Development of cinnamon essential oil-loaded PBAT/thermoplastic starch active packaging films with different release behavior and antimicrobial activity.

The poly (butylene adipate-co-terephthalate)/thermoplastic starch (PBAT/TPS) active packaging films containing cinnamon essential oil (CEO) were fabricated by melting blending and extrusion casting method. The effects of TPS content (0 %, 10 %, 20 %, 30 %, 40 % and 50 %) on the properties of the films and their application in largemouth bass preservation were studied. As TPS content increased from 0 % to 50 %, the water vapor permeability increased from 7.923 × 10-13 (g•cm/(cm2•s•Pa)) to 23.967 × 10-13 (g•cm/(cm2•s•Pa)), the oxygen permeability decreased from 8.642 × 10-11 (cm3•m/(m2•s•Pa)) to 3.644 × 10-11 (cm3•m/(m2•s•Pa)), the retention of CEO in the films increased. The release rate of CEO from the films into food simulant (10 % ethanol) accelerated with increasing TPS. The films exhibited different antibacterial activity against E. coli, S. aureus, and S. putrefaciens. It was closely related with the release behavior of the CEO. The films containing CEO could efficiently inhibit the decomposition of protein and the growth of microorganisms in largemouth bass. It showed that the higher TPS in the films, the better inhibitory effect. This study provided a new idea for developing PBAT/TPS active films with different release behavior of active agents and different antibacterial activity for food packaging.

Development and characterization of starch/PVA antimicrobial active films with controlled release property by utilizing electrostatic interactions between nanocellulose and lauroyl arginate ethyl ester.

The two nanocellulose (nanofibrillated cellulose (NFC) and carboxylated nanofibrillated cellulose (C-NFC)) could interact with lauryl arginine ethyl ester hydrochloride (LAE) through electrostatic bonding. The zeta potential (absolute value) of C-NFC (-27.80 mV) was higher than that of NFC (-10.07 mV). The starch/polyvinyl alcohol active films with controlled release property by utilizing electrostatic interactions between nanocellulose and LAE were prepared and their properties were investigated. For incorporation of the NFC or C-NFC, the cross-section of the films became slightly uneven and some fibrils were observed, the films exhibited an increase in strength, while the film water vapor and oxygen barrier properties decreased. The release of LAE from the films to food simulants (10 % ethanol) decelerated with increasing of NFC or C-NFC. These might be mainly attributed to the enhanced electrostatic interaction between NFC or C-NFC and LAE. It demonstrated that nanocellulose with higher negative charges would exhibit stronger electrostatic interaction with LAE, thus slowing the release of LAE. The film with highest C-NFC content exhibited smallest inhibition zone among LAE-containing films, which was related with its slowest release rate of LAE. It showed a great prospect to develop controlled release active packaging films by utilizing electrostatic interactions between substances.

Development of controlled-release antioxidant poly (lactic acid) bilayer active film with different distributions of α-tocopherol and its application in corn oil preservation.

The antioxidant poly (lactic acid) bilayer active films with a different distribution of α-tocopherol (TOC) in two layers (outer layer/inner layer: 0%/6%, 2%/4%, 3%/3%, 4%/2%, 6%/0%) were developed. The effects of TOC distribution on the structural, physicochemical, mechanical, antioxidant and release properties of the films and their application in corn oil packaging were investigated. The different distributions of TOC showed insignificant effects on the color, transparency, tensile strength and oxygen and water vapor barrier properties of the films, but it affected the release behavior of TOC from the films into 95% ethanol and the oxidation degree of corn oil. The film with higher TOC in outer layer showed a slower release rate. The corn oil packaged by the film containing 4% TOC in outer layer and 2% TOC in inner layer exhibited the best oxidative stability. This concept showed a great potential to develop controlled-release active films for food packaging.

Effects of starch/polyvinyl alcohol active film containing cinnamaldehyde on the quality of large yellow croaker (Pseudosciaena crocea) proteins during frozen storage.

This study aimed to investigate the effects of starch/polyvinyl alcohol (starch/PVA) film containing cinnamaldehyde (CIN) with different humidity treatment on the quality changes of large yellow croaker (Pseudosciaena crocea) under vacuum packaging during frozen storage. It was evaluated by measuring the water loss, water migration, total volatile basic nitrogen (TVB-N), thiobarbituric acid (TBA), free amino acids (FAA) content, myofibril secondary and tertiary structure and microstructure of large yellow croaker. Compared with control group, the starch/PVA films could inhibit the water loss, water migration, protein degradation, lipid oxidation and microstructure damage of fish. The film containing CIN with higher humidity treatment showed the best protective effect for large yellow croaker. The film with higher humidity treatment showed better to maintain the quality of fish than that with low humidity treatment. Therefore, starch/PVA active film containing CIN with high humidity treatment showed good fresh-keeping potential in the frozen storage of aquatic products.

Microfibrillated cellulose reinforced starch/polyvinyl alcohol antimicrobial active films with controlled release behavior of cinnamaldehyde.

The starch/polyvinyl alcohol (ST/PVA) films incorporated with cinnamaldehyde (CIN) and microfibrillated cellulose (MFC) were developed. The effect of MFC content on the films' properties was studied. The SEM results showed that MFC promoted compatibility among starch, PVA and CIN. With increased content of MFC, the strength of the films was improved and their flexibility reduced, the films' crystallinity degree and hydrophobicity were improved. The oxygen and water vapor permeability of the films both reduced first and then increased as a whole. The release of CIN from films into the food stimulant (10% ethanol) could be controlled by MFC. When MFC content was between 1% and 7.5%, it decelerated the release of CIN but high MFC content exceeded 10% promoted the release of CIN. It revealed that films containing CIN could inhibit growth of S. putrefaciens. It showed a good prospect of using MFC to develop controlled release active ST/PVA films.

Development of New Multilayer Active Packaging Films with Controlled Release Property Based on Polypropylene/Poly(Vinyl Alcohol)/Polypropylene Incorporated with Tea Polyphenols.

The polypropylene/poly(vinyl alcohol)/polypropylene (PP/PVA/PP) multilayer active films with controlled release property were developed, of which the intermediate PVA layer was incorporated with 4% (w/w) tea polyphenols (TP) and the microporous PP films with different pore size were used as the internal controlled release layer. The SEM results showed that each layer of these films was agglutinated tightly. With increasing pore size from 171.05 to 684.03 µm, there were little effect on the films' color and opacity, the tensile strength (TS) and elongation at break (EAB) decreased slightly, the gas barrier (O2 and water vapor) property of the film reduced faintly, the time of achieving the release equilibrium in 50% ethanol decreased from 75 hours to 30 hours. The diffusion coefficient for the films increased with the increase of pore size, from 2.06 × 10-11 cm2 /s to 8.06 × 10-11 cm2 /s, suggesting that the release rate of TP increased as the pore size increased. The results were indicated that its release rate could be controlled by adjusting the size of pore. The films also exhibited different antioxidant activities due to their different release profiles of TP. It showed promise for developing the controlled release active packaging film based on this concept. PRACTICAL APPLICATION: Controlled release packaging is propitious to extension of food shelf life. The microporous polypropylene films with different pore size used as the internal layer of polypropylene/poly(vinyl alcohol)/polypropylene (PP/PVA/PP) multilayer active films was proved that the release rate of tea polyphenols in the intermediate PVA layer released from the films into the food simulant can be controlled by adjusting the size of pore in this study. It showed a good prospect for using microporous or perforation-mediated film as the internal layer of multilayer film to develop the controlled release active packaging film for food packaging.

Laser induced breakdown spectroscopy of pure aluminum with high temporal resolution.

We report on a Laser Induced Breakdown Spectroscopy (LIBS) system with a very high temporal resolution, using femtosecond and picosecond pulse laser excitation of pure aluminum (Al). By using a 140 fs Ti:Sapphire laser in an ultrafast optical Kerr gate (OKG), we demonstrate LIBS sampling with a sub-ps time resolution (0.8 ± 0.08 ps) in a 14 ns window. The width of the gating window in this system was as narrow as 0.8 ps, owing to the inclusion of a carbon disulfide (CS(2)) cell, which has a fast response and a large nonlinear coefficient. Furthermore, when using a 100 ps pulsed Nd:YAG laser and a fast photomultiplier tube (PMT) we demonstrate a LIBS system with a nanosecond time resolution (2.20 ± 0.08 ns) in a microsecond window. With this sort of temporal resolution, a non-continuous decay in the Al signal could be observed. After 50 ns decay of the first peak, the second peak at 230 ns is started to perform. Experimental results with such short temporal windows in LIBS, in both nanosecond and microsecond ranges, are important for fast temporal evolution measurements and observations of early continuum emission in materials.

Solute migration caused by excited state absorptions.

Using the Z-scan technique, we find that migration of chloroaluminum phthalocyanine in liquid ethanol can be induced by the absorption of a 19 ps laser pulse with energy exceeding a threshold but not by that of a 2.8 ns pulse depositing more energy at the solute molecules. Considering each solute molecule as an oscillator confined within a potential well, we explain, in accordance with the five-energy-band model, that solute molecules excited by a 19 ps pulse retain more translational excess energy to overcome the potential well barrier compared with those excited by a 2.8 ns pulse of equal energy. Therefore, they are more likely to migrate out of the laser beam center, weakening the solution's absorption that we detect in the Z-scan measurements. Furthermore, we theoretically infer that the 19 ps pulse-induced solute migration tends to be nonquasistatic and experimentally verify that it cannot be attributed to the Soret effect, a quasistatic process.

Negative nonlinear refraction obtained with ultrashort laser pulses.

We present nonlinear refraction results for liquids methanol and acetic acid obtained with the Z-scan technique and 28 femtosecond (fs) 800 nm laser pulses. In contrast to the positive lensing effect obtained previously with picosecond and nanosecond laser pulses, a negative lensing effect is observed. The associated mechanism features the third-order polarization arising from the nonlinear response of the molecular skeletal motion that is driven into resonance through its electrostatic coupling to the valence electron cloud distorted by the fs laser field.

Mass transport following impulsive optical excitation.

Transition from reverse-saturable absorption to saturable absorption of the chloroaluminum phthalocyanine solution excited by a giant laser pulse is ascribed not just to the saturation of excited state absorption, but also to the outward migration of the solute molecules at the laser beam center. While the saturation of excited state absorption occurs within a single picosecond laser pulse, the beam center population decrease is sustained much longer than the pulse duration. We distinguish these two mechanisms with the Z-scan technique, utilizing picosecond pulses with pulse-to-pulse separations ranging from 0.1 to 5.0 s.