RESUMO
An energy storage device--a coaxial single fibre supercapacitor--was developed using a dip coating method and characterised using electrochemical methods. The specific capacitance per unit area and length were calculated to be 3.18 mF cm(-2) and 0.1 mF cm(-1), respectively, for a 2.6 cm supercapacitor. A 70 cm long fibre supercapacitor was then woven into a piece of fabric. Following characterisation using cyclic voltammetry, we found that this device had the same capacitance as its original value before integration into the fabric.
RESUMO
Phosphorescent copper(I) complexes carrying 2,2'-bipyridyl derivatives and phosphine ligands have been prepared and fully characterised. The role of the bipyridyl as well as the phosphine ligands in defining the optical, as well as the chemical properties of the complexes, are discussed. The light emission of these complexes is investigated as a function of the molecular geometry: rigid complexes with restricted freedom to rearrange in the excited state are found to show a quantum yield of phosphorescence one order of magnitude higher than those complexes with no steric constraint. The complexes have been extruded in a polymer matrix as a proof of principle of their processability.
RESUMO
An electric-field-assisted method to produce diffractive optical devices is demonstrated. A uniform film of liquid UV curable resin was produced as a drying ring from an organic solvent. Dielectrophoresis forces maintained the stability of the thin film and also imprinted a periodic corrugation deformation of pitch 20 µm on the film surface. Continuous in situ voltage-controlled adjustment of the optical diffraction pattern was carried out simultaneously with UV curing. A fully cured solid phase grating was produced with the particular voltage-selected tailored optical property that the zero transmitted order was suppressed for laser light at 633 nm.