Dual-comb spectroscopy using plasmon-enhanced-waveguide dispersion-compensated quantum cascade lasers.

In this Letter, we report on sub-millisecond response time mid-infrared dual-comb spectroscopy using a balanced asymmetric (dispersive) dual-comb setup with a matched pair of plasmon-enhanced-waveguide dispersion-compensated quantum cascade lasers. The system performance is demonstrated by measuring spectra of Bromomethane (CH3Br) and Freon 134a (CH2FCF3) at approximately 7.8 µm. A purely computational phase and timing-correction procedure is used to validate the coherence of the quantum cascade lasers frequency combs and to enable coherent averaging over the time scales investigated. The system achieves a noise-equivalent absorption better than 1×10-3 Hz-1/2, with a resolution of 9.8 GHz (0.326 cm-1) and an optical bandwidth of 1 THz (32 cm-1), with an average optical power of more than 1 mW per spectral element.

Frequency stability of a dual wavelength quantum cascade laser.

We characterized the dual wavelength operation of a distributed Bragg reflector (DBR) quantum cascade laser (QCL) operating at 4.5 µm using two independent optical frequency discriminators. The QCL emits up to 150 mW fairly evenly distributed between two adjacent Fabry-Perot modes separated by ≈11.6 GHz. We show a strong correlation between the instantaneous optical frequencies of the two lasing modes, characterized by a Pearson correlation coefficient of 0.96. As a result, we stabilized one laser mode of the QCL to a N2O transition using a side-of-fringe locking technique, reducing its linewidth by a factor 6.2, from 406 kHz in free-running operation down to 65 kHz (at 1-ms observation time), and observed a simultaneous reduction of the frequency fluctuations of the second mode by a similar amount, resulting in a linewidth narrowing by a factor 5.4, from 380 kHz to 70 kHz. This proof-of-principle demonstration was performed with a standard DBR QCL that was not deliberately designed for dual-mode operation. These promising results open the door to the fabrication of more flexible dual-mode QCLs with the use of specifically designed gratings in the future.

Plasmon-enhanced waveguide for dispersion compensation in mid-infrared quantum cascade laser frequency combs.

We demonstrate dispersion compensation in mid-infrared quantum cascade laser frequency combs (FCs) emitting at 7.8 µm using the coupling of a dielectric waveguide to a plasmonic resonance in the top cladding layer of the latter. Devices with group velocity dispersion lower than 110 fs2/mm were fabricated, and narrow beatnotes with FWHM linewidths below 1 kHz were measured on the entire operation range. At -20°C, the optical output power reaches 275 mW, and the optical spectrum spans 60 cm-1. The multi-heterodyne beating spectrum of two devices was measured and spans 46 cm-1, demonstrating the potential of dispersion-engineered waveguides for the fabrication of highly stable and reliable quantum cascade laser FCs with high output power across the mid-infrared.

Purely wavelength- and amplitude-modulated quartz-enhanced photoacoustic spectroscopy.

We report here on a quartz-enhanced photoacoustic (QEPAS) sensor employing a quantum cascade laser (QCL) structure capable of operating in a pure amplitude or wavelength modulation configuration. The QCL structure is composed of three electrically independent sections: Gain, Phase (PS) and Master Oscillator (MO). Selective current pumping of these three sections allows obtaining laser wavelength tuning without changes in the optical power, and power modulation without emission wavelength shifts. A pure QEPAS amplitude modulation condition is obtained by modulating the PS current, while pure wavelength modulation is achieved by modulating simultaneously the MO and PS QCL sections and slowly scanning the DC current level injected in the PS section.

Mid infrared quantum cascade laser operating in pure amplitude modulation for background-free trace gas spectroscopy.

We present a single mode multi-section quantum cascade laser source composed of three different sections: master oscillator, gain and phase section. Non-uniform pumping of the QCL's gain reveals that the various laser sections are strongly coupled. Simulations of the electronic and optical properties of the laser (based on the density matrix and scattering matrix formalisms, respectively) were performed and a good agreement with measurements is obtained. In particular, a pure modulation of the laser output power can be achieved. This capability of the device is applied in tunable-laser spectroscopy of N2O where background-free quartz enhanced photo acoustic spectral scans with nearly perfect Voigt line shapes for the selected absorption line are obtained.

High power and single mode quantum cascade lasers.

We present a single mode quantum cascade laser with nearly 1 W optical power. A buried distributed feedback reflector is used on the back section for wavelength selection. The laser is 6 mm long, 3.5 µm wide, mounted episide-up and the laser facets are left uncoated. Laser emission is centered at 4.68 µm. Single-mode operation with a side mode suppression ratio of more than 30 dB is obtained in whole range of operation. Farfield measurements prove a symmetric, single transverse-mode emission in TM00-mode with typical divergences of 41° and 33° in the vertical and horizontal direction respectively. This work shows the potential for simple fabrication of high power lasers compatible with standard DFB processing.

Extended tuning of mid-ir quantum cascade lasers using integrated resistive heaters.

We present single mode quantum cascade lasers including a microscopic heater for spectral emission tuning. Through the use of a buried heater element, the active region temperature can be modified without changing the submount one. Emission frequency tuning in continuous-wave as large as 9 cm(-1) at 1270 cm(-1) and 14 cm(-1) at 2040 cm(-1) are observed, corresponding to an increase of the active region temperatures of ∼ 90 K. Due to the proximity of the heaters to the active region, emission can be modulated at several kHz range and the absence of moving parts guarantees the mechanical stability of the system. This method can be successfully applied to all buried heterostructure lasers, becoming an attractive solution for molecular spectroscopy in the IR. Using the presented devices, molecular absorptions of N(2)O have been measured between 1270 cm(-1) and 1280 cm(-1) and are in agreement with data from the HITRAN database.

All-electrical frequency noise reduction and linewidth narrowing in quantum cascade lasers.

A novel all-electrical method of frequency noise reduction in quantum cascade lasers (QCLs) is proposed. Electrical current through the laser was continuously adjusted to compensate for fluctuations of the laser internal resistance, which led to an active stabilization of the optical emission frequency. A reduction of the linewidth from 1.7 MHz in the standard constant current mode of operation down to 480 kHz is demonstrated at 10-ms observation time when applying this method to a QCL emitting at 7.9 µm.