Ionic liquid modified PVDF/BCZT nanocomposites for space charge induced mechanical energy harvesting performance.

Mechanical energy harvesting performances of poly(vinylidene fluoride) (PVDF) based composites are most often correlated with their polar phase and the individual piezoelectricity of the used filler materials. Here we show that the significant enhancement of space charge polarization of the said composites can play the key dominant role in determining their mechanical energy harvesting performance regardless of their polar phase and individual piezoelectricity of the used fillers. For this purpose, ionic liquid has been incorporated into PVDF/0.5(Ba0.7Ca0.3)TiO3-0.5Ba(Ti0.8Zr0.2)O3(BCZT) composites which led to a huge enhancement in space charge polarization. The gradual addition of ionic liquid into 10 wt% BCZT loaded PVDF (PBCZT) has helped in extraordinarily enhancing the conductivity gradually which has confirmed the huge enhancement of space charge polarization. However, after a certain limit of ionic liquid addition, the polar phase of the composite films is decreased. Despite this, the output voltages from the piezoelectric and piezo-tribo hybrid nanogenerators (PENGs and HNGs, respectively) fabricated by using the developed films have been found to be increased gradually with the increase in the ionic liquid amount in PBCZT composite. As the amount of BCZT filler was kept fixed for all the films, this result has confirmed the key role of space charge polarization of PVDF-based composites in determining their mechanical energy harvesting performances compared to the effect of polar phase and individual piezoelectricity of filler. The optimized PENG and HNG devices have shown the output voltage as high as 52 and 167 V, respectively, with power densities ∼85 and 152µW cm-2which predicted their excellent usability in real life energy conversion devices. This work also shows that the effect of extraordinarily enhanced space charge polarization is effective in improving the performance of all types of mechanical energy harvesting devices regardless of their mechanisms (piezoelectric or hybrid).

Innovative enhancement of electron tunneling synergy in carbon-doped Ta2O5CuO photocatalyst with nematic liquid crystal for safe drinking water.

This study focuses on enhancing the photocatalytic properties of carbon-doped Ta2O5CuO (C-Ta2O5CuO) nanocomposites for drinking water purification. The nanocomposites were fabricated by depositing C-Ta2O5CuO onto Nematic Liquid Crystal Polaroid (NLCP) obtained from a discarded laptop monitor, employing the sputter deposition method. The X-ray diffraction (XRD) and High-resolution transmission electron microscopy (HRTEM) determined the nanocomposite thin films' crystallinity and structural properties. The EDX and XPS analyses confirmed the elemental composition and reality of the Cu-incorporated Ta2O5 nanocomposites, respectively. The combination of electron tunneling enhancement provided by the NLCP and graphitic carbon led to exceptional photocatalytic performance. This was particularly evident in the efficient degradation of P-Rosaniline Hydrochloride (PRH) dye in an aqueous medium. C-Ta2O5CuO catalytic activities were estimated at various dye concentrations, repeatability, reusability with time, and kinetics. Coating's stability and long-term activity in photocatalysis reactions were also tested. Additionally, Cu present in the C-Ta2O5CuO and ˙OH radicals exhibited remarkable bactericidal activity. They displayed significant antibacterial efficacy against both gram-positive Escherichia coli (E. coli) and gram-negative Staphylococcus aureus (S. aureus) bacteria. These findings have significant implications for the development of advanced materials with potent photocatalytic and antibacterial properties, holding promise for improving drinking water quality and addressing environmental and health challenges.

Electroactive properties and piezo-tribo hybrid energy harvesting performances of PVDF-AlFeO3 composites: role of crystal symmetry and agglomeration of fillers.

Inorganic filler-loaded PVDF-based composites have been very widely used for electrical and energy harvesting applications in recent times. In this regard, the effects of different parameters of fillers like size, shape, chemical states, distribution, functional properties, and many others on the output performance of PVDF have been widely studied. However, the effect of another important parameter, namely the crystal symmetry of the filler, in tuning the energy harvesting performance of PVDF has been rarely explored. Therefore, to explore this fact, here we develop PVDF-based composite films by using two types of AlFeO3 fillers, one with rhombohedral R3̄c symmetry (AFRH) and another with an orthorhombic Pc21n structure. Ferrite-based oxides have been chosen here as fillers due to their good dielectric compatibility with PVDF. On the other hand, AlFeO3 has been chosen due to the simplicity of synthesizing it with both centrosymmetric and non-centrosymmetric crystal structures and the scarcity of reports exploring the energy-harvesting performance of AlFeO3-based polymer composites. A significant difference in particle agglomeration has also been observed here between the mentioned two types of AlFeO3 fillers which was mainly due to their specific synthesis conditions. The electroactive properties of PVDF have been observed to be mostly dependent on filler agglomeration. However, the crystal symmetry has shown a strong effect on the piezoelectric energy harvesting performances. As a result of these facts, the piezo-tribo hybrid energy harvesting performance, which depends on both the dielectric permittivity and piezoelectric activity, has been observed to be better for the AFRH5-based hybrid device (AFRH5H) (with ∼72 V open circuit voltage and ∼45 µW cm-2 power density) compared to that of the AFOR5-based hybrid device (AFOR5H). The real-life applications of all the energy harvesting devices have also been demonstrated here.

Sputter -coated N-enriched mixed metal oxides (Ta2O5-Nb2O5-N) composite: A resilient solar driven photocatalyst for water purification.

This study demonstrated the formation of N-enriched mixed metal oxides (Ta2O5-Nb2O5-N and Ta2O5-Nb2O5) thin film composites used as photocatalysts to degrade P-Rosaniline Hydrochloride (PRH-Dye) dye under solar radiation. By controlling the N gas flow rate during the sputtering process, the N concentration in the Ta2O5-Nb2O5-N composite is significantly included, and demonstrated by XPS and HRTEM analysis. With the help of XPS and HRTEM investigations, it was determined that the addition of N to Ta2O5-Nb2O5-N significantly enhances the active sites. The Ta-O-N bond (N 1 s and Ta 4p3/2 spectra) was verified by the XPS spectra. Ta2O5-Nb2O5 was found to have a lattice interplanar distance (d-spacing) of 2.52, whereas Ta2O5-Nb2O5-N showed the 2.5 (620 planes). A sputter-coated Ta2O5-Nb2O5and Ta2O5-Nb2O5-N photocatalysts were prepared, and their photocatalytic activity was evaluated using PRH-Dye as a model pollutant under solar radiation by adding H2O2 (0.01 mol). The photocatalytic activity of the Ta2O5-Nb2O5-N composite was compared with TiO2 (P-25) and Ta2O5-Nb2O5. Ta2O5-Nb2O5-N showed very high photocatalytic activity compared to Degussa P-25 TiO2 and Ta2O5-Nb2O5 under solar radiation and confirmed the presence of N in Ta2O5-Nb2O5-N significantly increased the generation of ˙OH radicals (in pH 3, 7 and 9). With the use of LC/MS, the stable intermediates or metabolite created during the photooxidation of PRH-Dye were assessed. The results of this study will provide useful insights on how Ta2O5-Nb2O5-N influences the efficiency of water pollution remediation.

A comprehensive review of properties of the biocompatible thin films on biodegradable Mg alloys.

Magnesium (Mg) and its alloys have attracted attention as biodegradable materials for biomedical applications owing to their mechanical properties being comparable to that of bone. Mg is a vital trace element in many enzymes and thus forms one of the essential factors for human metabolism. However, before being used in biomedical applications, the early stage or fast degradation of Mg and its alloys in the physiological environment should be controlled. The degradation of Mg alloys is a critical criterion that can be controlled by a surface modification which is an effective process for conserving their desired properties. Different coating methods have been employed to modify Mg surfaces to provide good corrosion resistance and biocompatibility. This review aims to provide information on different coatings and discuss their physical and biological properties. Finally, the current withstanding challenges have been highlighted and discussed, followed by shedding some light on future perspectives.

Biocompatibility and corrosion evaluation of niobium oxide coated AZ31B alloy for biodegradable implants.

Biodegradable magnesium (Mg) based implants have considerable interest in the biomedical field as their use nullifies the necessity for implant removal surgery and avoids the long-standing adverse reaction of permanent bioimplants. The degradation resistance and biocompatibility of the Mg alloys can be improved by coating them with a suitable thin film. Here, thin films of niobium and niobium oxide were developed on the AZ31B Mg alloy by sputtering technique and their biocompatibility and corrosion resistance was examined. X-ray diffraction (XRD) and Transmission electron microscope (TEM) techniques confirmed the crystallinity of the thin films. Subsequently, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) techniques were employed to evaluate the morphology and chemical composition of the thin film surfaces, respectively. Thin-film coated Mg alloys revealed good corrosion resistance compared to their uncoated bare counterparts in simulated body fluid (SBF). The contact angle study was performed on the coated specimens to investigate their wettability which revealed their hydrophobic character. The cell viability studies on thin-film coated specimens exhibited significant cell proliferation, and cell morphological studies showed good cell attachment and growth. The in vitro MTT assay on mouse osteoblast precursor cells (MC3T3-E1) indicated that the Nb-based coatings are cytocompatible and promote cell proliferation.

Biological performance of metal metalloid (TiCuZrPd:B) TFMG fabricated by pulsed laser deposition.

The aim of our study is to investigate the effect of boron with different ratios in Ti-Cu-Pd-Zr metallic glass (MG) matrix (Ti-Cu-Pd-Zr:B) fabricated by Pulsed Laser Deposition (PLD) for biomedical implants. The Ti based Thin Film Metallic Glasses (TFMGs) in combination with boron (in different atomic %) was assessed in attaining the combined properties, like outstanding corrosion resistant properties and good biocompatibility in this work. The disordered structure and amorphous nature of the Ti-Cu-Pd-Zr:B thin films systems were achieved by the PLD process and affirmed by XRD and transmission electron microscopy. The boron incorporation in the TFMG has been elucidated by XPS analysis. The boron containing films displays distribution of boron protuberances interleaved in the amorphous matrix was stated from SEM analysis. It is found that increase in atomic percentage of boron contents in TFMG results in the improvement in glass transition temperatures. The electrochemical parameters suggest better corrosion resistance and capabilities of passivity when boron percentage was increased in the film thereby preventing adverse biological reactions. TFMGs exhibited excellent hemocompatibility by preventing the platelet activation. MTT assay manifests increase in cell concentration with culture period on the TFMGs for the MC3T3-E1 preosteoblasts cells. Cell morphology was also studied which confirmed the viable state of the cells on the TFMG surfaces. The combination of such distinctive properties marks these TFMG systems as prospective aspirants for biomedical implants.

Influence of nanocellulose on mechanics and morphology of polyvinyl alcohol xerogels.

Xerogels are porous networks of crosslinked polymers that are useful for biomedical applications such as drug delivery, scaffold engineering, tissue regeneration, cell culture and wound dressing. However, inferior mechanical properties curtail their applications to a considerable extent. Nanocellulose fibers and crystals are often added into the polymer matrix to improve their mechanical strength. Here, nanocellulose in the mass ratios of 7%, 13% and 18% are loaded into polyvinyl alcohol (PVA) matrix followed by thermo-morpho-mechanical characterization. With increase in nanocellulose content, thermal degradation occurs at a lower temperature. It is observed that addition of higher quantity of nanocellulose crystals leads to the formation of weak cellulose-rich regions causing xerogel rupture. This is predominantly observed for xerogel loaded with 18% nanocellulose crystals. Similarly, addition of higher quantity of nanocellulose fibers increase brittleness of the xerogels causing fracture. This is predominantly observed for xerogel loaded with 18% nanocellulose fibers. Creep strain and stress relaxation is observed to decrease with addition of nanocellulose loading owing to molecular chain restriction and polymer chain immobility.

Synthesis and viscoelastic characterization of microstructurally aligned Silk fibroin sponges.

Silk fibroin (SF) is a model candidate for use in tissue engineering and regenerative medicine owing to its bio-compatible mechanochemical properties. Despite numerous advances made in the fabrication of various biomimetic substrates using SF, relatively few clinical applications have been designed, primarily due to the lack of complete understanding of its constitutive properties. Here we fabricate microstructurally aligned SF sponge using the unidirectional freezing technique wherein a novel solvent-processing technique involving Acetic acid is employed, which obviates the post-treatment of the sponges to induce their water-stability. Subsequently, we quantify the anisotropic, viscoelastic response of the bulk SF sponge samples by performing a series of mechanical tests under uniaxial compression over a wide range of strain rates. Results for these uniaxial compression tests in the finite strain regime through ramp strain and ramp-relaxation loading histories applied over two orders of strain rate magnitude show that microstructural anisotropy is directly manifested in the bulk viscoelastic solid-like response. Furthermore, the experiments reveal a high degree of volume compressibility of the sponges during deformation, and also evince for their remarkable strain recovery capacity under large compressive strains during strain recovery tests. Finally, in order to predict the bulk viscoelastic material properties of the fabricated and pre-characterized SF sponges, a finite strain kinematics-based, nonlinear, continuum model developed within a thermodynamically-consistent framework in a parallel investigation, was successfully employed to capture the viscoelastic solid-like, transversely isotropic, and compressible response of the sponges macroscopically.