RESUMO
This study investigated the MBR performance, sludge morphology, and membrane fouling potential in treating sunflower oil refinery wastewater containing high oleic acid at three different SRTs of 10 days, 40 days, and infinite. The analysis of mixed liquor morphology including sludge volume index, PSD, EPS, and SMP showed that the sludge flocs compressibility and bioflocculation considerably improved at 40-days SRT. Additionally, at this SRT, the mixed liquor O&G, COD, and SMP accumulation were low, and the microbial activity and COD removal were enhanced. The gas chromatography/mass spectrometry analysis results confirmed the formation of three different new compounds related to non-readily biodegradable recalcitrant oily compounds and SMP at all SRTs. The analysis of mixed liquor EPS, PSD, SMP, and effluent COD at three different SRTs suggests that under the industrial conditions of MBR operation treating SORW with high oleic acid, the optimal operating conditions are predicted to be at 40-days SRT.