RESUMO
This study investigates the effectiveness of kaolin and bentonite catalysts in improving liquid hydrocarbon yields during the pyrolysis of waste tires. Raw clay, nitric acid-treated clay, and mono- or bimetal-impregnated clay were used as catalysts in the pyrolysis of waste tire. Acid-treated kaolin produced a higher yield of liquid hydrocarbons (43.24-47%) compared to acid-treated bentonite (35.34-41.85%). This improvement in the liquid yield can be attributed to the higher specific surface area and pore diameter of the acid-treated clay in comparison to raw kaolin (39.48%) and raw bentonite (31.62%). Moreover, the use of metal-impregnated catalysts, such as Fe/kaolin and Ni/Fe/kaolin, resulted in higher liquid yields (47%) compared to the 3 M HNO3-treated kaolin catalyst (43.24%). Gas chromatography-mass spectrometry (GC-MS) analysis confirmed the presence of limonene, a crucial ingredient for commercial perfume production, in the liquid products. The calorific values of oil obtained through kaolin and bentonite catalysis were measured at 13,922 and 10,174 kcal/kg, respectively, further highlighting the potential of these catalysts in waste tire valorization.
RESUMO
The Barail sandstone in the Surma Basin is a medium- to coarse-grained pinkish-colored rock exposed near the northeastern margin of Bangladesh. In this study, we evaluated the reservoir quality of the Barail sandstone based on its petrophysical and petrographic characteristics. Petrophysical analyses of outcropped samples showed that sandstones are made up of 16.48% porosity and 132.48 mD permeability. Sandstone density ranges from 1.94 g/cm3 to 2.37 g/cm3, with a mean value of 2.12 g/cm3, shown as moderately compacted sandstone. Integrated data such as bulk density, porosity, permeability, Rock Quality Index (RQI), Normalized Porosity Index (NPI), Flow Zone Indicator (FZI), compressive strength, etc. with their relationships indicate that Barail sandstone owing characters to become a good petroleum reservoir. The rock samples consisted mainly of quartz with an insignificant amount of rock fragments and plagioclase feldspar and are categorized as sub-arkose to sub-litharenite. The rock samples also contains lithic (andesine, microcline, muscovite, biotite, etc.) of granitic and gneissic fabric and some volcanic product like aguite, albite, andesine, garnet, spinel and ulvo-spinel indicating the source of nearby orogeny. The euhedral to subhedral shape of the quartz grain in a porphyritic texture, moderately sorted with a smaller amount of clay minerals indicating the moderately mature rock type. The iron oxide border around the quartz grain also indicates that the Barail sandstone was deposited under dry climatic condition.