Substituents Regulate the Cyclization of Conjugated Alkynes to Accurately Construct Cyclo-(E)-[3]dendralenes.

Substituent-regulated cyclization of conjugated alkynes with acid catalysis was developed in this paper, and it provides a straightforward synthesis of cyclic-(E)-[3]dendralenes. Depending on the electronic effect of the aromatic ring pairing, a variety of phosphinyl quintuplet/hexa cyclo-[3]dendralenes with diverse substitution patterns are accessible, with good efficiency and high stereoselectivity. This self-cyclization process achieves the first precise construction of a phosphinylcyclo-(E)-[3]dendralene from conjugated alkynes to aromatization.

Failure Analysis of Abnormal Cracking of the Track Circuit Reader Antenna Baffle for High-Speed Trains.

The track circuit reader (TCR) is an important part of train control systems. This paper reports a failure of the TCR antenna baffle, which is used to prevent the TCR antenna from being struck by foreign objects. The designed service life of the baffle is 4.8 million kilometers, but serious cracking was found during routine maintenance after only 0.67 million kilometers of operation. In order to avoid the hidden danger brought by the incident to the safe operation of the train, it is necessary to conduct a complete failure analysis of the failed TCR antenna baffle. Therefore, a comprehensive investigation of the base material, cleaning agents, crack morphologies, etc., was carried out, and the failure environment of the antenna baffle was verified by experiment. The final results show that the environmental stress cracking is the root cause of the failed antenna baffle, and the multiple bubbles produced by the formed process of the antenna baffle are another important cause. According to the conclusions, the solutions to prevent the reoccurrence of such failures are proposed. After these solutions are adopted, the number of failed antenna baffles is greatly reduced, which fully proves the correctness of this analysis.