Alkyne-to-alkene conversion in graphdiyne driving instant reversible deformation of whole carbon film.

The emerging field of soft robotics demands the core actuators and related responsive functional materials with rapid responsiveness and controllable accurate deformation. Here, we developed an alkyne-to-alkene chemical bond conversion way as the driving force to control ultrasensitive and instant reversible deformation of 2D carbon graphdiyne (GDY) film with an asymmetric interface design. The alkyne-to-alkene chemical bond conversion was triggered by acetone through the fast binding and release process. The as-fabricated GDY-based deformation modulator was exhibited to rapidly change shape (within 0.15 seconds) while dipped in an acetone vapor atmosphere and recover to its original form when exposed to air (recovery time < 0.01 seconds), with outstanding properties like large curvature, quick recovery time, excellent stability, and repeatability. It could mimic the movement of mosquito larvae, displaying great promise as micro bionic soft robots. Our results suggest alkyne-to-alkene bond conversion as a unique driving force for developing smart materials for areas like intelligent robotics and bionics.

Ultrasensitive Pressure Sensor Sponge Using Liquid Metal Modulated Nitrogen-Doped Graphene Nanosheets.

Wearable pressure sensors are crucial for real-time monitoring of human activities and biomimetic robot status. Here, the ultrasensitive pressure sensor sponge is prepared by a facile method, realizing ultrasensitive pressure sensing for wearable health monitoring. Since the liquid metal in the sponge-skeleton structure under pressure is conducive to adjust the contact area with nitrogen-doped graphene nanosheets and thus facilitates the charge transfer at the interface, such sensors exhibit a fast response and recovery speed with the response/recovery time 0.41/0.12 s and a comprehensive response range with a sensitivity of up to 476 KPa-1. Notably, the liquid metal-based spongy pressure sensor can accurately monitor the human body's pulse, the pressure on the skin, throat swallowing, and other activities in real time, demonstrating a broad application prospect. Those results provide a convenient and low-cost way to fabricate easily perceptible pressure sensors, expanded the application potential of liquid metal-based composites for future electronic skin development.

Novel Biomimic Crystalline Colloidal Array for Fast Detection of Trace Parathion.

A novel gold doped inverse opal photonic crystal (IO PC) was successfully fabricated with combination of molecularly imprinted technical for the fast determination of parathion. First, a closest silica array arrangement behaved as the 3D photonic crystal precursors to build the opal photonic crystal (O PC). Second, the parathion-containing polymeric solution with gold nanoparticles was drawn into the 3D array cracks. After polymerization, the well-designed O PC was treated with HF solution for the etching of the silica skeleton. Finally, the template parathion was removed and the Au-MIP IO PCs were obtained. The morphology of SiO2 and Au NPs was characterized by transmission electron microscopy (TEM), and the eluted influence of the IO PCs was monitored by scanning electron microscopy (SEM). The cross-linking effect was well optimized according to the best spectrum signal of parathion. The as-synthesized Au-MIP IO PCs displayed the specificity toward parathion and the selectivity to other competitive pesticide molecules. The response time was only 5 min, and the parathion could be well detected from real water samples. The recoveries were between 95.5% and 101.5%.