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1.
Chemphyschem ; 25(3): e202300599, 2024 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-38012079

RESUMO

Two-step deposition method has been widely exploited to fabricate FA1-x Csx PbI3 perovskite solar cells. However, in previous studies, CsI is mainly added into the PbI2 precursor with DMF/DMSO as solvent. Here in this study, a novel method to fabricate FA1-x Csx PbI3 perovskite has been proposed. The CsI is simultaneously added into the PbI2 precursor and the organic FAI/MACl salts solution in our modified two-step deposition process. The resulting FA1-x Csx PbI3 film exhibits larger perovskite crystals and suppressed defect density (4.05×1015  cm-3 ) compared with the reference perovskite film (9.23×1015  cm-3 ) without CsI. Therefore, the obtained FA1-x Csx PbI3 perovskite solar cells have demonstrated superior power conversion efficiencies (PCE=21.96 %) together with better long-term device stability.

2.
J Ethnopharmacol ; 321: 117540, 2024 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-38056534

RESUMO

ETHNOPHARMACOLOGICAL RELEVANCE: Chimonanthus nitens Oliv. Leaf Granule (COG) is a commonly used clinical preparation of traditional Chinese medicine for the treatment of cold, but there are folk reports that it can treat diarrhea and other gastrointestinal diseases. Therefore, the mechanism of COG in the treatment of ulcerative colitis with diarrhea as the main symptom needs to be studied. AIM OF THE STUDY: Combined network pharmacology and experimental validation to explore the mechanism of COG in the treatment of ulcerative colitis. MATERIALS AND METHODS: First, the main components of COG were characterized by liquid chromatography-mass spectrometry (LC-MS); subsequently, a network pharmacology approach was used to screen the effective chemical components and action targets of COG to construct a target network of COG for the treatment of ulcerative colitis (UC). The protein-protein interaction network (PPI) and literature reports were combined to identify the potential targets of COG for the treatment of UC. Finally, the predicted results of network pharmacology were validated by animal and cellular experiments. RESULTS: 19 components of COG were characterized by LC-MS, among which 10 bioactive components could act on 377 potential targets of UC. Key therapeutic targets were collected, including SRC, HSP90AA1, PIK3RI, MAPK1 and ESR1. KEGG results are enriched in pathways related to oxidative stress. Molecular docking analysis showed good binding activity of main components and target genes. Animal experiments showed that COG significantly relieved the colitis symptoms in mice, regulated the Treg/Th17 balance, and promoted the secretion of IL-10 and IL-4, along with the inhibition of IL-1ß and TNF-α. Additionally, COG reduced the apoptosis of colon epithelial cells, and significantly improved the levels of SOD, MAO, GSH-px, and inhibited MDA, iNOS, eNOS in colon. Also, it increased the expression of tight junction proteins such as ZO-1, Claudin1, Occludin and E-cadherin. In vitro experiments, COG inhibited the oxidative stress and inflammatory injury of HCT116 cells induced by LPS. CONCLUSIONS: Combining network pharmacology and in vitro and in vivo experiments, COG was verified to have a good protective effect in UC, which may be related to enhancing antioxidation in colon tissues.


Assuntos
Calycanthaceae , Colite Ulcerativa , Colite , Medicamentos de Ervas Chinesas , Animais , Camundongos , Colite Ulcerativa/induzido quimicamente , Colite Ulcerativa/tratamento farmacológico , Simulação de Acoplamento Molecular , Farmacologia em Rede , Diarreia , Medicamentos de Ervas Chinesas/farmacologia , Medicamentos de Ervas Chinesas/uso terapêutico , Sulfato de Dextrana
3.
Chempluschem ; 88(10): e202300367, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37724441

RESUMO

Solution processed perovskite films usually exhibit numerous defect states on the surfaces of the films. Here in this work, oxalic acid (H2 C2 O4 ), which has two C=O groups, is selected and used to passivate the surface defects of the two-step deposited perovskite films via post-treatment. Strong interaction between H2 C2 O4 molecule and the Pb2+ ions located on the surface of perovskite film has been confirmed via Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy, which can result in an effective suppress of the surface defects. Furthermore, time-resolved PL spectrum indicates that carrier lifetime is prolonged in the H2 C2 O4 passivated perovskite film. After optimizing the H2 C2 O4 concentration, the target perovskite solar cells can demonstrate superior power conversion efficiencies (21.67 % from reverse measurement and 21.54 % from forward measurement) and superior device-stability.

4.
Int J Psychol ; 58(4): 299-310, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37191038

RESUMO

To sustainably develop organisational goals, it is important to create conditions under which leaders are trusted and judged to be incorrupt. We proposed that and tested whether leader selection affects judgements of leader corruption. A correlational study with cross-national data and two experimental studies in China were conducted. Study 1 collected and analysed 20-year panel data on 93 countries/territories. To provide causal evidence for the results of Study 1 and account for this effect, Studies 2 and 3 manipulated leader selection and measured trust in leaders and perceptions of leader corruption. The three studies converged to show that election (vs. appointment) predicted decreased judgements of leader corruption. Furthermore, Studies 2 and 3 identified that trust in leaders is the underlying mechanism driving this leader selection effect. Our findings contribute to a better understanding of perceptions of leader corruption, the process of leader empowerment and the control of corruption.


Assuntos
Liderança , Confiança , Humanos , Política , China
5.
Chemistry ; 29(14): e202202744, 2023 Mar 07.
Artigo em Inglês | MEDLINE | ID: mdl-36446736

RESUMO

Among the factors that lead to the reduction of the efficiency of perovskite solar cells (PSCs) the difficulty involved in realizing a high-quality film and the efficient charge transfer that takes place at the interface between electron-transport layer (ETL) and perovskite is worth mentioning. Here, a strategy for planar-type devices by natural bio-functional interfaces that uses a buried electron-transport layer made of cobalamin complexed tin oxide (SnO2 @B12 ) is demonstrated. Having systematically investigated the effects of SnO2 @B12 interfacial layer in perovskite solar cells, it can be concluded that cobalamin can chemically link the SnO2 layer and the perovskite layer, resulting in improved perovskite film quality and interfacial defect passivation. Utilizing SnO2 @B12 improves the efficiency of planar-type PSCs by 20.60 %. Furthermore, after 250 h of exposure to an ambient atmosphere, unsealed PSCs containing SnO2 @B12 degrade by 10 %. This research provides a viable method for developing bio-functional molecules that will increase the effectiveness and durability of planar-perovskite solar cells.

6.
Front Cell Infect Microbiol ; 12: 907813, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35832382

RESUMO

The rising incidence of ulcerative colitis has become a new challenge for public health. Chimonanthus nitens Oliv. leaf granule (COG) is a natural medicine used for the treatment of respiratory diseases, which has excellent anti-inflammatory and antioxidant effects. However, the therapeutic effect of COG in ulcerative colitis (UC) has not been reported. Here, the experimental colitis was treated with dextran sodium sulfate (DSS) and COG. After treatment with high (30 g/kg), medium (15 g/kg), and low (7.5 g/kg) doses of COG for 11 consecutive days, the body weight, disease activity index (DAI) score, colon length, colon weight index, and the pathological score of mice were effectively improved. COG significantly reduced the levels of inflammatory cytokines in UC mice in vitro and in vivo and restored the secretion levels of IL-6 and IL-10 in the colon. Meanwhile, compared to mice with colitis, COG-treated mice showed lower levels of MDA, MPO, NO, and eNOS and higher levels of GSH-Px and MAO, which indicated that oxidative stress damage in colitic mice was alleviated by COG. Moreover, less Th17 and more Tregs were observed in the COG-treated groups. In addition, COG improved the diversity and relative abundance of gut microflora in the colon of colitic mice, and Lachnospiraceae_NK4A136_group and Lachnospiraceae_UCG-006 were obviously regulated at the genus level. In summary, COG has a protective effect on DSS-induced experimental colitis, mainly through inhibition of immune-inflammatory responses and oxidative stress and regulation of mTreg cell responses and intestinal flora composition.


Assuntos
Colite Ulcerativa , Colite , Microbioma Gastrointestinal , Animais , Colite/induzido quimicamente , Colite/tratamento farmacológico , Colite/metabolismo , Colite Ulcerativa/induzido quimicamente , Colite Ulcerativa/tratamento farmacológico , Colo/patologia , Sulfato de Dextrana/toxicidade , Modelos Animais de Doenças , Camundongos , Camundongos Endogâmicos C57BL , Estresse Oxidativo , Folhas de Planta , Linfócitos T Reguladores
7.
Front Nutr ; 8: 632546, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-33981719

RESUMO

Background: There are several approaches that can be used for the pre-treatment identification of malnutrition in oncology populations including the Patient-Generated Subjective Global Assessment (PG-SGA), the 2015 consensus statement by the European Society for Clinical Nutrition and Metabolism (ESPEN 2015) and the Global Leadership Initiative on Malnutrition (GLIM). Aims: This study aimed to evaluate whether malnutrition, as defined by these three methods, can be used to predict complications in esophageal cancer (EC) patients after esophagectomy. Methods: We performed a single center, observational cohort study that included 360 EC patients undergoing esophagectomy from December 2014 to November 2019 at Daping Hospital in China. The prevalence of malnutrition in the study population was prospectively defined using the PG-SGA (≥9 defined malnutrition), and retrospectively defined using the ESPEN 2015 and the GLIM. The prevalence of malnutrition and association with postoperative complications were compared in parallel for the three methods. Results: The prevalence of malnutrition before surgery was 23.1% (83/360), 12.2% (44/360), and 33.3% (120/360) in the study population, as determined by the PG-SGA, the ESPEN 2015 and the GLIM, respectively. The PG-SGA and GLIM had higher diagnostic concordance (Kappa = 0.519, P < 0.001) compared to the ESPEN 2015 vs. GLIM (Kappa = 0.361, P < 0.001) and PG-SGA vs. ESPEN 2015 (Kappa = 0.297, P < 0.001). The overall incidence of postoperative complications for the study population was 58.1% (209/360). GLIM- and ESPEN 2015-defined malnutrition were both associated with the total number of postoperative complications in multivariable analyses. Moreover, GLIM-defined malnutrition exhibited the highest power to identify the incidence of complications among all independent predictors in a pooled analysis. Conclusion: Among the PG-SGA, the ESPEN 2015 and the GLIM, the GLIM framework defines the highest prevalence rate of malnutrition and appears to be the optimal method for predicting postoperative complications in EC patients undergoing esophagectomy. These results support the importance of preoperatively identifying malnutrition using appropriate assessment tools, because it can facilitate the selection of management strategies that will optimize the clinical outcomes of EC patients.

8.
Phys Chem Chem Phys ; 21(27): 15206-15214, 2019 Jul 10.
Artigo em Inglês | MEDLINE | ID: mdl-31250869

RESUMO

Thiophene/benzene-fused π-conjugated systems are normally employed as the core units of two- and three-dimensionally expanded small molecule hole-transporting materials (HTMs) to improve their electronic and charge transport properties, whereas comparison studies between two-dimensional and three-dimensional core conformations are less reported. To further find useful clues for the design of highly-efficient small molecule HTMs and to find new core units, in this work, four HTM molecules are designed by employing triphenylene, benzotrithiophene, triptycene, and thiophenetriptycene as the core units, and simulated with density functional theory combined with the Marcus hopping model. Our results show that all the considered HTMs display appropriate molecular energy levels, less optical absorption in the visible light region and large Stokes shifts, and high hole mobilities (9.80 × 10-2 cm2 V-1 s-1). Compared with the two-dimensional core structures, the three-dimensional cores exhibit evident superiorities with the same chemical components. Meanwhile, we also find that the quasi-degenerate HOMO energy levels will be helpful to enlarge the transfer integrals between adjacent molecules, and further to promote the hole transport in HTMs. By considering the various elements simultaneously, these investigated HTMs (S-1-S-4) with thiophene- and benzene-fused cores can be expected as potential promising candidates to help create more efficient solar cells.

9.
J Exp Clin Cancer Res ; 38(1): 165, 2019 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-30987652

RESUMO

BACKGROUND: miRNAs play crucial role in the progression of K-Ras-mutated nonsmall cell lung cancer (NSCLC). However, most studies have focused on miRNAs that target K-Ras. Here, we investigated miRNAs regulated by mutant K-Ras and their functions. METHODS: miRNAs regulated by mutant K-Ras were screened using miRNA arrays. miR-199b expression levels were measured by qRT-PCR. The protein expression levels were measured using Western blot and immunohistochemistry. The effects of miR-199b on NSCLC were examined both in vitro and in vivo by overexpressing or inhibiting miR-199b. DNA methylation was measured by bisulfite sequencing. RESULTS: An inverse correlation was observed between K-Ras mutation status and miR-199b levels in NSCLC specimens and cell lines. The inhibition of miR-199b stimulated NSCLC growth and metastasis, while restoration of miR-199b suppressed K-Ras mutation-driven lung tumorigenesis as well as K-Ras-mutated NSCLC growth and metastasis. miR-199b inactivated ERK and Akt pathways by targeting K-Ras, KSR2, PIK3R1, Akt1, and Rheb1. Furthermore, we determined that mutant K-Ras inhibits miR-199b expression by increasing miR-199b promoter methylation. CONCLUSION: Our findings suggest that mutant K-Ras plays an oncogenic role through downregulating miR-199b in NSCLC and that overexpression of miR-199b is a novel strategy for the treatment of K-Ras-mutated NSCLC.


Assuntos
Carcinoma Pulmonar de Células não Pequenas/genética , Carcinoma Pulmonar de Células não Pequenas/metabolismo , Neoplasias Pulmonares/genética , Neoplasias Pulmonares/metabolismo , MicroRNAs/genética , Proteínas Proto-Oncogênicas p21(ras)/genética , Proteínas Proto-Oncogênicas p21(ras)/metabolismo , Carcinoma Pulmonar de Células não Pequenas/patologia , Linhagem Celular Tumoral , Movimento Celular , Proliferação de Células , Transformação Celular Neoplásica/genética , Transformação Celular Neoplásica/metabolismo , Metilação de DNA , Progressão da Doença , MAP Quinases Reguladas por Sinal Extracelular/metabolismo , Regulação Neoplásica da Expressão Gênica , Genes Reporter , Humanos , Neoplasias Pulmonares/patologia , Modelos Moleculares , Mutação , Proteínas Proto-Oncogênicas c-akt/metabolismo
10.
Nanoscale ; 8(42): 18121-18133, 2016 Oct 27.
Artigo em Inglês | MEDLINE | ID: mdl-27735952

RESUMO

The properties of nanomaterials are highly dependent on their size, shape and composition. Compared with zero-dimensional nanoparticles, the increased dimension of a one-dimensional silver nanowire (AgNW/Ag NW) leads to extra challenges on synthesizing it with controllable sizes. Here, a convenient way for the synthesis of AgNWs with tunable sizes has been developed simply by adjusting the amount of salt additives, i.e., ferric chloride (FeCl3), or Fe(NO3)3 & KCl. The average diameter and length of nanowires are readily tailored within 45-220 nm and 10-230 µm, respectively. The distinctive roles of Fe3+ and Cl- played during the growth stages of Ag NWs were revealed by comparative experiments and a heterogeneous nucleation model with the assistance of oxidative etching was proposed to elucidate the growth mechanism. Afterwards, transformations in XRD patterns from nanometer-size effects and quantitative relation for size-dependent peak wavelength of surface plasmon resonances (SPRs) in UV-vis spectroscopy of these nanowires were studied. In addition, as transparent conductive materials (TCMs), these metal nanowires were utilized to fabricate transparent conductive films (TCFs), and the effects of their diameters and lengths were elucidated. Very/ultra-long nanowires with a high aspect ratio up to 1600 achieved impressive properties of R = 12.4 ohm sq-1 at T% = 90.1% without any post treatment. This facile method for the size-tunable growth of uniform AgNWs with high yield is attractive and ready to be home-made, which is believed to promote research in their potential applications, especially in optoelectronic devices and flexible electronics.

11.
Huan Jing Ke Xue ; 37(1): 66-73, 2016 Jan 15.
Artigo em Chinês | MEDLINE | ID: mdl-27078942

RESUMO

Variations of air quality, meteorological conditions and the effect of pollution control measures on particle matter concentrations in Beijing were all analyzed during APEC (from 1st to 12th in November) in 2014 based on the atmospheric pollutant monitoring data, monitoring components of PM2.5, meteorological and remote sensing data and CMB model. The results showed that the average concentrations of PM2.5, PM10, SO2, NO2 were 43,62,8,46 [g.m respectively during APEC and the average concentrations of PM2.5, PM10, SO2, NO2 were decreased by 45%, 43%, 64% and 31% compared to those in the same period of the last 5 years (PM2. was the average of the last 2 years); the concentrations of PM25 at different sites were decreased by 27.4%-35.5%; the concentrations of PM2.5 in the center of city and northern mountainous areas were the lowest, which dropped by 30%-45% compared to those in the same period of the last 5 years while in the southern area the decrement was below 25%; the main component SO4(2-), the substance of the crust, and NO3- were decreased by 50%, 76%, 35% respectively compared to those in the same period in 2013 and the chemical mass balance (CMB) model analysis results indicated that contributions of coal boiler, dust, motor vehicle were 2%, 7%, 30% respectively during APEC; air pollution control measures (coal, dust and traffic management) had a significant effect on reducing pollutant emissions and the pollutant emissions control reduced the concentration peak and delayed the accumulation speed.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental , Material Particulado/análise , Pequim , Carvão Mineral , Poeira , Poluição Ambiental , Substâncias Perigosas , Modelos Químicos , Emissões de Veículos
12.
Nanoscale ; 8(11): 5847-51, 2016 Mar 21.
Artigo em Inglês | MEDLINE | ID: mdl-26932777

RESUMO

A novel composite nanostructured titanium dioxide (TiO2) based electron-transport layer (ETL) is designed by combining size blended nanoparticles (SBNP) and nanoarrays (NA) for efficient perovskite solar cell (PSC) applications. The composite nanostructured (SBNP + NA) ETL is successfully employed in hole-conductor free PSCs, there by achieving a stable device with a maximum efficiency of 13.5%. The improvement in the performance is attributed to the better charge transport and lower recombination in the SBNP + NA ETL. Despite the stable high efficiency, SBNP + NA ETL based PSCs are advantageous owing to their low cost, ease of all-solution fabrication process in an open environment and good reproducibility.

13.
Huan Jing Ke Xue ; 37(7): 2409-2418, 2016 Jul 08.
Artigo em Chinês | MEDLINE | ID: mdl-29964445

RESUMO

Variations of PM2.5 concentrations and effects of pollution control measures during two red alert periods in 2015 in Beijing were analyzed based on atmospheric pollutant monitoring data. The results showed that during the first red alert, the highest hourly-averaged PM2.5 concentration occurred at 19:00 on 9th December with a value of 282 µg·m-3 and the highest hourly PM2.5 concentration appeared at Yongledian station which is near the southeast border of Beijing, with the peak concentration of 496 µg·m-3. During the second red alert, the highest hourly-averaged concentration of PM2.5 occurred at 20:00 on 22th with a value of 421 µg·m-3. The highest hourly PM2.5 concentration was monitored at Liulihe station which is near the southwest border of Beijing, with the peak concentration of 831 µg·m-3. During the duration period of both red alerts, the concentrations at the southern stations were higher than those at downtown stations and the PM2.5 concentrations at northern stations were found to be the smallest. The difference between these two red alerts was that during the second red alert, the PM2.5 concentrations in southern Beijing were significantly higher than those in the northern area, while the magnitude of this south-to-north gradient was much smaller during the first one. During the second red alert, up to 93% of Beijing area showed an average PM2.5 concentration of above 150 µg·m-3, which was much larger than that in the first one. The meteorological conditions during the two red alerts were both not conducive to the spread of pollutants. Formation of secondary pollutants and regional pollutant transport existed as well. Though the stagnant weather conditions were in favor of the development of severe pollution, large regional-wide pollutant emission was the main reason for these two heavy air pollutions in Beijing. PM2.5 concentrations were decreased by 20%-25% after the implementation of emergency response measures, which showed the significance of emission reduction in air pollution control.

14.
Huan Jing Ke Xue ; 37(8): 2847-2854, 2016 Aug 08.
Artigo em Chinês | MEDLINE | ID: mdl-29964707

RESUMO

Based on the hourly O3 monitoring data from 2004 to 2015 of Beijing, a comprehensive discussion on the characteristics of O3 concentration at a background station Dingling in Beijing was conducted. The results showed that the annual concentration of O31h was increasing with a growth rate of 4.40 µg·m-3 while the annual concentration of O38h was decreasing with annual average rates of -1.0 µg·m-3 and -1.5 µg·m-3 from May to October in 2004 and 2015. Over the past 3 years, number of O38h severe pollution days increased significantly and the situation of O3 pollution in Beijing became more serious. O3 concentration reached its peak in June in a year and its diurnal peak concentration occurred at about 15:00-18:00 at Dingling station which was 101-1.56 times larger than that in the urban center of Beijing. In different years, the ozone peak concentration at Dingling Station was 1h later than that in the urban center from May to October in diurnal variation and the difference of peak concentration was significantly reduced in recent years, which on the one hand may be related to regional ozone pollution, on the other hand may be related to the expansion of Beijing's urbanization.

15.
Huan Jing Ke Xue ; 37(6): 2041-2051, 2016 Jun 08.
Artigo em Chinês | MEDLINE | ID: mdl-29964868

RESUMO

The spatial-temporal distribution characteristics of O3 and the correlations between O3 and meteorological elements in Beijing urban area were investigated based on the hourly O3 monitoring data from January to December in 2014 released by Beijing Municipal Environmental Monitoring Center. The annual concentration of O3 in Beijing was about 56.18 µg·m-3 in 2014. In the over polluted days during May and September, the O3 concentration could reach as high as 148.05 µg·m-3. The diurnal distribution of ozone presented a clear unimodal pattern with its peak appearing at 15:00 or 16:00 and trough at 06:00 or 07:00 and the concentrations of O3 during 09:00 and 23:00 was significantly higher than those in the Summer time. For the spatial distribution of O3, the concentration was lower in central urban area with the highest concentration appearing at plant garden site in the west of the urban area. Ground weather type of O3 over polluted days was divided into three categories including high-pressure, low-pressure, equalizing field, which accounted for 16%, 36%, 48%, respectively. The concentration of O3 was negatively correlated with the air pressure, humidity and visibility while it was positively correlated with the wind speed and temperature. In one heavy pollution episode of O3 caused by local photochemical pollution and regional transport from May 29th to June 1st in 2014 in Beijing, regional transport showed a very important influence on the concentration of O3 in Beijing.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental , Ozônio/análise , Tempo (Meteorologia) , Poluição do Ar , Pequim , Estações do Ano , Análise Espacial
16.
Guang Pu Xue Yu Guang Pu Fen Xi ; 36(12): 3937-40, 2016 Dec.
Artigo em Chinês | MEDLINE | ID: mdl-30235412

RESUMO

Yogurt is a food produced by bacterial fermentation of milk. All kinds of nutrition components are changing dramatically in the process of fermentation. Therefore, it is important to establish a fast and efficient measurement technology of yogurt nutrition, which is also an important goal for food safety supervision in terms of monitoring the yogurt production process in real time. Fourier transform infrared spectroscopy (FTIR) has been widely used in the field of food safety, for it has high efficiency, high throughput, no chemical pollution, thus it can be used in the inspection of food adulteration. Our study has established a quantitative model to predict the nutrition components in yogurt, such as energy value, protein, fat, carbohydrates and sodium content. Based on the least squares (PLS) method, the model used CaF(2) film FTIR technology. The results show that the new model can be used in quality control of yogurt production process: The R(2) values of the model were 0.938 9, 0.926 6, 0.918 6, 0.941 8 and 0.977 1, comparing energetic value, protein, fat, carbohydrate and sodium contents with the original spectrum of calibration samples by cross validation. And the predictive R(2) are 0.920 5, 0.905 3, 0.908 5, 0.939 3 and 0.936 4 respectively. Thus, the model has good prediction accuracy and reliability, which provides a feasible method for the rapid measurement of yogurt quality. As a preliminary exploration of the quality control technology of dairy products, this method has a good prospect of application.


Assuntos
Espectroscopia de Infravermelho com Transformada de Fourier , Iogurte , Animais , Calibragem , Carboidratos , Fermentação , Contaminação de Alimentos , Análise dos Mínimos Quadrados , Leite , Proteínas , Controle de Qualidade , Reprodutibilidade dos Testes
17.
Huan Jing Ke Xue ; 36(7): 2353-60, 2015 Jul.
Artigo em Chinês | MEDLINE | ID: mdl-26489298

RESUMO

In this paper, spatial and temporal distribution, transportation and deposition of PM2.5 in Shandong Province in Spring, 2014 were all analyzed by applying PSAT of CAMx model and we also developed a transport matrix of PM2.5 between different cities in Shandong. The results showed that ρ(PM2.5) presented obvious spatial distribution characteristics; ρ(PM2.5) was higher in the western part compared to that in peninsula and ρ(PM2.5) was mainly concentrated below 2 000 m in vertical direction. Simulated horizontal transport flux of PM2.5 was up to 110 µg.(m2.s)-1 and the total deposition amount of PM2.5 was 23. 05 x 10(4) t in Shandong during Spring, 2014. Analysis of regional contribution found that the pollutants mainly came from local districts and the average external transport contribution to the whole Shandong province was about 21. 08% ± 3. 83% while it was 40. 45% ± 5. 96% between different cities; the contribution rates of Jinjinji distrcit, background and boundary conditions gradually increased by 7. 56% and 6. 18% respectively as the altitude increased.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental , Material Particulado/análise , Estações do Ano , China , Cidades , Modelos Teóricos
18.
Huan Jing Ke Xue ; 36(4): 1154-63, 2015 Apr.
Artigo em Chinês | MEDLINE | ID: mdl-26164885

RESUMO

The weather conditions, atmospheric environmental background and formation mechanism of a heavy air pollution episode in Beijing City from January 9th to 15th, 2013 was preliminarily investigated by combining observed data and the WRF meteorology model. The results showed that the average concentration of PM2.5 was 323 µg x m(-3) from January 10th to 14th; the heavy pollution episode was closely related to the local meteorological conditions; the stable atmospheric circulation pattern provided favorable environmental field for the lasting of this heavy air pollution; small wind speed, high humidity, low PBL, and lasting temperature inversion were the main reasons for this heavy air pollution incident; further analysis showed that contributions of regional transmission to the receptor sites in Beijing were between 53% - 69% and there were obvious secondary conversions and transformations; overall regional transportation played a more important role during this serious air pollution incident; the meteorological conditions played a key role in the formation and destruction of the heavy air pollution, therefore we need to strengthen the study on early warning of heavy air pollution, in order to prevent and control the air heavy pollution effectively.


Assuntos
Poluição do Ar/análise , Monitoramento Ambiental , China , Cidades , Umidade , Modelos Teóricos , Temperatura , Tempo (Meteorologia) , Vento
19.
Huan Jing Ke Xue ; 36(11): 3961-71, 2015 Nov.
Artigo em Chinês | MEDLINE | ID: mdl-26910979

RESUMO

Spatial and temporal distribution of SO2 during 2000-2014 was all analyzed based on the SO2 monitoring data that Beijing Municipal Environmental Monitoring Center released and the formation mechanism of a typical air pollution episode in January 2014 was also investigated by combining numerical model CAM(x). Analysis results showed that mass concentration of ρ(SO2) in Beijing in 2014 decreased 69% compared to that in 2000 with an annual gradient from 2000 to 2014 of - 3.5 µg x (m3 x a)(-1). Monthly average concentration of SO2 changed in a U shape curve and from the lowest to the highest, and seasonal variations of SO2 concentrations were as follows: winter > spring > autumn > summer; concentration of SO2 in heating season was significantly higher than that in non heating season. Annual average concentration of SO2 was lower in northern and western regions while higher in six city area and southern area. Concentrations of SO2 at Shijingshan, Dongsi, Tongzhou monitoring sites were significantly decreased related to SO2 emission reduction measures. During a heavy air pollution process in January 14 - 18th 2014 there was obviously SO2 regional transportation and model simulation analysis based on PAST showed that the contribution of SO2 regional transport to Beijing was 83% with elevated power plants surrounding Beijing accounting for 21% and the four major Beijing power plants contributing about 3.5% to the SO2 concentration during this heavy air pollution process.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental , Dióxido de Enxofre/análise , Poluição do Ar , Pequim , Cidades , Modelos Teóricos , Material Particulado/análise , Centrais Elétricas , Estações do Ano , Análise Espaço-Temporal
20.
Huan Jing Ke Xue ; 36(9): 3150-8, 2015 Sep.
Artigo em Chinês | MEDLINE | ID: mdl-26717673

RESUMO

To analyze the impacts of emissions from fireworks on the air quality, monitoring data of PM2.5, PM10, SO2, NO2 chemical compositions of PM2.5 of automatic air quality stations in Beijing during Spring Festival(February 18th-24th) in 2015 were investigated. Moreover, we also estimated the fireworks on the New Year's Eve produced based on the ratio of PM.5 to CO. Analysis results showed that the concentrations of PM2.5, PM10, SO2, NO2 during 2015 Spring Festival was 116. 85, 184.71, 22. 14, and 36. 27 µg.m-3 respectively, which raised 52. 61%, 92. 41%, - 40. 15%, - 0.46% respectively compared to the same period in 2014; the concentration peaks of PM2.5, PM10, SO2, NO2 at 1 : 00 am on 19th was 412. 69, 541. 63, 152. 73, 51. 09 µg.m-3, respectively, which was increased 19. 02%, 14. 37%, 76. 57%, 11. 35% compared to that of 2014; the concentration peaks at dense population area were significantly higher than that in other districts; fireworks had great influence on the chemical compositions of PM2.5 especially on the concentrations of chloride ion, potassium ion, magnesian ion, which were 18. 85, 66. 72, and 70. 10 times than that in 2013-2014; fireworks resulted in severe air pollution in a short time and the estimated fireworks on the New Year's Eve was approximately 2. 13 x 10(5) kg of PM2.5. Reduction of pollutants during Spring Festival had a positive significant impact on air quality in Beijing.


Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental , Férias e Feriados , Poluição do Ar , Pequim , Material Particulado , Estações do Ano
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