Study of the Crystal Architecture, Optoelectronic Characteristics, and Nonlinear Optical Properties of 4-Amino Antipyrine Schiff Bases.

Two Schiff bases, (E)-4-((2-chlorobenzylidene)amino)-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one (4AAPOCB) and (E)-4-((4-chlorobenzylidene)amino)-1,5-dimethyl-2-phenyl-1,2-dihydro-3H-pyrazol-3-one (4AAPPCB), have been synthesized and grown as single crystals. Single-crystal X-ray diffraction analysis was employed to determine the crystal structure of the compounds, and the results suggest that the compounds crystallized into an orthorhombic crystal system having P212121 and Pbca space groups, respectively. Further, the crystallinity of the compounds was analyzed by the PXRD technique. The UV-vis-NIR spectra of the compounds demonstrate excellent transmittance in the entire visible region. The lower cutoff wavelengths of the compounds were determined to be 338 and 333 nm, respectively; additionally, optical band gaps of the compounds found were 4.60 and 4.35 eV. FTIR and NMR (1H and 13C) spectral techniques were utilized to analyze the molecular structure of the compounds. The compounds emit photoluminescence with broad emission bands with centers at 401 and 418 nm. The thermal stability and phase transitions were assessed through thermogravimetric methods. The phase transition prior to melting was indicated by the endothermic event at around 190 °C in the DTA curves of both crystals, and the same was observed in the DSC curves. The second harmonic efficiencies of the powdered compounds I and II were found to be 3.52 and 1.13 times better than that of the standard reference KDP. The 4AAPOCB and 4AAPPCB compounds showed isotropic polarizability amplitudes of 46.02 × 10-24 and 46.52 × 10-24 esu, respectively. The calculation of linear polarizability and NLO second-order polarizability (ß) along with other optical parameters was performed for optimized geometries. The nonzero amplitudes of the average ß values for compounds 4AAPOCB and 4AAPPCB were found to be 14.74 × 10-30 and 8.10 × 10-30 esu, respectively, which show a decent potential of the synthesized molecules for NLO applications. The calculated ß amplitudes were further explained based on calculated electronic parameters like molecular electrostatic potentials, frontier molecular orbitals, molecular orbital energies, transition energies, oscillator strengths, and unit spherical representation of NLO polarizability. The current analysis emphasizes the significance of synthesized compounds as prospective candidates for optical and NLO applications through the use of experiments and quantum computations.

Facile synthesis of efficient MoS2-coupled graphitic carbon nitride Z-scheme heterojunction nanocomposites: photocatalytic removal of methylene blue dye under solar light irradiation.

Among different types of semiconductor photocatalysts, MoS2 hybridized with graphitic carbon heterojunction has developed the most promising "celebrity" due to its static chemical properties, suitable band structure, and facile synthesis. Physiochemical and surface characterizations were revealed with structural, electronic, and optical analysis. Diffused reflectance spectroscopy evidenced the energy band gap tailoring from 2.62 eV for pure g-C3N4 and 1.68 eV for MoS2 to 2.12 eV for the hybridized heterojunction nanocomposite. Effective electron/hole pair separation, rise in redox species, and great utilization of solar range because of band gap modifying leading to greater degradation efficacy of g-C3N4/MoS2 heterojunction. The photocatalytic degradation with MoS2/g-C3N4 heterojunction catalyst to remove methylene blue dye was remarkably enriched and much higher than g-C3N4. By carefully examining the stimulus aspects, a probable mechanism is suggested, assuming that the concurring influence of MoS2 and g-C3N4, the lesser crystallite size, and more solubility in aquatic solution furnish the efficient e--h+ pair separation and tremendous photocatalytic degradation activity. This work delivers a novel idea to improve the efficient MoS2/g-C3N4 heterojunction for improved photocatalytic degradation in environmental refinement.

Synthesis of mesoporous Ag/α-Fe2O3/TiO2 heterostructures with enhanced and accelerated photo/-catalytic reduction of 4-nitrophenol.

4-Nitrophenol (4-NP) is reported to originate disadvantageous effects on the human body collected from industrial pollutants; therefore, the detoxification of 4-NP in aqueous contamination is strongly recommended. In this study, the heterojunction mesoporous α-Fe2O3/TiO2 modulated with diverse Ag percentages has been constructed via a sol-gel route in the occurrence of a soft template P123. The formation of biphasic crystalline TiO2 anatase and brookite phases has been successfully achieved with the average 10 nm particle sizes. The photo/-catalytic reduction of 4-NP has been performed utilizing NaBH4 as a reducing agent with and without visible illumination. All Ag/Fe2O3/TiO2 nanocomposites exhibited significantly higher photo/-catalytic reduction efficiency than pure Fe2O3, TiO2 NPs, and Fe2O3/TiO2 nanocomposite. 2.5% Ag/Fe2O3/TiO2 nanocomposite was considered the highest and superior photocatalytic reduction efficiency, and it almost achieved 98% after 9 min. Interestingly, the photocatalytic reduction of 4-NP was accelerated 9 times higher than the catalytic reduction over 2.5% Ag/Fe2O3/TiO2; its rate constant value was 709 and 706 times larger than pure TiO2 and Fe2O3 NPs, respectively. The enhanced photocatalytic reduction ability of Ag/Fe2O3/TiO2 nanocomposite might be referred to as significantly providing visible light absorption and a large surface area, and it can upgrade the effective separation and mobility of electron holes. The stability of the synthesized catalysts exhibited that the obtained catalysts can undergo a slight decrease in reduction efficiency after five successive cycles. This approach highlights a novel route for constructing ternary nanocomposite systems with high photo/-catalytic ability.

Removal of ceftriaxone sodium antibiotic from pharmaceutical wastewater using an activated carbon based TiO2 composite: Adsorption and photocatalytic degradation evaluation.

The water pollution becomes a serious concern for the sustainability of ecosystems due to the existence of pharmaceutical products (ceftriaxone (CEF) antibiotic). Even in low concentration of CEF has lethal effects on ecosystem and human health. To remove CEF, TiO2 is considered as an effective and efficient nanoparticles, however its performance is reduced due to wider energy gap and rapid recombination of charge carriers. In this study, activated carbon based TiO2 (ACT-X) heterogeneous nanocomposites were synthesized to improve the intrinsic properties of TiO2 and their adsorption-photocatalytic performance for the removal of CEF. The characterization results revealed that ACT-X composites have slower recombination of charge carriers, lower energy band gap (3.05 eV), and better light absorption under visible region of light. From ACT-X composites, the ACT-4 photocatalyst has achieved highest photocatalytic degradation (99.6%) and COD removal up (99.2%). The results of radical scavengers showed that photocatalytic degradation of CEF is mainly occurred due to superoxide and hydroxyl radicals. Meanwhile, the reusability of ACT-4 up to five cycles shows more than 80% photocatalytic degradation, which make the process more economical. The highest experimental adsorption capacity is achieved up to 844.8 mg g-1 using ACT-4. The favorable and multilayer heterogeneous adsorption is carried out according to the well-fitted data with pseudo-second-order and Freundlich models, respectively. These results indicate that the carbon-based TiO2 composites can be used as a green, stable, efficient, effective, reusable, renewable, and sustainable photocatalyst to eliminate the pharmaceutical pollutants (antibiotics) via adsorption and photocatalytic degradation processes.

A Targeted Review of Current Progress, Challenges and Future Perspective of g-C3 N4 based Hybrid Photocatalyst Toward Multidimensional Applications.

The increasing demand for searching highly efficient and robust technologies in the context of sustainable energy production totally rely onto the cost-effective energy efficient production technologies. Solar power technology in this regard will perceived to be extensively employed in a variety of ways in the future ahead, in terms of the combustion of petroleum-based pollutants, CO2 reduction, heterogeneous photocatalysis, as well as the formation of unlimited and sustainable hydrogen gas production. Semiconductor-based photocatalysis is regarded as potentially sustainable solution in this context. g-C3 N4 is classified as non-metallic semiconductor to overcome this energy demand and enviromental challenges, because of its superior electronic configuration, which has a median band energy of around 2.7 eV, strong photocatalytic stability, and higher light performance. The photocatalytic performance of g-C3 N4 is perceived to be inadequate, owing to its small surface area along with high rate of charge recombination. However, various synthetic strategies were applied in order to incorporate g-C3 N4 with different guest materials to increase photocatalytic performance. After these fabrication approaches, the photocatalytic activity was enhanced owing to generation of photoinduced electrons and holes, by improving light absorption ability, and boosting surface area, which provides more space for photocatalytic reaction. In this review, various metals, non-metals, metals oxide, sulfides, and ferrites have been integrated with g-C3 N4 to form mono, bimetallic, heterojunction, Z-scheme, and S-scheme-based materials for boosting performance. Also, different varieties of g-C3 N4 were utilized for different aspects of photocatalytic application i. e., water reduction, water oxidation, CO2 reduction, and photodegradation of dye pollutants, etc. As a consequence, we have assembled a summary of the latest g-C3 N4 based materials, their uses in solar energy adaption, and proper management of the environment. This research will further well explain the detail of the mechanism of all these photocatalytic processes for the next steps, as well as the age number of new insights in order to overcome the current challenges.

Ameliorative role of chitosan nanoparticles against silver nanoparticle-induced reproductive toxicity in male albino rats.

This study was designed to evaluate the protective potentials of chitosan nanoparticles (ChNPs) against silver nanoparticle (AgNP)-induced reproductive toxicity in male Wister albino rats. AgNPs, ChNPs, and AgNPs particles coated with ChNPs were characterized by using transmission electron microscope. Control rats were injected interperitoneally with 0.5% aqueous carboxymethyl cellulose. Second group was given ChNPs at a dose 300 mg/kg bwt. Third group was given AgNPs at a dose 50 mg/kg bwt. Fourth group was given AgNPs with chitosan nanoparticles simultaneously. Fifth group was given silver nanoparticles coated with chitosan nanoparticles at a dose 300 mg/kg bwt. TEM showed the formation of AgNPs with average size of 42.7 nm, ChNPs with average size of 33.3 nm, and AgNPs coated with ChNPs with average size of 48.1 nm. AgNPs significantly reduced serum levels of FSH, LH, testosterone and prolactin, sperm count, morphology index, vitality, total motility and progressive motility, the activities of catalase and superoxide dismutase, and the concentration of reduced glutathione in testicular tissues. However, it significantly increased malondialdehyde concentration in testicular tissues, sperm abnormalities, testicular tissue damages, non-progressive motility, and immotile sperms. On the contrast, ChNPs ameliorated AgNP-induced alteration in serum levels of sex hormones, spermogram, and testicular tissue's structure and functions. These results indicated that ChNPs had protective potential against AgNP-induced reproductive toxicity and ChNPs coating AgNPs had more potent protective effect than ChNPs administrated together with AgNPs.

Poly (Vinyl Alcohol)/Agar Hydrogel Electrolytes Based Flexible All-in-One Supercapacitors with Conducting Polyaniline/Polypyrrole Electrodes.

The major components of supercapacitor are electrodes and electrolytes which are fabricated using various materials and methods. Hydrogel is one such material that is used in supercapacitors as electrodes and electrolytes or both. Hydrogels are usually described as a soft and porous network of polymer materials that can swell in water because of the hydrophilic nature of its polymer chains, compriseng a 3D structure. It is well known that supercapacitors possess high-power density but low energy density. For enhancing energy density of these electrochemical cells and a boost in its electrochemical performance and specific capacity, binder free conducting polymer hydrogel electrodes have gained immense attention, especially polyaniline (PANI) and polypyrrole (PPy). Therefore, in this work, chemically crosslinked PVA/Agar hydrogel electrolytes have been prepared and employed. Agar has been added in PVA since it is environmentally friendly, biodegradable, and cost-effective natural polymer. Subsequently, the binder free polyaniline/polypyrrole electrodes were grown on the PVA/Agar hydrogel electrolytes to fabricate all-in-one flexible hydrogels. The synthesized hydrogels were characterized using X-ray diffraction (XRD) analysis, Fourier transform infrared (FTIR) analysis, Field emission scanning electron microscope (FESEM) and mechanical studies. Then, the all-in-one flexible supercapacitors were fabricated using the hydrogels. The electrochemical studies such cyclic voltammetry (CV), galvanic charge discharge (GCD), and electrochemical impedance spectroscopy (EIS) studies. The fabricated all-in-one lamination free supercapacitors showed promising results and by comparing all four samples, PAP2 where 5 mL of PVA was used in combination with 3 mL of Agar and 5 mL of PANI and PPy each, exhibited the highest areal capacitance of 750.13 mF/cm2, energy density of 103.02 µWh/cm2, and 497.22 µW/cm2 power density. The cyclic stability study revealed the 149% capacity retention after 15,000 cycles.

Are Antisense Long Non-Coding RNA Related to COVID-19?

Fighting external pathogens relies on the tight regulation of the gene expression of the immune system. Ferroptosis, which is a distinct form of programmed cell death driven by iron, is involved in the enhancement of follicular helper T cell function during infection. The regulation of RNA is a key step in final gene expression. The present study aimed to identify the expression level of antisense lncRNAs (A2M-AS1, DBH-AS1, FLVCR1-DT, and NCBP2AS2-1) and FLVCR1 in COVID-19 patients and its relation to the severity of the disease. COVID-19 patients as well as age and gender-matched healthy controls were enrolled in this study. The expression level of the antisense lncRNAs was measured by RT-PCR. Results revealed the decreased expression of A2M-AS1 and FLVCR1 in COVID-19 patients. Additionally, they showed the increased expression of DBH-AS1, FLVCR1-DT, and NCBP2AS2. Both FLVCR1-DT and NCBP2AS2 showed a positive correlation with interleukin-6 (IL-6). DBH-AS1 and FLVCR1-DT had a significant association with mortality, complications, and mechanical ventilation. A significant negative correlation was found between A2M-AS1 and NCBP2AS2-1 and between FLVCR1 and FLVCR1-DT. The study confirmed that the expression level of the antisense lncRNAs was deregulated in COVID-19 patients and correlated with the severity of COVID-19, and that it may have possible roles in the pathogenesis of this disease.

Effect of Polyethylene Glycol and Activated Carbon Macroparticles on Thermal Conductivity of Paraffin Wax for Thermal Storage Applications.

Low thermal conductivity is the major obstacle for the wide range utilization of phase change materials (PCMs), especially organic PCMs, for most practical applications in thermal engineering. This study investigates the potential of enhancing the charging and discharging rates of organic PCM (RT44HC) by introducing polyethylene glycol (PEG) and activated carbon macroparticles (ACMPs). Different concentrations of PEG and ACMPs ranging from 0.3 wt% to 2 wt% were tested separately. The optimized concentrations found were used as dual reinforcements to attain the highest possible thermal conductivity. The specimens were tested for a complete charging-discharging cycle using an improvised thermal apparatus. Use of ACMP alone resulted in a minimal reduction in complete charging-discharging time due to the settlement of ACMPs at the bottom after 2-3 heating-cooling cycles. However, the addition of PEG with ACMPs exhibited a reduction in charging-discharging time due to the formation of a stable dispersion. PEG served as a stabilizing agent for ACMPs. The lowest charging-discharging time of 180 min was exhibited by specimens containing 1 wt% PEG and 0.5 wt% ACMPs which is 25% lower compared to bare PCM.

Enhancement in the Structural, Electrical, Optical, and Photocatalytic Properties of La2O3-Doped ZnO Nanostructures.

A lanthanum oxide (La2O3)-ZnO nanostructured material was synthesized in the proposed study with different La2O3 concentrations, 0.001 g to 5 g (named So to S7), using the combustion method. X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transformation infrared spectroscopy (FT-IR) were utilized for investigating the structure, morphology, and spectral studies of the La2O3- ZnO nanomaterials, respectively. The results obtained from previous techniques support ZnO's growth from crystalline to nanoparticles' fine structure by changing the concentrations of lanthanum oxide (La2O3) dopants in the host matrix. The percentage of ZnO doped with La- influences the ZnO photocatalytic activity. SEM analysis confirmed the grain size ranged between 81 and 138 nm. Furthermore, UV-Vis diffuse reflectance spectroscopy was performed to verify the effects of La2O3 dopants on the linear optical properties of the nano-composite oxides. There was a variation in the energy bandgaps of La2O3-ZnO nanocomposites, increasing the weight concentrations of lanthanum dopants. The AC electrical conductivity, dielectric properties, and current-voltage properties support the enactment of the electrical characteristics of the ZnO nanoparticles by adding La2O3. All the samples under investigation were used for photodegradation with Rhodamine B (RhB) and Methylene Blue (MB). In less than 30 min of visible light irradiation, S4 (0.5 g) La2O3-ZnO reached 99% of RhB and MB degradation activity. This study showed the best photocatalytic effect for RhB and MB degradation of 0.13 and 0.11 min-1 by 0.5 g La2O3-ZnO. Recycling was performed five times for the nanocatalysts that displayed up to 98 percent catalytic efficiency for RhB and MB degradation in 30 min. The prepared La2O3-ZnO nanostructured composites are considered novel candidates for various applications in biomedical and photocatalytic studies.

Recent Advancement in Rational Design Modulation of MXene: A Voyage from Environmental Remediation to Energy Conversion and Storage.

Use of MXenes (Ti3 C2 Tx ), which belongs to the family of two-dimensional transition metal nitrides and carbides by encompassing unique combination of metallic conductivity and hydrophilicity, is receiving tremendous attention, since its discovery as energy material in 2011. Owing to its precursor selective chemical etching, and unique intrinsic characteristics, the MXene surface properties are further classified into highly chemically active compound, which further produced different surface functional groups i. e., oxygen, fluorine or hydroxyl groups. However, the role of surface functional groups doesn't not only have a significant impact onto its electrochemical and hydrophilic characteristics (i. e., ion adsorption/diffusion), but also imparting a noteworthy effect onto its conductivity, work function, electronic structure and properties. Henceforth, such kind of inherent chemical nature, robust electrochemistry and high hydrophilicity ultimately increasing the MXene application as a most propitious material for overall environment-remediation, electrocatalytic sensors, energy conversion and storage application. Moreover, it is well documented that the role of MXenes in all kinds of research fields is still on a progress stage for their further improvement, which is not sufficiently summarized in literature till now. The present review article is intended to critically discuss the different chemical aptitudes and the diversity of MXenes and its derivates (i. e., hybrid composites) in all aforesaid application with special emphasis onto the improvement of its surface characteristics for the multidimensional application. However, this review article is anticipated to endorse MXenes and its derivates hybrid configuration, which is discussed in detail for emerging environmental decontamination, electrochemical use, and pollutant detection via electrocatalytic sensors, photocatalysis, along with membrane distillation and the adsorption application. Finally, it is expected, that this review article will open up new window for the effective use of MXene in a broad range of environmental remediation, energy conversion and storage application as a novel, robust, multidimensional and more proficient materials.

Recent advancement in conjugated polymers based photocatalytic technology for air pollutants abatement: Cases of CO2, NOx, and VOCs.

According to World Health Organization (WHO) survey, air pollution has become the major reason of several fatal diseases, which had led to the death of 7 million peoples around the globe. The 9 people out of 10 breathe air, which exceeds WHO recommendations. Several strategies are in practice to reduce the emission of pollutants into the air, and also strict industrial, scientific, and health recommendations to use sustainable green technologies to reduce the emission of contaminants into the air. Photocatalysis technology recently has been raised as a green technology to be in practice towards the removal of air pollutants. The scientific community has passed a long pathway to develop such technology from the material, and reactor points of view. Many classes of photoactive materials have been suggested to achieve such a target. In this context, the contribution of conjugated polymers (CPs), and their modification with some common inorganic semiconductors as novel photocatalysts, has never been addressed in literature till now for said application, and is critically evaluated in this review. As we know that CPs have unique characteristics compared to inorganic semiconductors, because of their conductivity, excellent light response, good sorption ability, better redox charge generation, and separation along with a delocalized π-electrons system. The advances in photocatalytic removal/reduction of three primary air-polluting compounds such as CO2, NOX, and VOCs using CPs based photocatalysts are discussed in detail. Furthermore, the synergetic effects, obtained in CPs after combining with inorganic semiconductors are also comprehensively summarized in this review. However, such a combined system, on to better charges generation and separation, may make the Adsorb & Shuttle process into action, wherein, CPs may play the sorbing area. And, we hope that, the critical discussion on the further enhancement of photoactivity and future recommendations will open the doors for up-to-date technology transfer in modern research.

Modification of DSSC Based on Polymer Composite Gel Electrolyte with Copper Oxide Nanochain by Shape Effect.

Solvent evaporation and leakage of liquid electrolytes that restrict the practicality of dye-sensitized solar cells (DSSCs) motivate the quest for the development of stable and ionic conductive electrolyte. Gel polymer electrolyte (GPE) fits the criteria, but it still suffers from low efficiency due to insufficient segmental motion within the electrolytes. Therefore, incorporating metal oxide nanofiller is one of the approaches to enhance the performance of electrolytes due to the presence of cross-linking centers that can be coordinated with the polymer segments. In this research, polymer composite gel electrolytes (PCGEs) employing poly (vinyl butyral-co-vinyl alcohol-co-vinyl acetate) (P(VB-co-VA-co-VAc)) terpolymer as host polymer, tetrapropylammonium iodide (TPAI) as dopant salt, and copper oxide (CuO) nanoparticles as the nanofillers were produced. The CuO nanofillers were synthesized by sonochemical method and subsequently calcined at different temperatures (i.e., 200, 350, and 500 °C), denoted as CuO-200, CuO-350, and CuO-500, respectively. All CuO nanoparticles have different shapes and sizes that are connected in a chain which impact the amorphous phase and the roughness of the surface, proven by the structural and the morphological analyses. It was found that the PCGE consisting of CuO-350 exhibited the highest ionic conductivity of 2.54 mS cm-1 and apparent diffusion coefficient of triiodide of 1.537 × 10-4 cm2 s-1. The enhancement in the electrochemical performance of the PCGEs is correlated with the change in shape (rod to sphere) and size of CuO particles which disrupted the structural order of the polymer chain, facilitating the redox couple transportation. Additionally, a DSSC was fabricated and achieved the highest power conversion efficiency of 7.05% with JSC of 22.1 mA cm-2, VOC of 0.61 V, and FF of 52.4%.

Microstructure Study and Linear/Nonlinear Optical Performance of Bi-Embedded PVP/PVA Films for Optoelectronic and Optical Cut-Off Applications.

Hybrid polymer films of polyvinyl pyrrolidone (PVP)/polyvinyl alcohol (PVA) embedded with gradient levels of Bi-powder were prepared using a conventional solution casting process. XRD, FTIR, and SEM techniques have been used to examine the micro/molecular structure and morphology of the synthesized flexible films. The intensities of the diffraction peaks and transmission spectrum of the PVP/PVA gradually declined with the introduction of Bi-metal. In addition, filler changes the microstructure surface of the pure film. The modification in the microstructure leads to an enhancement in the optical absorption characteristic of the blend films. The indirect allowed transition energy was calculated via Tauc's and ASF (Absorption Spectra Fitting) models. The decrease in the hybrid film's bandgap returns to the localized states in the forbidden region, which led the present films to be suitable for photo-electric, solar cell, etc., applications. The relation between the transition energy and the refractive index was studied. The enhancement in the refractive index with Bi-metal concentrations led to use the as-prepared films in optical sensors. The rise of Bi-metal concentrations leads also to the improvement of the nonlinear susceptibility and refractive parameters. The optical limiting characteristics revealed that the higher concentration dopant films reduce the light transmission intensity which is appropriate for laser attenuation and optical limiting in photonic devices. The results suggest that hybrid films are promising materials in a wide range of opto-electronic applications.

The Auto-Combustion Method Synthesized Eu2O3- ZnO Nanostructured Composites for Electronic and Photocatalytic Applications.

An efficient and environmentally friendly combustion technique was employed to produce ZnO nanopowders with different Eu concentrations (from 0.001 g to 5 g). The structural morphology of the Eu2O3-ZnO nanocomposites was examined using XRD, SEM, and infrared spectroscopy (FT-IR). In addition, UV-Vis diffuse reflectance spectroscopy was also used to investigate the effects of europium (Eu) dopant on the optical behaviors and energy bandgaps of nano-complex oxides. The photocatalytic degradation efficiency of phenol and methylene blue was investigated using all the prepared Eu2O3-ZnO nanostructured samples. Photocatalytic effectiveness increased when europium (Eu) doping ratios increased. After adding moderate Eu, more hydroxyl radicals were generated over ZnO. The best photocatalyst for phenol degradation was 1 percent Eu2O3-ZnO, while it was 0.5 percent Eu2O3-ZnO for methylene blue solutions. The obtained Eu2O3-doped ZnO nanostructured materials are considered innovative, promising candidates for a wide range of nano-applications, including biomedical and photocatalytic degradation of organic dyes and phenol.

Thermal Stability, Optical Properties, and Gamma Shielding Properties of Tellurite Glass Modified with Potassium Chloride.

The synthesized glass system with a composition of (80-x) TeO2-10P2O5-10Nb2O5-xKCl mol% (where x = 5, 10, 15, 20, and 25) was successfully fabricated. The density (ρ) and molar volume (Vm) have been calculated. The investigated glasses were characterized using different analysis methods (differential thermal analysis (DTA) and UV-VIS-NIR spectroscopy). The radiation shielding effectiveness of the synthesized glass system was evaluated using different shielding parameters, such as mass and linear attenuation coefficients (MAC, LAC), half-value layer (HVL), mean free path (MFP), effective atomic number (Zeff), and effective electron number (Neff). The results showed that with the increasing potassium chloride (KCl) concentration and decreasing tellurium oxide (TeO2) concentration, the density, refractive index, Urbach energy (Eu), and glass transition temperature (Tg) decreased, while the optical energy gap (Eopt) and thermal stability increased. As the KCl concentration increases, the values of MAC, LAC, and Zeff increase in the following order: TPNK5 % > TPNK10 % > TPNK15 % > TPNK20 % > TPNK25 %. Additionally, the shielding effectiveness of TPNK glass system showed good performance compared with some standard materials. The synthesized glass with a minimum KCl content has both good shielding effectiveness and good optical properties, in addition to reasonable thermal stability, which makes it suitable for shielding and optical applications.

Assembling Hollow Cactus-Like ZnO Nanorods with Dipole-Modified Graphene Nanosheets for Practical Room-Temperature Formaldehyde Sensing.

Formaldehyde (HCHO) sensing plays a critical role for indoor environment monitoring in smart home systems. Inspired by the unique hierarchical structure of cactus, we have prepared a ZnO/ANS-rGO composite for room-temperature (RT) HCHO sensing, through assembling hollow cactus-like ZnO nanorods with 5-aminonaphthalene-1-sulfonic acid (ANS)-modified graphene nanosheets in a facile and template-free manner. Interestingly, it was found that the ZnO morphology could be simply tuned from flower clusters to hollow cactus-like nanostructures, along with the increase of the reaction time during the assembly process. The ZnO/ANS-rGO-based sensors exhibited superior RT HCHO-sensing performance with an ultrahigh response (68%, 5 ppm), good repeatability, long-term stability, and an outstanding practical limit of detection (LOD: 0.25 ppm) toward HCHO, which is the lowest practical LOD reported so far. Furthermore, for the first time, a 30 m3 simulation test cabinet was adapted to evaluate the practical gas-sensing performance in an indoor environment. As a result, an instantaneous response of 5% to 0.4 ppm HCHO was successfully achieved in the simulation test. The corresponding sensing mechanism was interpreted from two aspects including high charge transport capability of ANS-rGO and the distinct gas adsorbability derived from nanostructures, respectively. The combination of a biomimetic hierarchical structure and supramolecular assembly provides a promising strategy to design HCHO-sensing materials with high practicability.

Multifunctional and smart Er2O3-ZnO nanocomposites for electronic ceramic varistors and visible light degradation of wastewater treatment.

In this proposed study, erbium (Er3+)-doped ZnO nanocomposites were prepared through the effective, basic, and green combustion method. The significant effects of Er dopants on the structural, morphological features, dielectric, and optical behaviors of the pure ZnO matrix as well as Er2O3-ZnO nanostructured materials were investigated applying X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transformation infrared (FT-IR) spectroscopy, and UV-Vis spectrophotometer techniques. These results showed that the synthesized Er2O3-ZnO nanocomposites are well polycrystalline. The Er2O3-ZnO nanocomposites are almost uniformly distributed on the surface morphologies. Furthermore, UV-Vis diffuse reflectance spectroscopy, AC electrical conductivity, and dielectric properties' current-voltage characteristics were utilized to examine the influence of erbium doping on the optical properties, energy bandgaps of the proposed Er2O3-ZnO nanostructured powder. The tested nano-samples were applied for the visible light photodegradation of p-chlorophenol(4-CP) and p-nitrophenol (4-NP). The Er-doped ZnO ratio affects the photocatalytic activity of the ZnO matrix. This current research substantiated that more than 99.5% of 4-CP and 4-NP were photodegraded through 30 min of irradiation. Four times, the Er:ZnO nanocatalysts were used and still displayed an efficiency of more than 96.5% for 4-CP and 4-NP degradations in the specified period of 30 min. The as-prepared Er2O3-ZnO nanostructures are considered novel potential candidates in broad nano-applications from visible photocatalytic degradation of waste pollutants to the electronic varistor devices.

Charge transfer driven by redox dye molecules on graphene nanosheets for room-temperature gas sensing.

Special functional groups to modify the surface of graphene have received much attention since they enable the charge transfer enhancement, thus realizing gas-sensing at room temperature. In this work, three typical redox dye molecules, methylene blue (MB), indigo carmine (IC) and anthraquinone-2-sulfonate (AQS), were selected to be supramolecularly assembled with reduced graphene oxide (rGO), respectively. Remarkably, three graphene-based materials AQS-rGO (response = 3.2, response time = 400 s), IC-rGO (response = 4.3, response time = 300 s) and MB-rGO (response = 7.1, response time = 100 s) exhibited excellent sensitivity and short response time toward 10 ppm NO2 at room temperature. The corresponding NO2 sensing mechanism of the obtained materials was further investigated by cyclic voltammetry (CV) measurements. CV was conducted to measure the anodic peak potential (Epa) of three redox dyes. Interestingly, it is obvious that the Epa values were positively correlated with the gas sensitivity and response time of the three materials. To explore the mechanism, UV-vis spectroscopy was adopted to analyze the lowest unoccupied molecular orbitals (LUMOs) of three redox dye molecules. The results show that the oxidation abilities of three redox dyes were also positively correlated with the gas sensitivity and response time of three corresponding graphene-based materials.

The Recent Progress on Silver Nanoparticles: Synthesis and Electronic Applications.

Nanoscience enables researchers to develop new and cost-effective nanomaterials for energy, healthcare, and medical applications. Silver nanoparticles (Ag NPs) are currently increasingly synthesized for their superior physicochemical and electronic properties. Good knowledge of these characteristics allows the development of applications in all sensitive and essential fields in the service of humans and the environment. This review aims to summarize the Ag NPs synthesis methods, properties, applications, and future challenges. Generally, Ag NPs can be synthesized using physical, chemical, and biological routes. Due to the great and increasing demand for metal and metal oxide nanoparticles, researchers have invented a new, environmentally friendly, inexpensive synthetic method that replaces other methods with many defects. Studies of Ag NPs have increased after clear and substantial support from governments to develop nanotechnology. Ag NPs are the most widely due to their various potent properties. Thus, this comprehensive review discusses the different synthesis procedures and electronic applications of Ag NPs.