Synthesis, characterization and adsorption optimization of bimetallic La-Zn metal organic framework for removal of 2,4-dichlorophenylacetic acid.

To eliminate the hazardous pesticide 2,4-dichlorophenylacetic acid (2,4-D) through aqueous solutions, stacked nanorods known as hetero bimetallic organic frameworks (MOFs) of 2-methyl imidazole based on lanthanum and zinc are created. The research's convincing discoveries displayed that La/Zn-MOF is an actual adsorbent for the removal of 2,4-D through aqueous solutions. The La/Zn-MOF was investigated using a variability of techniques, with scanning electron microscope (SEM), powered X-ray diffraction (PXRD), and Brunauer-Emmett-Teller (BET) investigation. La/Zn-MOF has a significant pore capacity of 1.04 cm³/g and a comparatively large surface area of 897.69 m2/g. Our findings, which are quite intriguing, demonstrate that adsorption behavior is pointedly wedged by variations in pH. A pH 6 dose of 0.02 g was shown to be the optimal setting for the greatest capacity for adsorption. Because adsorption is an endothermic process, temperature variations affect its capability. The adsorption method was fit both isothermally and kinetically using the Langmuir isotherm classical. It was created that the entire process made use of a chemisorption mechanism. Solution pH, temperature, adsorbent dosage, and time were all improved using the Box-Behnken design (BBD) and Response Surface Methodology (RSM). We were able to accurately calculate the values of ΔHo, ΔSo, and ΔGo for 2,4-D by following the guidelines. These results demonstrated the spontaneous and endothermic character of the adsorption procedure employing La/Zn-MOF as an adsorbent. Adsorption-desorption cycles can be carried out up to five times. With the synthesized La/Zn-MOF adsorbent due to its exceptional reusability. Many processes, such π-π interaction, pore filling, H-bonding, or electrostatic contact, were postulated to explain the connection between La/Zn-MOF and 2,4-D after extra research to appreciate well the link was conducted. This is the first study to demonstrate the effectiveness of utilizing La/Zn-MOF as an adsorbent to eliminate 2,4-D from wastewater models. The results display that a pH of 6 is required to achieve the maximal 2,4-D adsorption capability on La/Zn-MOF, which is 307.5 mg/g.

Optical and electronic properties of MgPc-Ch-diisoQ blend organic thin film as an active layer for photovoltaic cells.

Organic photovoltaic cells are a promising technology for generating renewable energy from sunlight. These cells are made from organic materials, such as polymers or small molecules, and can be lightweight, flexible, and low-cost. Here, we have created a novel mixture of magnesium phthalocyanine (MgPc) and chlorophenyl ethyl diisoquinoline (Ch-diisoQ). A coating unit has been utilized in preparing MgPc, Ch-diisoQ, and MgPc-Ch-diisoQ films onto to FTO substrate. The MgPc-Ch-diisoQ film has a spherical and homogeneous surface morphology with a grain size of 15.9 nm. The optical absorption of the MgPc-Ch-diisoQ film was measured, and three distinct bands were observed at 800-600 nm, 600-400 nm, and 400-250 nm, with a band gap energy of 1.58 eV. The current density-voltage and capacitance-voltage measurements were performed to analyze the photoelectric properties of the three tested cells. The forward current density obtained from our investigated blend cell is more significant than that for each material by about 22%. The photovoltaic parameters (Voc, Isc, and FF) of the MgPc-Ch-diisoQ cell were found to be 0.45 V, 2.12 µA, and 0.4, respectively. We believe that our investigated MgPc-Ch-diisoQ film will be a promising active layer in organic solar cells.

Biomass and domestic waste: a potential resource combination for bioenergy generation and water treatment via benthic microbial fuel cell.

The benthic microbial fuel cell (BMFC) is one of the most efficient types of bioelectrochemical fuel cell systems. Modern bioelectrochemical fuel cells have several drawbacks, including an unstable organic substrate and a microorganism-unfriendly atmosphere. The recent literature to encounter such issues is one of the emerging talks. Researchers are focusing on the utilization of biomass and waste to encounter such challenges and make the technique more feasible at the pilot scale. This study investigated the combination of local bakery waste as an organic substrate with lignocellulosic biomass material. The whole experiment was conducted for 45 days. At an external resistance of 1000 ῼ and an internal resistance of 677 ῼ, the power density was found to be 3.51 mW/m2. Similarly, for Pb2+, Cd2+, Cr3+, Ni2+, and Co2+, the degradation efficiency was 84.40%, 81.21%, 80%, 89.50%, and 86.0%, respectively. The bacterial identification results showed that Liquorilactobacillus nagelii, Proteus mirabilis, Pectobacterium punjabense, and Xenorhabdus thuongxuanensis are the most prominent species found on anode biofilm. The method of electron generation in this study, which includes the degradation of metal ions, is also well described. Lastly, optimising the parameters showed that pH 7 provides a feasible environment for operation. A few future suggestions for practical steps are enclosed for the research community.

Novel Copper Oxide-Integrated Carbon Paste Tirofiban Voltammetric Sensor.

The present study introduced the construction and electroanalytical characterization of novel tirofiban (TIR) carbon paste voltammetric sensors integrated with copper oxide nanoparticles. The copper oxide nanostructure remarkably enhanced the oxidation of TIR molecules on the electrode surface with an irreversible anodic oxidation peak at about 1.18 V. The peak current values of the recorded differential pulse voltammograms were correlated to the TIR concentrations within a defined linear range from 0.060 to 7.41 µg mL-1 with an LOD value of 20.7 ng mL-1. Based on the electrochemical behavior of TIR at different scan rates and with the aid of the molecular orbital calculations performed on the TIR molecule, the electro-oxidation reaction was postulated to undergo through the oxidation of the five-membered-ring nitrogen atom with the transfer of one electron and one proton. Based on the reported selectivity and sensitivity of the proposed method, TIR was successfully determined in Aggrastat intravenous infusion and biological samples with mean average recoveries agreeable with the UV spectrophotometric method.

Kinetics, isotherms, and mechanism of removing cationic and anionic dyes from aqueous solutions using chitosan/magnetite/silver nanoparticles.

Modified magnetite chitosan with silver nanoparticles was synthesized and tested for removing cationic and anionic dyes in aqueous solutions. Initial dye concentration, pH, and contact time were examined. Results showed that pH (4.0) was optimal for removing anionic dyes (methyl orange) and pH 8.0 for removing cationic dyes (methylene blue). According to these results, zeta potentials were found to be 8.43 and - 39.17 mV at pH 4.0 and 8.0, respectively. So, it is attracted to positively charged cationic dyes in an alkaline medium and negatively charged anionic dyes in an acidic medium because of their opposite charges. Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), thermal gravimetric analysis (TGA), and zeta potential measurements were used to characterize the synthesized nanosorbents. A pseudo-second-order kinetic model is fitted with the Langmuir adsorption model, with an adsorption capacity of 417 and 476 mg/g for methyl orange and methylene blue, respectively. For both dyes, modified magnetite chitosan with silver nanoparticles showed high regeneration capability and recovery for up to four cycles without adsorption efficiency loss. Furthermore, modified magnetite chitosan with silver nanoparticles, as prepared in the present study, was demonstrated to be an effective adsorbent for organic pollutants in wastewater.

Quantum chemical modification of indaceno dithiophene-based small acceptor molecules with enhanced photovoltaic aspects for highly efficient organic solar cells.

In this computational work, with the aim of boosting the ultimate efficiency of organic photovoltaic cells, seven small acceptors (IDST1-IDST7) were proposed by altering the terminal-acceptors of reference molecule IDSTR. The optoelectronic characteristics of the IDSTR and IDST1-IDST7 molecules were investigated using the MPW1PW91/6-31G(d,p) level of theory, and solvent-state computations were examined using time-dependent density functional theory (TD-DFT) simulation. Nearly all the investigated photovoltaic aspects of the newly proposed molecules were found to be better than those of the IDSTR molecule e.g. in comparison to IDSTR, IDST1-IDST7 exhibit a narrower bandgap (E gap), lower first excitation energy (E x), and a significant red-shift in the absorbance maxima (λ max). According to the findings, IDST3 has the lowest E x (1.61 eV), the greatest λ max (770 nm), and the shortest E gap (2.09 eV). IDST1-IDST7 molecules have higher electron mobility because their RE of electrons is less than that of IDSTR. Hole mobility of IDST2-IDST7 is higher than that of the reference owing to their lower RE for hole mobility than IDSTR. By coupling with the PTB7-Th donor, the open circuit voltage (V OC) of the investigated acceptor molecules (IDSTR and IDST1-IDST7) was calculated and investigation revealed that IDST4-IDST6 molecules showed higher V OC and fill factor (FF) values than IDSTR molecules. Accordingly, the modified molecules can be seriously evaluated for actual use in the fabrication of OSCs with enhanced photovoltaic and optoelectronic characteristics in light of the findings of this study.

Synthesis and Self-assembly of Novel Nanofeather-like Fluorescent Alkyloxy-Containing Diphenyl Ether Organogelators.

In this study, novel fluorescent low molecular-weight organogelators are derived from diphenyl ethers and substituted with para-alkoxy groups of different aliphatic chain lengths. The present research promotes the preparation of innovative nanofeather-like assemblies from the synthesized diphenyl ether-derived organogelators. The gelation performance of the prepared alkoxy-substituted diphenyl ethers was reported. The synthesis procedure was achieved by using a base-catalyzed reaction of hydroxyl-substituted diphenyl with various alcohols of different aliphatic chain lengths. The chemical structures of the synthesized diphenyl ether derivatives were studied by 1H/13C NMR and infrared spectroscopy. Fluorescence and UV-vis absorption spectral analyses showed solvatochromism. The diphenyl ether derivatives with longer alkoxy terminal substituents showed enhanced thermoreversible gelation activity as compared to the diphenyl ether derivatives with shorter alkoxy terminal substituents. The morphological properties of the self-assembled diphenyl ethers were studied by transmission electron microscopy and scanning electron microscopy, which showed supramolecular architectures of highly ordered nanofeathers, enforced by van der Waals interactions and π-stacks. Depending on the length of the aliphatic tail, different morphologies were detected, including nanofeathers, nanofibers, and nanosheets. The antimicrobial and cytotoxic properties of the prepared diphenyl ether-derived organogelators were examined to confirm their possible use in various fields like drug delivery systems.

Optical properties of novel luminescent nacre-like epoxy/graphene nanocomposite coating integrated with lanthanide-activated aluminate nanoparticles.

Nacre structure has aragonite polygonal tablets, tessellated to generate separate layers, and exhibits adjacent layers and tablets within a layer bonded by a biopolymer. Here, we report the development of a nacre-like organic/inorganic hybrid nanocomposite coating consisting of epoxy tablets as well as rare-earth-activated aluminate and graphene oxide tablet/tablet interfaces. The lanthanide-activated aluminate was prepared using a high temperature solid-state approach followed by top-down technology to provide the phosphor nanoparticles (PNPs). Graphene oxide nanosheets were prepared from graphite. The prepared epoxy/graphene/phosphor nanocomposites were applied onto mild steel. Covalent bonds were formed between epoxy polymer chains resin and the graphene oxide nanosheets. These interface interactions resulted in a tough surface, high tensile strength, and excellent durability. The use of phosphor in the nanoparticle form guaranteed that no agglomerations were produced throughout the hardening procedure by allowing better distribution of PNPs in the nacre-like matrix. The generated nacre-like substrates displayed reversible fluorescence. The excitation of the white coloured nacre-like coats at 367 nm resulted in a green emission band at 518 nm as designated by the Commission Internationale de l'éclairage (CIE) Laboratory and photoluminescence spectra. Various analysis methods were utilized to inspect the surface structure and elemental composition of the nacre-like coats. An improved hydrophobicity and mechanical characteristics were detected when increasing the phosphor concentration. Due to the astonishing characteristics of the prepared nacre-like composite paint, both ceramics and metals can benefit from the current simple strategy.

Optical Detection of Acetone Using "Turn-Off" Fluorescent Rice Straw Based Cellulose Carbon Dots Imprinted onto Paper Dipstick for Diabetes Monitoring.

Persistent bad breath has been reported as a sign of serious diabetes health conditions. If an individual's breath has a strong odor of acetone, it may indicate high levels of ketones in the blood owing to diabetic ketoacidosis. Thus, acetone gas in the breath of patients with diabetes can be detected using the current easy-to-use fluorescent test dipstick. In another vein, rice straw waste is the most well-known solid pollutant worldwide. Thus, finding a simple technique to change rice straw into a valuable material is highly important. A straightforward and environmentally friendly approach for reprocessing rice straw as a starting material for the creation of fluorescent nitrogen-doped carbon dots (NCDs) has been established. The preparation process of NCDs was carried out via one-pot hydrothermal carbonization using NH4OH as a passivation substance. A testing strip was developed on the basis of cellulose CD nanoparticles (NPs) immobilized onto cellulose paper assay. The NCDs demonstrated a quantum yield of 23.76%. A fluorescence wavelength was detected at 443 nm upon applying an excitation wavelength of 354 nm. NCDs demonstrated remarkable selectivity for acetone gas as their fluorescence was definitely exposed to quenching by acetone as a consequence of the inner filter effect. A linear correlation was observed across the concentration range of 0.5-150 mM. To detect and measure acetone gas, the present cellulose paper strip has a "switch off" fluorescent signal. A readout limit was accomplished for an aqueous solution of acetone as low as 0.5 mM under ambient conditions. The chromogenic fluorescence of the cellulose assay responsiveness depends on the fluorescence quenching characteristic of the cellulose carbon dots in acetone. A thin fluorescent cellulose carbon dot layer was deposited onto the surface of cellulose strips by a simple impregnation process. CDs were made using NP morphology and analyzed using infrared spectroscopy and transmission electron microscopy. The carbon dot distribution on the paper strip was evaluated by scanning electron microscope and energy-dispersive X-ray analysis. The absorption and fluorescence spectral analyses were investigated. The paper sheets' mechanical qualities were also examined.

Development of photoluminescent artificial nacre-like nanocomposite from polyester resin and graphene oxide.

Long-lasting phosphorescent nacre-like material was simply prepared from a nanocomposite of inorganic and organic materials. Low molecular weight unsaturated polyester (PET), graphene oxide (GO), and nanoparticles of rare-earth activated aluminate pigment were used in the preparation process of an organic/inorganic hybrid nanocomposite. Using methylethylketone peroxide (MEKP) as a hardener, we were able to develop a fluid solution that hardens within minutes at room temperature. Covalent and hydrogen bonds were introduced between the polyester resin and graphene oxide nanosheets. The interface interactions of those bonds resulted in toughness, excellent tensile strength, and high durability. The produced nacre substrates demonstrated long-persistent and reversible luminescence. The excitation of the produced nacre substrates at 365 nm resulted in a 524 nm emission. After being exposed to UV light, the photoluminescent nacre substrates became green. The increased superhydrophobic activity of the produced nacre substrates was achieved without affecting their physico-mechanical properties. HIGHLIGHTS: Colorless photoluminescent smart nacre-like nanocomposites were prepared. Graphene oxide and polyester were mixed with phosphor nanoparticles at 25°C. Photostable long-persistent phosphorescence lighting was observed in the dark. Photochromic change to green emission was detected under ultraviolet light. The nacre-like composites exhibit improved hardness and hydrophobicity.

Development of green and sustainable smart biochromic and therapeutic bandage using red cabbage (Brassica oleracea L. Var. capitata) extract encapsulated into alginate nanoparticles.

Novel multifunctional wound dressing with the ability to protect, cure and sense the healing process, was developed. Red-cabbage extract has been reported to exhibit bioactive compounds with the ability to function as antioxidant, antiinflammatory, anticancer, antibacterial, antifungal, and antiviral agent, as well as a natural pH-sensory chromophoric material. An anthocyanin extract was prepared from Red-cabbage (Brassica oleracea L. Var. capitata). The anthocyanins extract was encapsulated into calcium alginate in the presence of potash alum mordant, which was then applied to the surface of the cotton gauze. Red-cabbage based anthocyanin chromophoric extract was encapsulated at different concentrations into alginate-based hydrogel and immobilized into cotton gauze to provide a smart therapeutic pH-responsive wound dress to function as an antimicrobial and biochromic matrix providing a comfortable dress sensor to monitor the wound status. Decreasing the pH of a wound mimic solution caused a blue shift from 579 to 437 nm. The anthocyanin spectroscopic probe's halochromic activity demonstrated a colorimetric change from purple to pink, which was critical to the dyed cotton diagnostic assay's biochromic performance. The colorimetric parameters of the prepared dressing sensor were proved by UV-Vis absorbance and CIE Lab coordinates. Both mechanical and morphological properties of the prepared dressing were studied using different analytical methods. The effect of anthocyanin concentration on the mechanical, water vapor permeability, water absorption and morphological properties of the wound dressing were investigated. No substantial flaws in air-permeability or bend length were detected after dyeing. The colored cotton gauze samples were tested for their high colorfastness. The cytotoxicity and antimicrobial activity of the prepared biochromic cotton gauze were explored. The dyed cotton samples exhibited no cytotoxicity and improved antimicrobial activity with increasing the anthocyanin ratio on cotton surface.

Development of sponge-like cellulose colorimetric swab immobilized with anthocyanin from red-cabbage for sweat monitoring.

Novel sponge-like biochromic swab was developed via immobilization of natural anthocyanin (Cy) biomolecular probe into microporous cellulose aerogel. The current biosensor is characterized with simple preparation, environmentally-friendly, biocompatibility, biodegradability, flexibility, portability and reversibility. This biochromic sponge-like aerogel detector displayed a color change from pink to green-yellow in response to the biochemical changes occurs to sweat. This could be ascribed to intramolecular charge transfer occurs to the molecular system of Cy. Thus, the anthocyanin probe displayed colorimetric variations in UV-Vis absorption spectra via a blue shifting from 620 to 529 nm when raising the pH value of the prepared mimic sweat solution. Natural pH sensitive anthocyanin spectroscopic probe was extracted from red-cabbage plant, characterized by HPLC, and encapsulated into microporous cellulose. The microporous sponge-like cellulose swab was prepared by activating wood pulp utilizing phosphoric acid, and then subjected to freeze-drying. This anthocyanin probe is highly soluble in water. Thus, it was encapsulated as a direct dye into cellulose substrate during the freeze-drying process. To allow a better fixation of this water-soluble anthocyanin probe to the cellulose substrate, potash alum was added to the freeze-dried mixture to act as a fixing agent or mordant (M) generating Cy/M coordination complex. The produced Cy/M nanoparticles (NPs) were explored by transmission electron microscopy (TEM). The morphological features of the generated aerogels were investigated by scan electron microscope (SEM), energy-dispersive X-ray (EDX) spectra, and Fourier-transform infrared spectra (FT-IR). The cytotoxicity of the prepared aerogel-based biosensor was also evaluated. The naked-eye colorimetric changes were studied by exploring color strength, UV-Vis spectra and CIE Lab colorimetric coordinates.