RESUMO
Side by side air sampling was conducted using a PTFE filter membrane as dry sampler and an impinger containing a suitable culture medium as a wet sampler. Most of the samples were collected from two hospitals and few air samples were collected from private houses of non-hospitalized confirmed COVID-19 patients. The collected air samples were analyzed using RT-PCR. The results indicated that all air samples collected from the hospitals were PCR negative for SARS-CoV-2. While two of four air samples collected from the house of non-hospitalized patients were PCR positive. In this study, most of the hospitalized patients had oxygen mask and face mask, and hence this may be a reason for our negative results regarding the presence of SARS-CoV-2 in indoor air of the hospitals, while non-hospitalized patients did not wear oxygen and protective face masks in their houses. Moreover, a very high concentration of particles in the size range of droplet nuclei (< 5 µm) was identified compared to particles in the size range of respiratory droplets (> 5-10 µm) in the areas where patients were hospitalized. It can be concluded that using face mask by patients can prevent the release of viruses into the indoor air, even in hospitals with a high density of patients.
Assuntos
Poluição do Ar em Ambientes Fechados , COVID-19 , Hospitais , Humanos , Oxigênio , SARS-CoV-2RESUMO
A wide variety of methods have been applied in indoor air to reduce the microbial load and reduce the transmission rate of acute respiratory diseases to personnel in healthcare sittings. In recent months, with the occurrence of COVID-19 pandemic, the role of portable ventilation systems in reducing the load of virus in indoor air has received much attention. The present study delineates a comprehensive up-to-date overview of the available photocatalysis technologies that have been applied for inactivating and removing airborne viruses. The detection methods for identifying viral particles in air and the main mechanisms involving in virus inactivation during photocatalysis are described and discussed. The photocatalytic processes could effectively decrease the load of viruses in indoor air. However, a constant viral model may not be generalizable to other airborne viruses. In photocatalytic processes, temperature and humidity play a distinct role in the inactivation of viruses through changing photocatalytic rate. The main mechanisms for inactivation of airborne viruses in the photocatalytic processes included chemical oxidation by the reactive oxygen species (ROS), the toxicity of metal ions released from metal-containing photocatalysts, and morphological damage of viruses.
Assuntos
Poluição do Ar em Ambientes Fechados , COVID-19 , Vírus , Humanos , Pandemias , SARS-CoV-2RESUMO
Providing clean and safe drinking water by point of use (POU) disinfection methods has become a critical issue, especially in crises and epidemics. In this study, antimony-and nickel-doped tin oxide electrode (Ni-Sb-SnO2) was employed as an electrode for electro-catalytic disinfection of surface water. The synthetized electrodes were characterized using scanning electron microscope, linear sweep voltammetry and X-Ray diffraction techniques. The results revealed that the highest electrochemical disinfection efficiency was achieved by the Ni-Sb-SnO2 electrode under weak acidic conditions and its performance decreased with increasing pH towards alkaline environment. Based on the results, total coliform (TC) and fecal coliform (FC) were completely removed at current density of 0.67 mA cm-2. Moreover, the electrochemical disinfection of microorganisms showed that the process efficiency was directly proportional to increasing time and at 0.6 C cm-2 of charge passed, 3-log removal of the both indicators occurred after 15 min. The highest removal efficiency of TC and FC was also achieved at 8 mmol of NaCl concentration at <10 min of detention time. The results of this study depicted that the Ti/Ni-Sb-SnO2 electrode provides higher disinfection efficiency for the removal of TC and FC compared with Ti and SS/PbO2 electrodes. Moreover, the proposed system was able to completely eliminate heterotrophic, Streptococcus faecalis and Pseudomonas aerogenes indicators under optimal conditions. Therefore, it can be concluded that the proposed electrochemical system can be efficiency applied as a POU disinfection system for disinfection of water contaminated with microbial indicators, especially for crises and epidemics.
Assuntos
Poluentes Químicos da Água , Purificação da Água , Antimônio , Bactérias , Eletrodos , Níquel , Oxirredução , Compostos de Estanho , Titânio , ÁguaRESUMO
Severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) is a strain of coronaviruses that causes coronavirus disease 2019 (COVID-19). In these days, the spread of the SARS-CoV-2 virus through the air has become a controversial topic among scientists. Various organizations provide standard methods for monitoring biological agents in the air. Nevertheless, there has been no standard recommended method for sampling and determination of viruses in air. This manuscript aimed at reviewing published papers for sampling and detection of corona viruses, especially SARS-Cov-2 as a global health concern. It was found that SARS-Cov 2 was present in some air samples that were collected from patient's rooms in hospitals. This result warrants its airborne transmission potential. However, due to the fact that in the most reviewed studies, sampling was performed in the patient's room, it seems difficult to discriminate whether it is airborne or is transmitted through respiratory droplets. Moreover, some other disrupting factors such as patient distance from the sampler, using protective or oxygen masks by patients, patient activities, coughing and sneezing during sampling time, air movement, air conditioning, sampler type, sampling conditions, storage and transferring conditions, can affect the results. About the sampling methods, most of the used samplers such as PTFE filters, gelatin filers and cyclones showed suitable performance for trapping SARS-Co and MERS-Cov viruses followed by PCR analysis.
Assuntos
Infecções por Coronavirus/epidemiologia , Pandemias , Pneumonia Viral/epidemiologia , Betacoronavirus , COVID-19 , Humanos , SARS-CoV-2RESUMO
In this work, the efficiencies of Fenton catalytic and sonolysis processes were investigated separately and in combination together for the treatment and reduction of sludge volume. Moreover, the effects of operating parameters such as retention time, initial pH, iron concentration, and H2O2 concentration on COD reduction as well as the proportion of volatile solids to total solids (VS/TS) were studied. Finally, the effects of these processes on the sludge volume index (SVI) and sludge volume reduction (SVR) were evaluated. According to the results, the retention time of 60â¯min, pHâ¯=â¯3, hydrogen peroxide concentration of 0.13â¯M/L, and iron concentration of 2â¯mM/L were achieved as the optimum values. Furthermore, the SVR and SVI removal efficiencies in the Fenton process were 19% and 25%, respectively, but the removal efficiency in sonolysis process was very low and can be ignored. Under optimum conditions in sono-Fenton (SF) process, the SVR and SVI removal efficiencies were 55.7% and 83%, respectively. The results showed that by combining sonolysis and Fenton processes; due to the synergistic effect of ultrasonic waves, Fenton agent, and the production of more hydroxyl radicals; the COD removal efficiency increased to 77%, and the proportion of VS/TS in row activated sludge was reduced from 75% to 26%. Generally, by combining sonolysis and Fenton processes, the removal efficiency increased significantly as compared to separate processes owing to the production of more oxidizing agents and improving mass transfer.
Assuntos
Oxirredução , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Análise Custo-Benefício , Peróxido de Hidrogênio/metabolismo , Concentração de Íons de Hidrogênio , Ferro/metabolismo , Água/químicaRESUMO
BACKGROUND: Electrochemical methods, as one of the advanced oxidation processes (AOPs), have recently been applied to remove different contaminants from water and wastewater. This study compares the performance of anodic oxidation (AO) and electro-Fenton (EF) methods on waste sludge treatment. METHODS: This experimental study was performed on real sludge and the effect of operating parameters such as solution pH, operating time, current density, supporting electrolyte and hydrogen peroxide concentration were investigated in a batch reactor. For determination of oxidation and treatability of the sludge, chemical oxygen demand (COD) and total coliform (TC) removal were examined. Pb/PbO2 and iron electrodes respectively for AO and EF were applied. RESULTS: Experimental data indicated for both AO and EF as the operating time and current density increased, COD removal increased. pH=4.0 and 3.0 and current density=1.75 and 2 A respectively for AO and EF and the concentration = 57.2 mMol of hydrogen peroxide for EF were measured as the optimum amounts of these variables. The removal efficiency of COD in AO and EF process was 76% and 72%, respectively. Of course, the efficiency of EF in TC removal was better and the percentage of TC removal in 60 min for AO and EF was 99.0% and 99.9%, respectively. The amounts of consumed electrical energy for AO and EF were 8.6 and 28.0 kWh kg-1 COD, respectively. CONCLUSIONS: AO was more effective in treatment and mineralization of waste sludge and TC removal than EF in terms of environmental economical features.