Low-oxygen rare earth steels.

Rare earth (RE) addition to steels to produce RE steels has been widely applied when aiming to improve steel properties. However, RE steels have exhibited extremely variable mechanical performances, which has become a bottleneck in the past few decades for their production, utilization and related study. Here in this work, we discovered that the property variation of RE steels stems from the presence of oxygen-based inclusions. We proposed a dual low-oxygen technology, and keeping low levels of oxygen content in steel melts and particularly in the raw RE materials, which have long been ignored, to achieve impressively stable and favourable RE effects. The fatigue life is greatly improved by only parts-per-million-level RE addition, with a 40-fold improvement for the tension-compression fatigue life and a 40% enhancement of the rolling contact fatigue life. We find that RE appears to act by lowering the carbon diffusion rate and by retarding ferrite nucleation at the austenite grain boundaries. Our study reveals that only under very low-oxygen conditions can RE perform a vital role in purifying, modifying and micro-alloying steels, to improve the performance of RE steels.

In Situ Passivation on Rear Perovskite Interface for Efficient and Stable Perovskite Solar Cells.

Despite the rocketing rise in power conversion efficiencies (PCEs), the performance of perovskite solar cells (PSCs) is still limited by the carrier transfer loss at the interface between perovskite (PVSK) absorbers and charge transporting layers. Here, we propose a novel in situ passivation strategy by using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) to improve the charge dynamics at the rear PVSK/CTL interface in the n-i-p structure device. A pre-deposited PCBM-doped PbI2 layer is redissolved during PVSK deposition in our routine, establishing a bottom-up PCBM gradient that is facile for charge extraction. Meanwhile, the surface defects are in situ-passivated via PCBM-PVSK interaction, which substantially suppresses the trap-assisted recombination at the rear interface. Due to the synergistic effect of charge-extraction promotion and trap passivation, the fabricated PSCs deliver a champion PCE of 20.10% with attenuated hysteresis and improved long-term stability, much higher than the 18.39% of the reference devices. Our work demonstrates a promising interfacial engineering strategy for further improving the performance of PSCs.

Detection and Assessment of a Large and Potentially Tsunamigenic Periglacial Landslide in Barry Arm, Alaska.

The retreat of glaciers in response to global warming has the potential to trigger landslides in glaciated regions around the globe. Landslides that enter fjords or lakes can cause tsunamis, which endanger people and infrastructure far from the landslide itself. Here we document the ongoing movement of an unstable slope (total volume of 455 × 106 m3) in Barry Arm, a fjord in Prince William Sound, Alaska. The slope moved rapidly between 2010 and 2017, yielding a horizontal displacement of 120 m, which is highly correlated with the rapid retreat and thinning of Barry Glacier. Should the entire unstable slope collapse at once, preliminary tsunami modeling suggests a maximum runup of 300 m near the landslide, which may have devastating impacts on local communities. Our findings highlight the need for interdisciplinary studies of recently deglaciated fjords to refine our understanding of the impact of climate change on landslides and tsunamis.

A Study on the Susceptibility to SCC of 7050 Aluminum Alloy by DCB Specimens.

The stress corrosion cracking (SCC) of different aging states for 7050 aluminum alloy in 3.5% sodium chloride aqueous solution has been studied by means of double cantilever beam (DCB) specimens, cathodic polarization, scanning electron microscope (SEM), transmission electron microscope (TEM) and time-of-flying second ion mass spectrometer (ToF-SIMS). The results showed that the susceptibility to SCC (Iscc) of 7050 aluminum alloy decreases with increasing the aging time. When a cathodic polarization potential of -1100 mV was applied to DCB specimens, the ion current intensity of hydrogen (IH⁺) near the crack tip and Iscc increased obviously, thus the degree of the diffusion of hydrogen into the grain boundary become more serious. The observation of microstructure indicated that the precipitates on the grain boundary become coarse and are sparsely distributed with increasing the aging time of 7050 aluminum alloy.

Active sites and mechanisms for direct oxidation of benzene to phenol over carbon catalysts.

The direct oxidation of benzene to phenol with H2 O2 as the oxidizer, which is regarded as an environmentally friendly process, can be efficiently catalyzed by carbon catalysts. However, the detailed roles of carbon catalysts, especially what is the active site, are still a topic of debate controversy. Herein, we present a fundamental consideration of possible mechanisms for this oxidation reaction by using small molecular model catalysts, Raman spectra, static secondary ion mass spectroscopy (SIMS), DFT calculations, quasi in situ ATR-IR and UV spectra. Our study indicates that the defects, being favorable for the formation of active oxygen species, are the active sites for this oxidation reaction. Furthermore, one type of active defect, namely the armchair configuration defect was successfully identified.

Insight into the mechanism of nanodiamond catalysed decomposition of methane molecules.

Nanodiamond can catalyze the decomposition of methane, and its initial rate is linearly dependent on the number of -CH=CH- defective sites. Thermal treatment improves the ordering of surface atoms, resulting in an inferior activity but a more stable performance over a long period of time, and above 1300 °C few-layered graphene can be found.