RESUMO
BACKGROUND: Elemental mapping (EM) yields necessary insights into mechanisms of interest in solid samples across multiple disciplines. There are several EM techniques available but long acquisition time is a common limitation. Glow discharge optical emission spectroscopy (GDOES) allows direct quantitative multi-EM at very high throughput (â¼10 s s) when coupled to traditional hyperspectral imaging (HSI) techniques. However, GDOES consumes the sample via sputtering, such that traditional HSI sequential scanning requirements lead to loss of information/resolution, which is compounded for multi-EM and limits nanomaterials analysis. Thus, there is a need for faster HSI to enable GDOES multi-EM of nanoscale materials. RESULTS: Here, a new technique is described, Glow discharge Optical emission Coded Aperture elemental Mapping (GOCAM), that takes advantage of compressive coded aperture spectral imaging to enable multi-EM in a single camera exposure. In this first phase of development, computer model simulations were implemented to study the effects of coded aperture parameters on data fidelity, which showed the best fidelity is achieved at smaller mask element sizes and transmittance of 60 %. In addition, SeSCIGPU demonstrated the best fidelity performance compared to several compressed sensing reconstruction algorithms, including TwIST, GAP-TV, SeSCICPU, and ADMM-TV, as evaluated by studying the effects of varying the corresponding hyperparameters. SIGNIFICANCE: This study shows GOCAM's feasibility and provides a starting point for the second phase hardware development currently underway. GOCAM's potential to allow multi-EM from solid surfaces in a fraction of a second will be particularly enabling for nanostructured materials characterization.
RESUMO
The almost-two-centuries history of spectrochemical analysis has generated a body of literature so vast that it has become nearly intractable for experts, much less for those wishing to enter the field. Authoritative, focused reviews help to address this problem but become so granular that the overall directions of the field are lost. This broader perspective can be provided partially by general overviews but then the thinking, experimental details, theoretical underpinnings and instrumental innovations of the original work must be sacrificed. In the present compilation, this dilemma is overcome by assembling the most impactful publications in the area of analytical atomic spectrometry. Each entry was proposed by at least one current expert in the field and supported by a narrative that justifies its inclusion. The entries were then assembled into a coherent sequence and returned to contributors for a round-robin review.