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1.
PLoS One ; 19(4): e0301331, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38630769

RESUMO

Fostering equity in undergraduate science, technology, engineering, and mathematics (STEM) programs can be accomplished by incorporating learner-centered pedagogies, resulting in the closing of opportunity gaps (defined here as the difference in grades earned by minoritized and non-minoritized students). We assessed STEM courses that exhibit small and large opportunity gaps at a minority-serving, research-intensive university, and evaluated the degree to which their syllabi are learner-centered, according to a previously validated rubric. We specifically chose syllabi as they are often the first interaction students have with a course, establish expectations for course policies and practices, and serve as a proxy for the course environment. We found STEM courses with more learner-centered syllabi had smaller opportunity gaps. The syllabus rubric factor that most correlated with smaller gaps was Power and Control, which reflects Student's Role, Outside Resources, and Syllabus Focus. This work highlights the importance of course syllabi as a tool for instructors to create more inclusive classroom environments.


Assuntos
Currículo , Engenharia , Humanos , Engenharia/educação , Tecnologia/educação , Estudantes , Matemática
2.
PLoS One ; 17(4): e0264059, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35395005

RESUMO

It is well established that there is a national problem surrounding the equitable participation in and completion of science, technology, engineering, and mathematics (STEM) higher education programs. Persons excluded because of their ethnicity or race (PEERs) experience lower course performance, major retention, sense of belonging, and degree completion. It is unclear though how pervasive these issues are across an institution, from the individual instructor, course, and discipline perspectives. Examining over six years of institutional data from a large-enrollment, research-intensive, minority-serving university, we present an analysis of racial opportunity gaps between PEERs and non-PEERs to identify the consistency of these issues. From this analysis, we find that there is considerable variability as to whether a given course section taught by a single instructor does or does not exhibit opportunity gaps, although encouragingly we did identify exemplar instructors, course-instructor pairs, courses, and departments that consistently had no significant gaps observed. We also identified significant variation across course-instructor pairs within a department, and found that certain STEM disciplines were much more likely to have courses that exhibited opportunity gaps relative to others. Across nearly all disciplines though, it is clear that these gaps are more pervasive in the lower division curriculum. This work highlights a means to identify the extent of inequity in STEM success across a university by leveraging institutional data. These findings also lay the groundwork for future studies that will enable the intentional design of STEM education reform by leveraging beneficial practices used by instructors and departments assigning equitable grades.


Assuntos
Engenharia , Estudantes , Engenharia/educação , Humanos , Matemática , Tecnologia/educação , Universidades
3.
Proc Natl Acad Sci U S A ; 115(20): 5105-5110, 2018 05 15.
Artigo em Inglês | MEDLINE | ID: mdl-29712869

RESUMO

Tidewater glacier fjords are often filled with a collection of calved icebergs, brash ice, and sea ice. For glaciers with high calving rates, this "mélange" of ice can be jam-packed, so that the flow of ice fragments is mostly determined by granular interactions. In the jammed state, ice mélange has been hypothesized to influence iceberg calving and capsize, dispersion and attenuation of ocean waves, injection of freshwater into fjords, and fjord circulation. However, detailed measurements of ice mélange are lacking due to difficulties in instrumenting remote, ice-choked fjords. Here we characterize the flow and associated stress in ice mélange, using a combination of terrestrial radar data, laboratory experiments, and numerical simulations. We find that, during periods of terminus quiescence, ice mélange experiences laminar flow over timescales of hours to days. The uniform flow fields are bounded by shear margins along fjord walls where force chains between granular icebergs terminate. In addition, the average force per unit width that is transmitted to the glacier terminus, which can exceed 107 N/m, increases exponentially with the mélange length-to-width ratio. These "buttressing" forces are sufficiently high to inhibit the initiation of large-scale calving events, supporting the notion that ice mélange can be viewed as a weak granular ice shelf that transmits stresses from fjord walls back to glacier termini.

4.
CBE Life Sci Educ ; 16(4)2017.
Artigo em Inglês | MEDLINE | ID: mdl-29196430

RESUMO

Recent calls for improvement in undergraduate education within STEM (science, technology, engineering, and mathematics) disciplines are hampered by the methods used to evaluate teaching effectiveness. Faculty members at research universities are commonly assessed and promoted mainly on the basis of research success. To improve the quality of undergraduate teaching across all disciplines, not only STEM fields, requires creating an environment wherein continuous improvement of teaching is valued, assessed, and rewarded at various stages of a faculty member's career. This requires consistent application of policies that reflect well-established best practices for evaluating teaching at the department, college, and university levels. Evidence shows most teaching evaluation practices do not reflect stated policies, even when the policies specifically espouse teaching as a value. Thus, alignment of practice to policy is a major barrier to establishing a culture in which teaching is valued. Situated in the context of current national efforts to improve undergraduate STEM education, including the Association of American Universities Undergraduate STEM Education Initiative, this essay discusses four guiding principles for aligning practice with stated priorities in formal policies: 1) enhancing the role of deans and chairs; 2) effectively using the hiring process; 3) improving communication; and 4) improving the understanding of teaching as a scholarly activity. In addition, three specific examples of efforts to improve the practice of evaluating teaching are presented as examples: 1) Three Bucket Model of merit review at the University of California, Irvine; (2) Evaluation of Teaching Rubric, University of Kansas; and (3) Teaching Quality Framework, University of Colorado, Boulder. These examples provide flexible criteria to holistically evaluate and improve the quality of teaching across the diverse institutions comprising modern higher education.


Assuntos
Cultura , Políticas , Pesquisa/educação , Recompensa , Ensino , Universidades , Currículo , Feminino , Humanos , Masculino , Modelos Educacionais , Estudantes
5.
Soft Matter ; 13(24): 4402, 2017 06 21.
Artigo em Inglês | MEDLINE | ID: mdl-28597897

RESUMO

Correction for 'Stable small bubble clusters in two-dimensional foams' by Kai Zhang et al., Soft Matter, 2017, DOI: .

6.
Soft Matter ; 13(24): 4370-4380, 2017 Jun 21.
Artigo em Inglês | MEDLINE | ID: mdl-28513729

RESUMO

Key features of the mechanical response of amorphous particulate materials, such as foams, emulsions, and granular media, to applied stress are determined by the frequency and size of particle rearrangements that occur as the system transitions from one mechanically stable state to another. This work describes coordinated experimental and computational studies of bubble rafts, which are quasi-two dimensional systems of bubbles confined to the air-water interface. We focus on small mechanically stable clusters of four, five, six, and seven bubbles with two different sizes with diameter ratio σL/σS ≃ 1.4. Focusing on small bubble clusters, which can be viewed as subsystems of a larger system, allows us to investigate the full ensemble of clusters that form, measure the respective frequencies with which the clusters occur, and determine the form of the bubble-bubble interactions. We emphasize several important results. First, for clusters with N > 5 bubbles, we find using discrete element simulations that short-range attractive interactions between bubbles give rise to a larger ensemble of distinct mechanically stable clusters compared to that generated by long-range attractive interactions. The additional clusters in systems with short-range attractions possess larger gaps between pairs of neighboring bubbles on the periphery of the clusters. The ensemble of bubble clusters observed in experiments is similar to the ensemble of clusters with long-range attractive interactions. We also compare the frequency with which each cluster occurs in simulations and experiments. We find that the cluster frequencies are extremely sensitive to the protocol used to generate them and only weakly correlated to the energy of the clusters.

7.
Phys Rev E ; 93(3): 032613, 2016 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-27078420

RESUMO

We report on the collapse of bubble rafts under compression in a closed rectangular geometry. A bubble raft is a single layer of bubbles at the air-water interface. A collapse event occurs when bubbles submerge beneath the neighboring bubbles under compression, causing the structure of the bubble raft to go from single-layer to multilayer. We studied the collapse dynamics as a function of compression velocity. At higher compression velocity we observe a more uniform distribution of collapse events, whereas at lower compression velocities the collapse events accumulate at the system boundaries. We propose that this system can be understood in terms of a linear elastic sheet coupled to a local internal (Ising) degree of freedom. The two internal states, which represent one bubble layer versus two, couple to the elasticity of the sheet by locally changing the reference state of the material. By exploring the collapse dynamics of the bubble raft, one may address the basic nonlinear mechanics of a number of complex systems in which elastic stress is coupled to local internal variables.

8.
Biophys J ; 107(7): 1573-81, 2014 Oct 07.
Artigo em Inglês | MEDLINE | ID: mdl-25296309

RESUMO

We study the impact of the addition of particles of a range of sizes on the phase transition behavior of lung surfactant under compression. Charged particles ranging from micro- to nanoscale are deposited on lung surfactant films in a Langmuir trough. Surface area versus surface pressure isotherms and fluorescent microscope observations are utilized to determine changes in the phase transition behavior. We find that the deposition of particles close to 20 nm in diameter significantly impacts the coexistence of the liquid-condensed phase and liquid-expanded phase. This includes morphological changes of the liquid-condensed domains and the elimination of the squeeze-out phase in isotherms. Finally, a drastic increase of the domain fraction of the liquid-condensed phase can be observed for the deposition of 20-nm particles. As the particle size is increased, we observe a return to normal phase behavior. The net result is the observation of a critical particle size that may impact the functionality of the lung surfactant during respiration.


Assuntos
Tamanho da Partícula , Transição de Fase , Surfactantes Pulmonares/química , Pressão , Propriedades de Superfície , Temperatura
9.
Artigo em Inglês | MEDLINE | ID: mdl-23767541

RESUMO

We study the power-law scaling behavior and pinch-off morphology of two-dimensional bubble rafts under tension. As a function of pulling speed, we observe two distinct pinch-off morphologies that have been observed in other fluid systems: long threads (LT) and double-cone (DC). At any given pulling speed, there is a nonzero probability of observing LT or DC, with the probability of observing LT modes increasing with pulling velocity. The bubble rafts are composed of millimeter scale bubbles, and we are able to directly observe pinch-off to the point of final separation and measure the scaling of the minimum width in time. For both the LT and DC modes, the final scaling regime before pinch-off exhibits a universal power-law scaling behavior, with power-law fitting exponents of 0.73 ± 0.01. However, the final cone angle is different for states that initially exhibit LT or DC pinch-off, and for the LT case, the final scaling is best described as a local double-cone mode.


Assuntos
Gases/química , Modelos Químicos , Modelos Moleculares , Simulação por Computador , Estresse Mecânico , Resistência à Tração
10.
Phys Rev Lett ; 110(13): 137802, 2013 Mar 29.
Artigo em Inglês | MEDLINE | ID: mdl-23581375

RESUMO

Microrheological studies of phospholipid monolayers, bilayers, and other Langmuir monolayer systems are traditionally performed by observing the thermal fluctuations of tracers attached to the membrane or interface. Measurements of this type obtain surface moduli that are orders of magnitude different from those obtained using macroscopic or active techniques. These large discrepancies can result from uncertainties in the tracer's coupling to the monolayer or the local disruption of the monolayer by the tracer. To avoid such problems, we perform a microrheological experiment with the tracer particle placed at a known depth beneath the monolayer; this avoids the issues mentioned at the cost of generating a weaker, purely hydrodynamic coupling between the tracer and the monolayer. We calculate the appropriate response functions for this submerged particle microrheology and demonstrate the technique on three model monolayer systems.

11.
Langmuir ; 28(39): 13976-83, 2012 Oct 02.
Artigo em Inglês | MEDLINE | ID: mdl-22921324

RESUMO

We report on the impact of differently sized particles on the collapse of a Langmuir monolayer. We use an SDS-DODAB monolayer because it is known to collapse reversibly under compression and expansion cycles. Particles with diameters of 1 µm, 0.5 µm, 0.1 µm, and 20 nm are deposited on the SDS-DODAB monolayer. We find a critical particle size range of 0.1 to 0.5 µm that produces a transition from reversible to irreversible collapse. The nature of the collapse is determined through optical observations and surface pressure measurements. In addition, although 20 nm particles do not cause irreversible collapse in the monolayer, they significantly decrease the collapse pressure relative to the other systems. Therefore, we observe three distinct collapse behaviors-reversible, irreversible, and reversible at a reduced surface pressure.


Assuntos
Compostos de Amônio Quaternário/química , Dodecilsulfato de Sódio/química , Tamanho da Partícula , Propriedades de Superfície
12.
Langmuir ; 26(15): 12755-60, 2010 Aug 03.
Artigo em Inglês | MEDLINE | ID: mdl-20590121

RESUMO

The collapse dynamics of giant folds in a catanionic monolayer at the air-water interface are examined. A monolayer of dioctadecyldimethylammonium bromide (DODAB) and sodium dodecyl sulfate (SDS) in a 1:1 ratio is the system of study that previously was found to fold upon compression in a Langmuir trough. Carboxylate-coated polystyrene beads (1 microm diameter) are deposited and bound to the monolayer. Displacement of the beads is measured with epifluorescence microscopy and particle image velocimetry, yielding a measurement of the velocity of the monolayer around the fold. Reversibility is confirmed by measuring the amount of monolayer material entering and leaving the fold. Material near folds are found to have a maximum relative velocity on the order of 0.1 mm/s, and fold depths are found to be on the order of 1 mm. The folds exhibit regular unfolding behavior, which can be explained qualitatively by a simple mechanical model.


Assuntos
Compostos de Amônio Quaternário/química , Cátions/química , Microscopia de Fluorescência , Microesferas , Poliestirenos/química , Propriedades de Superfície
13.
Phys Rev E Stat Nonlin Soft Matter Phys ; 79(4 Pt 1): 041405, 2009 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-19518231

RESUMO

A fundamental difference between fluids and solids is their response to applied shear. Solids possess static shear moduli, while fluids do not. Complex fluids such as foams display an intermediate response to shear with nontrivial frequency-dependent shear moduli. In this paper, we conduct coordinated experiments and numerical simulations of model foams subjected to boundary-driven oscillatory planar shear. Our studies are performed on bubble rafts (experiments) and the bubble model (simulations) in two dimensions. We focus on the low-amplitude flow regime in which T1 events, i.e., bubble rearrangement events where originally touching bubbles switch nearest neighbors, do not occur, yet the system transitions from solid- to liquidlike behavior as the driving frequency is increased. In both simulations and experiments, we observe two distinct flow regimes. At low frequencies omega, the velocity profile of the bubbles increases linearly with distance from the stationary wall, and there is a nonzero total phase shift between the moving boundary and interior bubbles. In this frequency regime, the total phase shift scales as a power law Delta approximately omegan with n approximately 3. In contrast, for frequencies above a crossover frequency omega>omegap, the total phase shift Delta scales linearly with the driving frequency. At even higher frequencies above a characteristic frequency omeganl>omegap, the velocity profile changes from linear to nonlinear. We fully characterize this transition from solid- to liquidlike flow behavior in both the simulations and experiments and find qualitative and quantitative agreements for the characteristic frequencies.

14.
Langmuir ; 25(9): 5006-11, 2009 May 05.
Artigo em Inglês | MEDLINE | ID: mdl-19301830

RESUMO

The behavior of the catanionic system of dioctadecyldimethylammonium bromide (DODAB) and sodium dodecyl sulfate (SDS) was investigated at 23 +/- 1 degrees C at the air-water interface using a Langmuir trough. The surface pressure as a function of surface area was measured while monitoring domain structures using epifluorescence microscopy. At high surface densities, the monolayer exhibits collapse through reversible folding at about 47 mN m(-1). This corresponds to the DODAB collapse surface pressure. The number of folds increases with the rate of compression speed and is history-dependent.


Assuntos
Corantes Fluorescentes/química , Cátions/química , Microscopia de Fluorescência , Estrutura Molecular
15.
Phys Rev E Stat Nonlin Soft Matter Phys ; 78(5 Pt 1): 051504, 2008 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-19113133

RESUMO

Shear banding is an important feature of flow in complex fluids. Essentially, shear bands refer to the coexistence of flowing and nonflowing regions in driven material. Understanding the possible sources of shear banding has important implications for a wide range of flow applications. In this regard, quasi-two-dimensional flow offers a unique opportunity to study competing factors that result in shear bands. One proposal for interpretation and analysis is the competition between intrinsic dissipation and an external source of dissipation. In this paper, we report on the experimental observation of the transition between different classes of shear bands that have been predicted to exist in cylindrical geometry as the result of this competition [R. J. Clancy, E. Janiaud, D. Weaire, and S. Hutzlet, Eur. J. Phys. E 21, 123 (2006)].

16.
Rev Sci Instrum ; 79(6): 063905, 2008 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-18601415

RESUMO

A Langmuir monolayer trough that is equipped for simultaneous microrheology and standard rheology measurements has been constructed. The central elements are the trough itself with a full range of optical tools accessing the air-water interface from below the trough and a portable knife-edge torsion pendulum that can access the interface from above. The ability to simultaneously measure the mechanical response of Langmuir monolayers on very different length scales is an important step for our understanding of the mechanical response of two-dimensional viscoelastic networks.


Assuntos
Bicamadas Lipídicas/química , Reologia/instrumentação , Lipossomas Unilamelares/química , Reologia/métodos , Viscosidade
17.
Phys Rev E Stat Nonlin Soft Matter Phys ; 77(4 Pt 1): 041505, 2008 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-18517626

RESUMO

For crystalline materials, the microscopic origin of plasticity is well understood in terms of the dynamics of topological defects. For amorphous materials, the underlying structural disorder prevents such a description. Therefore identifying and characterizing the microscopic plastic events in amorphous materials remains an important challenge. We show direct evidence for the coexistence of reversible and irreversible plastic events (T1 events) at the microscopic scale in both experiments and simulations of two-dimensional foam. In the simulations, we also demonstrate a link between the reversibility of T1 events and pathways in the potential energy landscape of the system.

18.
Phys Rev E Stat Nonlin Soft Matter Phys ; 77(1 Pt 1): 011909, 2008 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-18351878

RESUMO

We report on the surface rheology of cross-linked F-actin networks associated with a lipid monolayer at the air-water interface of a Langmuir monolayer. The rheological measurements are made using a Couette cell. These data demonstrate that the network has a finite elastic modulus that grows as a function of the cross-linking concentration. We also note that under steady-state flow the system behaves as a power-law fluid in which the effective viscosity decreases with imposed shear.


Assuntos
Actinas/química , Actinas/ultraestrutura , Proteínas do Citoesqueleto/química , Bicamadas Lipídicas/química , Microfluídica/métodos , Modelos Químicos , Modelos Moleculares , Simulação por Computador , Elasticidade , Complexos Multiproteicos/química , Complexos Multiproteicos/ultraestrutura , Conformação Proteica , Estresse Mecânico , Propriedades de Superfície , Viscosidade
19.
Soft Matter ; 4: 2019-2029, 2008 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-19657472

RESUMO

Surfactants at air/water interfaces are often subjected to mechanical stresses as the interfaces they occupy are reduced in area. The most well characterized forms of stress relaxation in these systems are first order phase transitions from lower density to higher density phases. Here we study stress relaxation in lipid monolayers that occurs once chemical phase transitions have been exhausted. At these highly compressed states, the monolayer undergoes global mechanical relaxations termed collapse. By studying four different types of monolayers, we determine that collapse modes are most closely linked to in-plane rigidity. We characterize the rigidity of the monolayer by analyzing in-plane morphology on numerous length scales. More rigid monolayers collapse out-of-plane via a hard elastic mode similar to an elastic membrane, while softer monolayers relax in-plane by shearing.

20.
Phys Rev Lett ; 98(22): 220602, 2007 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-17677828

RESUMO

In equilibrium systems, time and ensemble averages of physical quantities are equivalent due to ergodic exploration of phase space. In driven systems, it is unknown if a similar equivalence of time and ensemble averages exists. We explore effective limits of such convergence in a sheared bubble raft using averages of the bubble velocities. In independent experiments, averaging over time leads to well-converged velocity profiles. However, the time averages from independent experiments result in distinct velocity averages. Ensemble averages are approximated by randomly selecting bubble velocities from independent experiments. Increasingly better approximations of ensemble averages converge toward a unique velocity profile. Therefore, the experiments establish that in practical realizations of nonequilibrium systems, temporal averaging and ensemble averaging can yield convergent (stationary) but distinct distributions.

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