Adsorption mechanisms on perfluorooctanoic acid by FeCl3 modified granular activated carbon in aqueous solutions.

Perfluorooctanoic acid (PFOA) is an emerging organic pollutant that is persistent in the environmental, and has been detected in humans, and wildlife. Several technologies, such as activated carbon (AC) adsorption have been used to remove PFOA from water. In this study, Fe-impregnation with/without post-thermal treatment of AC was applied to improve the adsorption of PFOA. The adsorption mechanisms were evaluated using three kinetic models: pseudo-first-order model, pseudo-second-order model, and intra-particle diffusion models. Interpretation of experimental results with the kinetic models revealed that chemical interactions, such as electrostatic attraction or complexation were suggested as the adsorption mechanisms along with physical adsorption. Two isotherm models demonstrated that the modified ACs (171.0-189.9 mg g-1) had increases in adsorption capacities than the unmodified AC (164.9 mg g-1), which indicated that modification improved the maximum achievable surface concentrations and adsorption affinity to some extent. The evenly distributed iron content on the modified ACs was visualized using an energy dispersive X-ray spectroscopy. The Fe-impregnated AC showed a reduction in the specific surface area and total pore volume; however, post-thermal treatment largely recovered the pore structures. The isotherms normalized by the accessible surface area revealed the importance of the Fe-impregnated surfaces on PFOA adsorption. Comparable pH values of the point of zero charge and chemical compositions of the ACs implied that an increase in Fe-impregnated surface was crucial to improve PFOA adsorption. Thus, substantial enhancement of PFOA removal can be achieved by implementing a proper strategy for AC modification, especially using Fe-impregnation.

Disinfection by-product formation potential of algogenic organic matter from Microcystis aeruginosa: Effects of growth phases and powdered activated carbon adsorption.

Algae can exhibit different disinfection by-product formation potential (DBPFP) depending on the characteristics of the algogenic organic matter (AOM) released during growth. In this study, the amount of AOM released by Microcystis aeruginosa and its DBPFP were compared between the exponential growth phase and the death phase. Moreover, the efficiency of DBPFP removal through powdered activated carbon (PAC) adsorption was evaluated. The correlations between DBPFPs and dissolved organic carbon concentration or ultraviolet absorbance at 254 nm (UV254) were also investigated to predict DBPFPs. Among DBPFPs, which were higher at the death phase, the formation potential (FP) of haloacetic acid was the highest. In addition, the high relative haloacetonitrile FP at the death phase indicated that a relevant portion of the intracellular organic matter derived from cell autolysis was converted into a large amount of haloacetonitriles. Furthermore, PAC addition reduced all DBPFPs at both growth phases. PAC was found to selectively adsorb dichloroacetic acid precursors at the death phase and dichloroacetonitrile precursors at both growth phases. Finally, UV254 showed greater correlations with the three DBPFPs at all growth phases. These results highlight the possible use of UV254 as an alternative analytical tool for fast determination of M. aeruginosa DBPFPs.