1.
Chem Commun (Camb)
; 47(12): 3580-2, 2011 Mar 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21327281
RESUMO
The kinetics of activation of RX by a Cu(I) complex has been investigated in MeCN both in the absence and presence of halide ions. The system Cu(I)/L/X(-) (L = Me(6)TREN) is mainly composed of Cu(I)L(+), XCu(I)L and Cu(I)X(2)(-), but only Cu(I)L(+) is found to be an active catalyst reacting with RX.