Enhancement of nitrogen removal and energy recovery from low C/N ratio sewage by multi-electrode electrochemical technology and tidal flow via siphon aeration.

In view of the difficulty in denitrification of low C/N ratio wastewater, electrochemical technology with multiple electrodes and tidal flow method via siphon aeration were used to enhance the denitrification process. At the same time, because of the low phosphorus removal efficiency in traditional activated sludge process, the constructed wetland and microbial fuel cell (CW-MFC) reactor with dewatered alum sludge (DAS) as substrate were constructed. In addition, the REDOX conditions of the reactor were changed by siphon, which significantly improved the removal efficiency of N and P and the energy recovery capacity of the reactor. In the 172 d, the Tidal Flow Constructed Wetland-Microbial Fuel Cell (TF CW-MFC) had the highest removal efficiency of COD and total nitrogen (TN), which were 97.4% and 83.4%, respectively. Although the removal rate of total phosphorus (TP) by TF CW-MFC was lower than artificial aeration, it can still reached 89.0%. The removal effect of aromatic protein substances in water was also significant. The amount of electrons generated by the artificial aeration anode and the amount of oxygen generated by the cathode were not enough to match. The voltage of TF CW-MFC was significantly higher than artificial aeration, around 350 mV, and the maximum power density was 98.16 mW m-3. In addition, MFC had an inhibitory effect on CW methane emissions. The analysis of the microbial community structure showed that most of the dominant bacteria of TF CW-MFC belonged to the Proteobacteria, Actinobacteria and Chloroflexi. These results showed that the TF CW-MFC technology as a zero-energy oxygen supply mode had high efficiency in the treatment of low C/N ratio wastewater and also had the environmental effect of reducing methane emissions. This study suggests that this green wastewater treatment technology has potential application value.

The role and related microbial processes of Mn-dependent anaerobic methane oxidation in reducing methane emissions from constructed wetland-microbial fuel cell.

Anaerobic oxidation of methane (AOM) plays an important role in global carbon cycle and greenhouse gas emission reduction. In this study, an effective green technology to reduce methane emissions was proposed by introducing Mn-dependent anaerobic oxidation of methane (Mn-AOM) and microbial fuel cell (MFC) technology into constructed wetland (CW). The results indicate that the combination of biological methods and bioelectrochemical methods can more effectively control the methane emission from CW than the reported methods. The role of dissimilated metal reduction in methane control in CW and the biochemical process associated with Mn-AOM were also investigated. The results demonstrated that using Mn ore as the matrix and operating MFC effectively reduced methane emissions from CW, and higher COD removal rate was obtained in CW-MFC (Mn) during the 200 days of operation. Methane emission from CW-MFC (Mn) (53.76 mg/m2/h) was 55.61% lower than that of CW (121.12 mg/m2/h). The highest COD removal rate (99.85%) in CW-MFC (Mn) was obtained. As the dissimilative metal-reducing microorganisms, Geobacter (5.10%) was found enriched in CW-MFC (Mn). The results also showed that the presence of Mn ore was beneficial to the biodiversity of CW-MFCs and the growth of electrochemically active bacteria (EAB) including Proteobacteria (35.32%), Actinobacteria (2.38%) and Acidobacteria (2.06%), while the growth of hydrogenotrophic methanogens Methanobacterium was effectively inhibited. This study proposed an effective way to reduce methane from CW. It also provided reference for low carbon technology of wastewater treatment.

Carbon dioxide and methane emission of denitrification bioreactor filling waste sawdust and industrial sludge for treatment of simulated agricultural surface runoff.

Carbon dioxide (CO2) and methane (CH4) produced by denitrification bioreactors in processing agricultural surface runoff have contributed to increasing proportion of greenhouse gases (GHG) emissions. It is the first time to monitor and quantify the emission flux of CO2 and CH4 produced by laboratory-scale denitrification bioreactors which recycled waste Cunninghamia lanceolata sawdust (CLS) and industrial sludge (IS) as fillers to process simulated agricultural surface runoff. Sludge-water ratio, inflow rate and water flow direction are used as experimental factors to study the effect on the emission flux of CO2 and CH4. Results show that emission flux of CO2 from denitrification bioreactors with different sludge-water ratio approached 20 mg m-2h-1, simultaneously the average emission flux of CH4 produced by all bioreactors was 1.785 mg m-2h-1. The addition of sludge increased the emission flux of CH4 and had no significant effect on the emission flux of CO2. Increasing the inflow rate reduced the CO2 emission flux from 21.57 to 1.27 mg m-2h-1, and at the same time increased the CH4 emission flux from 0.007 to 9.54 mg m-2h-1. The gravity flow of wastewater reduced the emission flux of CO2 and CH4. The emissions of CO2 and CH4 from folded plate denitrification bioreactor with CLS and industrial sludge with a volume ratio of 1:2 can be reduced by 24.67% and 73.3%, respectively. There was no need to add special gas collection and treatment devices because CO2 and CH4 emission fluxes produced by the folded plate denitrification bioreactor and gravity denitrification bioreactor are not enough to increase the greenhouse effect. This study quantified the CO2 and CH4 produced by denitrification bioreactors filling CLS and IS, and provided a reference for future research on the gases produced by the denitrification process.

Characterization of dissolved organic matter for understanding the adsorption on nanomaterials in aquatic environment: A review.

Nanomaterials (NMs) have received tremendous attention as emerging adsorbents for environmental applications. The ever-increasing release into aquatic systems and the potential use in water treatment processes heighten the likelihood of the interactions of NMs with aquatic dissolved organic matter (DOM). Once DOM is adsorbed on NMs, it substantially modifies the surface properties, thus altering the fate and transport of NMs, as well as their toxic effects on (micro)organisms in natural and engineered systems. The environmental consequences of DOM-NMs interaction have been widely studied in the literature. In contrast, a comprehensive understanding of DOM-NM complexes, particularly regarding the controlling factors, is still lacking, and its significance has been largely overlooked. This gap in the knowledge mainly arises from the complex and heterogeneous structures of the DOM, which prompts the urgent need to further characterize the DOM properties to deepen the understanding associated with the adsorption processes on NMs. This review aims to provide in-depth insights into the complex DOM adsorption behavior onto NMs, whether they are metal- or carbon-based materials. First, we summarize the up-to-date analytical methods to characterize the DOM to unravel the underlying adsorption mechanisms. Second, the key DOM characteristics governing the adsorption processes are discussed. Next, the environmental factors, such as the nature of adsorbents and solution chemistry, affecting the DOM-NM interactions, are identified and discussed. Finally, future studies are recommended to fully understand the chemical traits of DOM upon its adsorption onto NMs.

Improved Anti-Biofouling Performance of Thin -Film Composite Forward-Osmosis Membranes Containing Passive and Active Moieties.

Forward osmosis (FO) has gained increasing attention in desalination, wastewater treatment, and power generation. However, biofouling remains a major obstacle for the sustainable development of the FO process. Both passive and active strategies have been developed to mitigate membrane biofouling. A comprehensive understanding of different strategies and mechanisms has fundamental significance for the antifouling membrane development. In this study, thin-film composite (TFC) FO membranes were modified with polydopamine (PDA) coating as a passive antibacterial moiety and silver nanoparticles (Ag NPs) as an active antibacterial moiety. Their anti-biofouling performances were investigated both in static and dynamic conditions. In static exposure, the PDA-coated membranes exhibited great passive anti-adhesive property, and the Ag-NP-generated membranes presented both of excellent passive anti-adhesive properties and active antibacterial performance. While in dynamic cross-flow running conditions, Ag NPs effectively mitigated the membrane water flux decline due to their inhibition of biofilm growth, the PDA coating failed because of its inability to inactivate the attached bacteria growth. Moreover, Ag NPs were stable and active on membrane surfaces after 24 h of cross-flow operation. These findings provide new insights into the performances and mechanisms of passive and active moieties in the FO process.

Surface Engineering of Thin Film Composite Polyamide Membranes with Silver Nanoparticles through Layer-by-Layer Interfacial Polymerization for Antibacterial Properties.

We developed a simple and facile approach to covalently immobilize Ag nanoparticles (NPs) onto polyamide surfaces of thin film composite membranes through layer-by-layer interfacial polymerization (LBL-IP) for biofouling mitigation. Stable and uniform bovine serum albumin (BSA) capped Ag NPs with an average diameter of around 20 nm were synthesized using BSA as a template under the assistance of sonication, and Ag NPs incorporated thin film composite (TFC) polyamide membrane was then fabricated by LBL-IP on a nanoporous polysulfone (PSf) substrate upon sequential coating with m-phenylenediamine (MPD) aqueous solution, trimesoyl chloride (TMC)-hexane solution, and finally BSA-capped Ag NPs aqueous solution. The influence of Ag NPs incorporation was investigated on the surface physicochemical properties, water permeability, and salt rejection of TFC polyamide membrane. Our findings show that Ag NPs functionalized membrane exhibited excellent antibacterial properties without sacrificing their permeability and rejection, and Ag NPs incorporation affected very little surface roughness and charge of polyamide layer. Moreover, the incorporated Ag NPs presented a low release rate and excellent stability on polyamide surface in cross-flow conditions. Given the simplicity and versatility of this approach, our study provides a practicable avenue for direct incorporation of various surface-tailored nanomaterials on the polyamide surface to develop high-performance TFC membranes with fouling-resistant properties on a large scale.