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1.
Chemosphere ; 354: 141702, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38490618

RESUMO

Removal of toxic dyes such as Rhodamine B is essential as it pollutes aqueous and soil streams as well. This comprehensive study explores the potential of Calophyllum inophyllum seed char as an efficient bio-adsorbent based on their characteristic properties and a comparative study between various carbon-based adsorbents on the adsorption capacity of Rhodamine B dye. In this study, the char was prepared from Calophyllum inophyllum seed using a slow pyrolysis process (298 K/min) at an optimum temperature of 823 K and used as an adsorbent for the removal of Rhodamine B from water. The resulting char was mesoporous and had 155.389 m2/g surface areas (BET) and 0.628 cc/g pore volume. The formation of pores was observed from the SEM analysis. The adsorption studies were tested and optimized through various parameters such as solution pH, adsorbent dosage, initial dye concentration, stirring speed, contact time, and solution temperature. Maximum 95.5 % removal of Rhodamine B was possible at the pH: 2, stirring speed: 100 rpm, time: 25 min, temperature 308 K, and dose: 1.2 g/L. The highest adsorption capacity at equilibrium was determined to be 169.5 (mg/g) through Langmuir adsorption isotherm studies and followed pseudo 2nd order kinetics. The thermodynamics study confirmed the adsorption processes were spontaneous (ΔG°=-0.735 kJ/mol) and endothermic (ΔH° = 4.1 kJ/mol) processes. The reusability study confirmed that the mesoporous char can be reused as an efficient adsorbent for up to 3 cycles for environmental remediation.


Assuntos
Carvão Vegetal , Corantes , Rodaminas , Poluentes Químicos da Água , Corantes/análise , Adsorção , Poluentes Químicos da Água/análise , Concentração de Íons de Hidrogênio , Termodinâmica , Água/química , Cinética
2.
Database (Oxford) ; 20232023 10 16.
Artigo em Inglês | MEDLINE | ID: mdl-37847815

RESUMO

Medicinal plants are anticipated to be one of the most valuable resources for the remedial usage in the treatment of various ailments. The data on key medicinal plants and their therapeutic efficacy against various ailments are quite scattered and not available on a single platform. Moreover, currently there is no means/mechanism of finding the best medicinal plant(s) from numerous plants known to cure any disease. DISPEL (Diseases Plants Eliminate) is a compendium of medicinal plants available across the world that are used to cure infectious as well as non-infectious diseases in humans. The association of a medicinal plant with a disease it cures is hereby referred to as 'medicinal plant-disease cured' linkage. The DISPEL database hosts ∼60 000 'medicinal plant-disease cured' linkages encompassing ∼5500 medicinal plants and ∼1000 diseases. This platform provides interactive and detailed visualization of medicinal plants, diseases and their relations using comprehensible network graph representation. The user has the freedom to search the database by specifying the name of disease(s) as well as the scientific/common name(s) of plant. Each 'medicinal plant-disease cured' relation is scored based on the availability of any medicine/product derived from that medicinal plant, information about active compound(s), knowledge regarding the part of plant that is effective and number of distinct articles/books/websites confirming the effectiveness of the medicinal plant. The user can find the best plant(s) that can be used to cure any desired disease(s). The DISPEL database is the first step towards generating the 'most-effective' combination of plants to cure a disease since it delineates as well as ranks all the therapeutic medicinal plants for that disease. The combination of best medicinal plants can then be used to conduct clinical trials and thus pave the way for their use in clinics for treatment of diseases. Database URL https://compbio.iitr.ac.in/dispel.


Assuntos
Plantas Medicinais , Humanos , Fitoterapia
3.
Environ Pollut ; 312: 120019, 2022 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-36037850

RESUMO

This study investigates a comparison between the photocatalytic action of two nanocomposites (TiO2 and TiO2(Ag) doped) on the degradation of phenol from water. The nanocomposites were synthesized by the UV photo-reduction process to get a silver metal loading of 0.25, 0.5, 0.75, and 1% (w/w). In addition to this, Eriochrome Cyanine Red (ECR) and Eosin Yellow (EY) both anionic dyes were used for sensitization of Ag-doped TiO2 photo-catalyst such as TiO2(Ag)ECR and TiO2(Ag)EY. The TiO2(Ag-1.0)EY photo-catalyst indicated higher absorbance compared to the TiO2(Ag-1.0)ECR in the 400-700 nm range (visible range). The degradation of phenol was tested by varying the pH, silver loading and catalyst dosage. The maximum degradation of phenol was 98% in 180 min at pH 7 in presence of 1% (w/w) silver loading with 0.5 gL-1 dosage of photo-catalyst TiO2(Ag-1.0)EY. At this condition, the reduction in the phenol concentration was noticed from 20 mg/L to 0.4 mg/L.


Assuntos
Nanocompostos , Prata , Compostos Azo , Catálise , Corantes , Amarelo de Eosina-(YS) , Naftalenossulfonatos , Fenol , Titânio , Água
4.
J Parasit Dis ; 45(4): 1077-1083, 2021 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-34789992

RESUMO

Two distinct morphologies of Cymothoidae isopod, Lobothorax typus were collected from the marine water of Bay of Bengal, Goapalpur-on-Sea as the first record of this parasite from coastal water of Odisha, India. All specimens were found attached to the buccal region of different individuals of the same host fish Trichiurus lepturus. With the aid of COI gene sequencing and morphological analysis, the individuals were found to be conspecific. The most prominent variation among the two morphologies includes the size of 5th pereonite and pleon length to total body length ratio. These variations are as a result of the biphasic moulting process. Maximum Likelihood tree analysis based on COI gene sequences concluded the monophyletic taxonomy of different buccal attaching genera under the family Cymothoidae which is in congruence with their morphological divergence.

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