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1.
ACS Environ Au ; 3(5): 308-318, 2023 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-37743952

RESUMO

Developing advanced onsite wastewater treatment systems (OWTS) requires accurate and consistent water quality monitoring to evaluate treatment efficiency and ensure regulatory compliance. However, off-line parameters such as chemical oxygen demand (COD), total suspended solids (TSS), and Escherichia coli (E. coli) require sample collection and time-consuming laboratory analyses that do not provide real-time information of system performance or component failure. While real-time COD analyzers have emerged in recent years, they are not economically viable for onsite systems due to cost and chemical consumables. This study aimed to design and implement a real-time remote monitoring system for OWTS by developing several multi-input and single-output soft sensors. The soft sensor integrates data that can be obtained from well-established in-line sensors to accurately predict key water quality parameters, including COD, TSS, and E. coli concentrations. The temporal and spatial water quality data of an existing field-tested OWTS operated for almost two years (n = 56 data points) were used to evaluate the prediction performance of four machine learning algorithms. These algorithms, namely, partial least square regression (PLS), support vector regression (SVR), cubist regression (CUB), and quantile regression neural network (QRNN), were chosen as candidate algorithms for their prior application and effectiveness in wastewater treatment predictions. Water quality parameters that can be measured in-line, including turbidity, color, pH, NH4+, NO3-, and electrical conductivity, were selected as model inputs for predicting COD, TSS, and E. coli. The results revealed that the trained SVR model provided a statistically significant prediction for COD with a mean absolute percentage error (MAPE) of 14.5% and R2 of 0.96. The CUB model provided the optimal predictive performance for TSS, with a MAPE of 24.8% and R2 of 0.99. None of the models were able to achieve optimal prediction results for E. coli; however, the CUB model performed the best with a MAPE of 71.4% and R2 of 0.22. Given the large fluctuation in the concentrations of COD, TSS, and E. coli within the OWTS wastewater dataset, the proposed soft sensor models adequately predicted COD and TSS, while E. coli prediction was comparatively less accurate and requires further improvement. These results indicate that although water quality datasets for the OWTS are relatively small, machine learning-based soft sensors can provide useful predictive estimates of off-line parameters and provide real-time monitoring capabilities that can be used to make adjustments to OWTS operations.

2.
ACS Environ Au ; 3(4): 209-222, 2023 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-37483306

RESUMO

Achieving safely managed sanitation and resource recovery in areas that are rural, geographically challenged, or experiencing rapidly increasing population density may not be feasible with centralized facilities due to space requirements, site-specific concerns, and high costs of sewer installation. Nonsewered sanitation (NSS) systems have the potential to provide safely managed sanitation and achieve strict wastewater treatment standards. One such NSS treatment technology is the NEWgenerator, which includes an anaerobic membrane bioreactor (AnMBR), nutrient recovery via ion exchange, and electrochlorination. The system has been shown to achieve robust treatment of real waste for over 100 users, but the technology's relative life cycle sustainability remains unclear. This study characterizes the financial viability and life cycle environmental impacts of the NEWgenerator and prioritizes opportunities to advance system sustainability through targeted improvements and deployment. The costs and greenhouse gas (GHG) emissions of the NEWgenerator (general case) leveraging grid electricity were 0.139 [0.113-0.168] USD cap-1 day-1 and 79.7 [55.0-112.3] kg CO2-equiv cap-1 year-1, respectively. A transition to photovoltaic-generated electricity would increase costs to 0.145 [0.118-0.181] USD cap-1 day-1 but decrease GHG emissions to 56.1 [33.8-86.2] kg CO2-equiv cap-1 year-1. The deployment location analysis demonstrated reduced median costs for deployment in China (-38%), India (-53%), Senegal (-31%), South Africa (-31%), and Uganda (-35%), but at comparable or increased GHG emissions (-2 to +16%). Targeted improvements revealed the relative change in median cost and GHG emissions to be -21 and -3% if loading is doubled (i.e., doubled users per unit), -30 and -12% with additional sludge drying, and +9 and -25% with the addition of a membrane contactor, respectively, with limited benefits (0-5% reductions) from an alternative photovoltaic battery, low-cost housing, or improved frontend operation. This research demonstrates that the NEWgenerator is a low-cost, low-emission NSS treatment technology with the potential for resource recovery to increase access to safe sanitation.

3.
J Environ Manage ; 296: 112921, 2021 Oct 15.
Artigo em Inglês | MEDLINE | ID: mdl-34303262

RESUMO

Globally, there is a dire need for a new class of advanced non-sewered sanitation systems (NSSS) to provide onsite wastewater treatment that is capable of meeting stringent discharge or reuse criteria. These systems need to be simple to operate and maintain, reliable, and resilient to unreliable electrical service. The NEWgenerator (NG) is a compact, automated, solar-powered wastewater treatment system comprised of three major treatment processes: anaerobic membrane bioreactor (AnMBR), nutrient capture system (NCS) with ion exchange and carbon sorption, and electrochlorination (EC). The NG system operated at an informal settlement community in South Africa over a 534 d period, treating high-strength blackwater (BW) and yellow water (YW) from a public toilet facility. Over three test stages (BW, BW + YW, BW) that included several periods of dormancy, the NG system was able to provide a high level of removal of total suspended solids (97.6 ± 3.1%), chemical oxygen demand (94.5 ± 5.0%), turbidity (96.3 ± 9.7%), color (92.0 ± 10.5%), total nitrogen (82.1 ± 24.0%), total phosphorus (43.0 ± 22.1%), E. coli (7.4 ± 1.5 LRV, not detected in effluent), and helminth ova (not detected in effluent). The treatment levels met most of the ISO 30500 NSSS standard for liquid effluent and local water reuse criteria. A series of maintenance events were successfully conducted onsite over the 534 d field trial: two membrane cleanings, two NCS regenerations, and granular activated carbon replacement. Desludging, a major pain point for onsite sanitation systems, was unnecessary during the field trial and thereby not performed. The AnMBR performed well, removing 94.5 ± 5.0% of the influent COD across all three stages. The high COD removal rate is attributed to the sub-micron separation provided by the ultrafiltration membrane. The NCS was highly efficient at removing total nitrogen, residual COD and color, but the regeneration process was lengthy and is a topic of ongoing research. The EC provided effective disinfection, but frequent prolonged run cycles due to power supply and water quality issues upstream limited the overall system hydraulic throughput. This extended field trial under actual ambient conditions successfully demonstrated the feasibility of using advanced NSSS to address the global water and sanitation crises.


Assuntos
Saneamento , Eliminação de Resíduos Líquidos , Análise da Demanda Biológica de Oxigênio , Reatores Biológicos , Escherichia coli , África do Sul , Águas Residuárias
4.
Membranes (Basel) ; 11(6)2021 May 31.
Artigo em Inglês | MEDLINE | ID: mdl-34072658

RESUMO

A lab-scale (6.2 L) anaerobic membrane bioreactor combined with a tubular, cross-flow, PVDF ultrafiltration membrane was developed and operated to assess the long-term fouling behavior of a cyclically operated anaerobic membrane bioreactor (AnMBR). The AnMBR was operated at 35 ± 1 °C for 200 days with a synthetic influent of 501 mg·L-1 COD to mimic municipal wastewater. The system exhibited high treatment performance with an average COD removal efficiency of 86.5 ± 6.4% (n = 20) and an average permeate COD concentration of 63.9 ± 31.1 mg·L-1. A clear permeate with an average turbidity of 0.6 ± 0.2 NTU, was achieved. Permeate TN and TP concentrations were 22.7 ± 5.1 mg·L-1 and 6.9 ± 2.0 mg·L-1 corresponding to removal efficiencies of 20.6% and 49.3%, respectively, likely due to membrane rejection of particulate, colloidal, and organic fractions. A stable membrane flux of 4.3 L.m-2.h-1 (LMH) was maintained for 183 days without gas-lift, gas sparge, or chemical cleaning. Cyclical operation with frequent relaxation (60 s for every 30 min of the permeate production run) and periodic permeate backwash (15 s for every 186 min) maintained stable membrane operation with an average TMP of 0.25 bar and a fouling rate of 0.007 kPa/h for the entire operating period. The comparison revealed frequent backwashing and relaxation is a sustainable strategy for operation of the AnMBR.

6.
Water Sci Technol ; 72(9): 1543-51, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-26524445

RESUMO

Slums are challenging locations for sanitation technologies. High population densities, a lack of water and electricity infrastructure, and space constraints combine to ensure that many traditional waste treatment technologies fail when implemented in this context. This paper proposes the use of anaerobic membrane bioreactors (AnMBRs) for slum sanitation. AnMBRs allow for localized water reuse, high quality treatment, and energy production at the point of treatment. A water, energy, nutrient, and mass balance was conducted on a theoretical AnMBR directly coupled to a public toilet. The combined system would be capable of recycling its water for use in toilet flushing and would be capable of providing enough energy to power both the toilet and AnMBR operation. The addition of food waste to the feed would help to ensure process stability and energy production by the AnMBR. Ammonia accumulation within the system would have to be managed through struvite precipitation, ion exchange, oxidation, plant uptake or other means. Generated biogas can be converted into heat and/or electricity using small scale gas generators. AnMBR technology has high potential for success in slum settings, if considerations for maintenance and supplies are made as part of the design and system delivery.


Assuntos
Reatores Biológicos , Áreas de Pobreza , Reciclagem , Banheiros/estatística & dados numéricos , Gerenciamento de Resíduos , Anaerobiose , Cidades , Estudos de Viabilidade , Humanos , Membranas Artificiais , Saneamento , Água
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