Efficient Photocatalytic Luminous Textile for Simulated Real Water Purification: Advancing Economical and Compact Reactors.

The growing worldwide problem of wastewater management needs sustainable methods for conserving water supplies while addressing environmental and economic considerations. With the depletion of freshwater supplies, wastewater treatment has become critical. An effective solution is needed to efficiently treat the organic contaminants departing from wastewater treatment plants (WWTPs). Photocatalysis appears to be a viable method for eliminating these recalcitrant micropollutants. This study is focused on the degradation of Reactive Black 5 (RB5), a typical contaminant from textile waste, using a photocatalytic method. Titanium dioxide (TiO2) was deposited on a novel luminous fabric and illuminated using a light-emitting diode (LED). The pollutant degrading efficiency was evaluated for two different light sources: (i) a UV lamp as an external light source and (ii) a cold LED. Interestingly, the LED UV source design showed more promising results after thorough testing at various light levels. In fact, we note a 50% increase in mineralization rate when we triple the number of luminous tissues in the same volume of reactor, which showed a clear improvement with an increase in compactness.

Experimental Analysis and Neural Network Modeling of the Rheological Behavior of Xanthan Gum and Its Derivatives.

The main objective of this study was to create a mathematical tool that could be used with experimental data to predict the rheological flow behavior of functionalized xanthan gum according to the types of chemical groups grafted onto its backbone. Different rheological and physicochemical analyses were applied to assess six derivatives synthesized via the etherification of xanthan gum by hydrophobic benzylation with benzyl chloride and carboxymethylation with monochloroacetic acid at three (regent/polymer) ratios R equal to 2.4 and 6. Results from the FTIR study verified that xanthan gum had been modified. The degree of substitution (DS) values varying between 0.2 and 2.9 for carboxymethylxanthan gum derivatives were found to be higher than that of hydrophobically modified benzyl xanthan gum for which the DS ranged from 0.5 to 1. The molecular weights of all the derivatives were found to be less than that of xanthan gum for the two types of derivatives, decreasing further as the degree of substitution (DS) increased. However, the benzyl xanthan gum derivatives presented higher molecular weights varying between 1,373,146 (g/mol) and 1,262,227 (g/mol) than carboxymethylxanthan gum derivatives (1,326,722-1,015,544) (g/mol). A shear-thinning behavior was observed in the derivatives, and the derivatives' viscosity was found to decrease with increasing DS. The second objective of this research was to create an ANN model to predict one of the rheological properties (the apparent viscosity). The significance of the ANN model (R2 = 0.99998 and MSE = 5.95 × 10-3) was validated by comparing experimental results with the predicted ones. The results showed that the model was an efficient tool for predicting rheological flow behavior.