Formation of Natural Magnesium Silica Hydrate (M-S-H) and Magnesium Alumina Silica Hydrate (M-A-S-H) Cement.

Occurrences of natural magnesium alumina silicate hydrate (M-(A)-S-H) cement are present in Feragen and Leka, in eastern and western Trøndelag Norway, respectively. Both occurrences are in the subarctic climate zone and form in glacial till and moraine material deposited on ultramafic rock during the Weichselian glaciation. Weathering of serpentinized peridotite dissolves brucite and results in an alkaline fluid with a relatively high pH which subsequently reacts with the felsic minerals of the till (quartz, plagioclase, K-feldspar) to form a cement consisting of an amorphous material or a mixture of nanocrystalline Mg-rich phyllosilicates, including illite. The presence of plagioclase in the till results in the enrichment of alumina in the cement, i.e., forms M-A-S-H instead of the M-S-H cement. Dissolution of quartz results in numerous etch pits and negative quartz crystals filled with M-A-S-H cement. Where the quartz dissolution is faster than the cement precipitation, a honeycomb-like texture is formed. Compositionally, the cemented till (tillite) contains more MgO and has a higher loss of ignition than the till, suggesting that the cement is formed by a MgO fluid that previously reacted with the peridotite. The M-(A)-S-H cemented till represents a new type of duricrust, coined magsilcrete. The study of natural Mg cement provides information on peridotites as a Mg source for Mg cement and as a feedstock for CO2 sequestration.

Dynamic earthquake rupture in the lower crust.

Earthquakes in the continental crust commonly occur in the upper 15 to 20 km. Recent studies demonstrate that earthquakes also occur in the lower crust of collision zones and play a key role in metamorphic processes that modify its physical properties. However, details of the failure process and sequence of events that lead to seismic slip in the lower crust remain uncertain. Here, we present observations of a fault zone from the Bergen Arcs, western Norway, which constrain the deformation processes of lower crustal earthquakes. We show that seismic slip and associated melting are preceded by fracturing, asymmetric fragmentation, and comminution of the wall rock caused by a dynamically propagating rupture. The succession of deformation processes reported here emphasize brittle failure mechanisms in a portion of the crust that until recently was assumed to be characterized by ductile deformation.

Earthquakes track subduction fluids from slab source to mantle wedge sink.

Subducting plates release fluids as they plunge into Earth's mantle and occasionally rupture to produce intraslab earthquakes. It is debated whether fluids and earthquakes are directly related. By combining seismic observations and geodynamic models from western Greece, and comparing across other subduction zones, we find that earthquakes effectively track the flow of fluids from their slab source at >80 km depth to their sink at shallow (<40 km) depth. Between source and sink, the fluids flow updip under a sealed plate interface, facilitating intraslab earthquakes. In some locations, the seal breaks and fluids escape through vents into the mantle wedge, thereby reducing the fluid supply and seismicity updip in the slab. The vents themselves may represent nucleation sites for larger damaging earthquakes.

High Pressure Metamorphism Caused by Fluid Induced Weakening of Deep Continental Crust.

Studies of mineral equilibria in metamorphic rocks have given valuable insights into the tectonic processes operating at convergent plate margins during an orogeny. Geodynamic models simulating orogenesis and crustal thickening have been constrained by temperature and pressure estimates inferred from the mineral assemblages of the various lithologies involved along with age constrains from increasingly precise geochronological techniques. During such studies it is assumed that the pressure experienced by a given rock is uniquely related to its depth of burial. This assumption has been challenged by recent studies of high pressure (HP) and ultrahigh pressure (UHP) rocks. Here, we describe an example of Caledonian HP metamorphism from the Bergen Arcs in western Norway, and show that the associated formation of Caledonian eclogites at the expense of Proterozoic granulites was related to local pressure perturbations rather than burial, and that the HP metamorphism resulted from fluid-induced weakening of an initially dry and highly stressed lower crust when thrust upon the hyperextended margin of the Baltic shield.

Earthquake-induced transformation of the lower crust.

The structural and metamorphic evolution of the lower crust has direct effects on the lithospheric response to plate tectonic processes involved in orogeny, including subsidence of sedimentary basins, stability of deep mountain roots and extension of high-topography regions. Recent research shows that before orogeny most of the lower crust is dry, impermeable and mechanically strong 1 . During an orogenic event, the evolution of the lower crust is controlled by infiltration of fluids along localized shear or fracture zones. In the Bergen Arcs of Western Norway, shear zones initiate as faults generated by lower-crustal earthquakes. Seismic slip in the dry lower crust requires stresses at a level that can only be sustained over short timescales or local weakening mechanisms. However, normal earthquake activity in the seismogenic zone produces stress pulses that drive aftershocks in the lower crust 2 . Here we show that the volume of lower crust affected by such aftershocks is substantial and that fluid-driven associated metamorphic and structural transformations of the lower crust follow these earthquakes. This provides a 'top-down' effect on crustal geodynamics and connects processes operating at very different timescales.

Peridotite weathering is the missing ingredient of Earth's continental crust composition.

The chemical composition of the continental crust cannot be adequately explained by current models for its formation, because it is too rich in Ni and Cr compared to that which can be generated by any of the proposed mechanisms. Estimates of the crust composition are derived from average sediment, while crustal growth is ascribed to amalgamation of differentiated magmatic rocks at continental margins. Here we show that chemical weathering of Ni- and Cr-rich, undifferentiated ultramafic rock equivalent to ~1.3 wt% of today's continental crust compensates for low Ni and Cr in formation models of the continental crust. Ultramafic rock weathering produces a residual that is enriched in Ni and also silica. In the light of potentially large volumes of ultramafic rock and high atmospheric CO2 concentrations during the Archean, chemical weathering must therefore have played a major role in forming compositionally evolved components of the early Earth's crust.

Fragmentation of wall rock garnets during deep crustal earthquakes.

Fractures and faults riddle the Earth's crust on all scales, and the deformation associated with them is presumed to have had significant effects on its petrological and structural evolution. However, despite the abundance of directly observable earthquake activity, unequivocal evidence for seismic slip rates along ancient faults is rare and usually related to frictional melting and the formation of pseudotachylites. We report novel microstructures from garnet crystals in the immediate vicinity of seismic slip planes that transected lower crustal granulites during intermediate-depth earthquakes in the Bergen Arcs area, western Norway, some 420 million years ago. Seismic loading caused massive dislocation formations and fragmentation of wall rock garnets. Microfracturing and the injection of sulfide melts occurred during an early stage of loading. Subsequent dilation caused pervasive transport of fluids into the garnets along a network of microfractures, dislocations, and subgrain and grain boundaries, leading to the growth of abundant mineral inclusions inside the fragmented garnets. Recrystallization by grain boundary migration closed most of the pores and fractures generated by the seismic event. This wall rock alteration represents the initial stages of an earthquake-triggered metamorphic transformation process that ultimately led to reworking of the lower crust on a regional scale.