Determination of the Long-Term Thermal Performance of Foam Insulation Materials through Heat and Slicing Acceleration.

Foam insulation materials are widely used in the construction industry due to their low thermal conductivity attributable to their microstructures and their low-conductivity blowing agents and affordability. In this study, we evaluate how the thermal performance of foam insulation materials used for the exterior walls of buildings, viz., extruded polystyrene (XPS), polyisocyanurate (PIR), and phenolic foam (PF), age over the life cycle of a building. To compare the aging of thermal performance during the life cycle of a building, each material was tested at 70 and 110 °C and with slicing acceleration according to EN and ISO standards. The thermal conductivity of each foam insulation material was measured using a heat flow meter at an operating temperature of 23 °C and converted into thermal resistance values. Different foam insulation materials have different aging procedures according to material-specific EN standards, while ISO 11561 applies the same procedure to all material classifications. Upon comparing the aged values according to ISO and EN standards to the initial values, the analysis showed a change rate of 23 to 26% in PIR and 18 to 20% in PF. In XPS, a rate of change of 10 to 23.8% was calculated. Our results indicated that the slicing acceleration induced a thermal resistance reduction rate about three times faster than aging at 70 °C. However, the long-term changed thermal resistance values of the foam insulation material applied via the calculating procedure specified in the ISO and EN standards were similar.

An Effective Expanded Graphite Coating on Polystyrene Bead for Improving Flame Retardancy.

Although foamed plastic insulation is widely used in construction in the Korean market, it is vulnerable to fire. To improve the flame retardancy, the method of flame-retardant coating with the EG in water-soluble state on the surface of expanded polystyrene (EPS) beads has been widely used. However, polystyrene beads coated with a water-soluble flame retardant easily separate the coated flame retardant in manufacturing. In this study is devised a flame-retardant coating and two steps of coating process for adhering the flame-retardant coating film evenly to the surface of the polystyrene bead without exfoliation. It was analyzed whether a flame-retardant EPS (FR-EPS) with excellent flame retardancy could be manufactured using polystyrene beads coated in this way. Ten FR-EPS samples satisfied the HF-1 and V-0 levels in horizontal and vertical burning tests, respectively. The THR of eight FR-EPS samples for ten minutes did not exceed 8 MJ∙m-2 and the maximum HRR did not exceed 200 kW∙m-2 for more than ten consecutive seconds. FR-EPS passed the building material standard of semi-nonflammability in Korean regulations, in contrast to commercial EPS, which have not passed the semi-nonflammability standard. It was also analyzed how effective the designed coating is in this study, comparing it with composites that were planned to improve the flame resistance of polystyrene, as reported in the literature. Flame Retardancy Index (FRI) values of FR-EPS proved the "excellent" level and had higher values compared with other polystyrene composites. These results demonstrated that the coated EPS containing a water-soluble flame retardant manufactured from EG and two steps of application with the coating solution achieved fire safety standard regulations.