of vanadium species in both half-cell electrolytes. To rebalance the electrolyte solutions, it is first necessary to determine the current AOS. In this study, a new method was developed that enables an accurate determination of the AOS. A potential-step analysis was performed with mixed electrolyte solutions of both half-cells during the initial charging. The potential was recorded with a simple open-circuit voltage (OCV) cell, and the potential-steps were analyzed. A correlation between the duration of the potential plateaus in the OCV and the amount of vanadium ions of a certain oxidation state in the half-cell electrolytes was found and used to precisely determine the AOS with a maximum error of 3.6 %.

A vapor-phase-assisted growth route for large-scale uniform deposition of MoS2 monolayer films.

In this work a vapor-phase-assisted approach for the synthesis of monolayer MoS2 is demonstrated, based on the sulfurization of thin MoO3-x precursor films in an H2S atmosphere. We discuss the co-existence of various possible growth mechanisms, involving solid-gas and vapor-gas reactions. Different sequences were applied in order to control the growth mechanism and to obtain monolayer films. These variations include the sample temperature and a time delay for the injection of H2S into the reaction chamber. The optimized combination allows for tuning the process route towards the potentially more favorable vapor-gas reactions, leading to an improved material distribution on the substrate surface. Raman and photoluminescence (PL) spectroscopy confirm the formation of ultrathin MoS2 films on SiO2/Si substrates with a narrow thickness distribution in the monolayer range on length scales of a few millimeters. Best results are achieved in a temperature range of 950-1000 °C showing improved uniformity in terms of Raman and PL line shapes. The obtained films exhibit a PL yield similar to mechanically exfoliated monolayer flakes, demonstrating the high optical quality of the prepared layers.

Laser perforated ultrathin metal films for transparent electrode applications.

Transmittance and conductivity are the key requirements for transparent electrodes. Many optoelectronic applications require additional features such as mechanical flexibility and cost-efficient fabrication at low temperatures. Here we demonstrate a simple method to fabricate high performance transparent electrodes that is based on perforation of thin silver layers using picosecond laser pulses. Transparent electrodes have been characterized optically and electrically in order to determine the influence of specific surface coverage. Special attention was paid to maintaining sufficient conductivity in the metal-free areas. As a result, transmittance of a much higher bandwidth was achieved as compared to unpatterned metal films. Transparent electrodes have been fabricated on glass and plastic foil, as well as wafer-based silicon heterojunction solar cells, demonstrating their applicability for most relevant cases.

Comparison of Ag and SiO2 Nanoparticles for Light Trapping Applications in Silicon Thin Film Solar Cells.

Plasmonic and photonic light trapping structures can significantly improve the efficiency of solar cells. This work presents an experimental and computational comparison of identically shaped metallic (Ag) and nonmetallic (SiO2) nanoparticles integrated to the back contact of amorphous silicon solar cells. Our results show comparable performance for both samples, suggesting that minor influence arises from the nanoparticle material. Particularly, no additional beneficial effect of the plasmonic features due to metallic nanoparticles could be observed.