Coupled photochemical-biological system to treat biorecalcitrant wastewater.

The aim of the present work is to study a coupled system to treat biorecalcitrant wastewaters. The combination consists of an advanced oxidation process (AOP) named photo-Fenton (Ph-F), which is a photochemical treatment and a sequencing batch biofilter reactor (SBBR). The synthetic wastewater used to optimise this process is a solution of 200 ppm of 4-chlorophenol (4-CP). The first part of the work is the study of the biodegradability enhancement achieved by the photochemical process, measured as the ratio between the biochemical oxygen demand (BOD5) and the chemical oxygen demand (COD). The second step is the start-up and optimisation of the biological process. The results showed that it is necessary to severely treat the toxic solution (with 500 ppm of [H2O2]0) in order to achieve more than 90% of TOC removal in the whole process. The photochemical and biological treatments lasted 50 minutes and 24 hours, respectively.

Approach to TiO2-light interaction in heterogeneous photocatalysis.

Photocatalysis can be a useful tool in the treatment of some recalcitrant and toxic pollutants. In fact, it is being applied today in several industrial processes. However some problems arise in the modelling of photocatalytic systems, most of them related to the radiation field. In this work, some methods are presented which can be powerful tools in the evaluation of the radiation absorbed by the photocatalyst, which is the energy really useful in promoting the photocatalytic process. All these methods are based on actinometric procedures carried out in different experimental conditions and using different photoreactors.