RESUMO
Significant advancements have been made in the development of CO2 reduction processes for applications such as electrosynthesis, energy storage, and environmental remediation. Several materials have demonstrated great potential in achieving high activity and selectivity for the desired reduction products. Nevertheless, these advancements have primarily been limited to small-scale laboratory settings, and the considerable technical obstacles associated with large-scale CO2 reduction have not received sufficient attention. Many of the researchers have been faced with persistent challenges in the catalytic process, primarily stemming from the low Faraday efficiency, high overpotential, and low limiting current density observed in the production of the desired target product. The highlighted materials possess the capability to transform CO2 into various oxygenates, including ethanol, methanol, and formates, as well as hydrocarbons such as methane and ethane. A comprehensive summary of the recent research progress on these discussed types of electrocatalysts is provided, highlighting the detailed examination of their electrocatalytic activity enhancement strategies. This serves as a valuable reference for the development of highly efficient electrocatalysts with different orientations. This review encompasses the latest developments in catalyst materials and cell designs, presenting the leading materials utilized for the conversion of CO2 into various valuable products. Corresponding designs of cells and reactors are also included to provide a comprehensive overview of the advancements in this field.
RESUMO
Metal-air batteries and fuel cells are considered the most promising highly efficient energy storage systems because they possess long life cycles, high carbon monoxide (CO) tolerance, and low fuel crossover ability. The use of energy storage technology in the transport segment holds great promise for producing green and clean energy with lesser greenhouse gas (GHG) emissions. In recent years, nanoscale based electrocatalysts have shown remarkable electrocatalytic performance towards the construction of sustainable energy-related devices/applications, including fuel cells, metal-air battery and water-splitting processes. This review summarises the recent advancement in the development of nanoscale-based electrocatalysts and their energy-related electrocatalytic applications. Further, we focus on different synthetic approaches employed to fabricate the nanomaterial catalysts and also their size, shape and morphological related electrocatalytic performances. Following this, we discuss the catalytic reaction mechanism of the electrochemical energy generation process, which provides close insight to develop a more efficient catalyst. Moreover, we outline the future perspectives and challenges pertaining to the development of highly efficient nanoscale-based electrocatalysts for green energy storage technology.