Visible-to-Near-Infrared Mechanoluminescence in Bi-Activated Spinel Compounds for Multiple Information Anticounterfeiting.

Mechanoluminescence (ML) is the nonthermal luminescence generated in the process of force-to-light conversion, which has broad prospects in stress sensing, wearable devices, biomechanics, and multiple information anticounterfeiting. Multivalence emitter ions utilize their own self-reduction process to realize multiband ML without introducing another dopant, such as Eu3+/Eu2+, Sm3+/Sm2+, and Mn4+/Mn2+. However, self-reduction-induced ML in bismuth-activated materials has rarely been reported so far. In this work, a novel visible-to-near-infrared (vis-NIR) ML induced by the self-reduction of Bi3+ to Bi2+ in the spinel-type compound (MgGa2O4) is reported. The photoluminescence (PL) spectra, PL excitation (PLE) spectra, and PL lifetime curves demonstrate that Bi3+/Bi2+ ions are the main luminescence centers. Notably, the possible self-reduction model is proposed, where a magnesium vacancy (VMg″) is considered as the driving force for the self-reduction of Bi3+ to Bi2+. Furthermore, an oxygen vacancy (VO••) is confirmed by electron paramagnetic resonance (EPR) spectroscopy. Combined with thermoluminescence (TL) glow curves and ML spectra, a plausible trap-controlled ML mechanism is illustrated, where electron-hole (VO••/VMg″) pairs play a significant role in capturing electrons and holes. It is worth noting that the proof-of-concept dual-mode electronic signature application is implemented based on the flexible ML film, which improves the capabilities of signature anticounterfeiting for high-level security applications. Besides, multistimulus-responsive luminescence behaviors of the ML film are realized under the excitation of a 254 nm UV lamp, thermal disturbance, 980 nm laser, and mechanical stimuli. In general, this study provides new insights into designing vis-NIR ML materials toward wider application possibilities.

Enhanced Thermoelectric Properties of Bi2 Te3 -Based Micro-Nano Fibers via Thermal Drawing and Interfacial Engineering.

High-performance thermoelectric (TE) materials with great flexibility and stability are urgently needed to efficiently convert heat energy into electrical power. Recently, intrinsically crystalline, mechanically stable, and flexible inorganic TE fibers that show TE properties comparable to their bulk counterparts have been of interest to researchers. Despite remarkable progress in moving TE fibers toward room-temperature TE conversion, the figure-of-merit value (ZT) and bending stability still need enhancement. Herein, interfacial-engineering-enhanced TE properties of micro-nano polycrystalline TE fibers fabricated by thermally drawing Bi2 Te3 -based bulks in a glass-fiber template are reported. The interfacial engineering effect comes from generating stress-induced oriented nanocrystals to increase electrical conductivity and producing strain-distorted interfaces to decrease thermal conductivity. The 4 µm-diameter fibers achieve a 40% higher ZT (≈1.4 at 300 K) than their bulk counterparts and show a reversible bending radius of 50 µm, approaching the theoretical elastic limit. This fabrication strategy works for a wide range of inorganic TE materials and benefits the development of fiber-based micro-TE devices.

Mn2+-activated dual-wavelength emitting materials toward wearable optical fibre temperature sensor.

Photothermal sensing is crucial for the creation of smart wearable devices. However, the discovery of luminescent materials with suitable dual-wavelength emissions is a great challenge for the construction of stable wearable optical fibre temperature sensors. Benefiting from the Mn2+-Mn2+ superexchange interactions, a dual-wavelength (530/650 nm)-emitting material Li2ZnSiO4:Mn2+ is presented via simple increasing the Mn2+ concentration, wherein the two emission bands have different temperature-dependent emission behaviours, but exhibit quite similar excitation spectra. Density functional theory calculations, coupled with extended X-ray absorption fine structure and electron-diffraction analyses reveal the origins of the two emission bands in this material. A wearable optical temperature sensor is fabricated by incorporating Li2ZnSiO4:Mn2+ in stretchable elastomer-based optical fibres, which can provide thermal-sensitive emissions at dual- wavelengths for stable ratiometric temperature sensing with good precision and repeatability. More importantly, a wearable mask integrated with this stretchable fibre sensor is demonstrated for the detection of physiological thermal changes, showing great potential for use as a wearable health monitor. This study also provides a framework for creating transition-metal-activated luminescence materials.

Experimental Study on Glaze Icing Detection of 110 kV Composite Insulators Using Fiber Bragg Gratings.

Icing detection of composite insulators is essential for the security and stability of power grids. As conventional methods have met difficulties in harsh weather, a 110 kV composite insulator with embedded Fiber Bragg Gratings (FBGs) was proposed for detecting glaze icing in this paper. FBG temperature compensation sensors in ceramic tubes were adopted for simultaneous measurement of icicle loads and temperature. Then, temperature calibration experiments and simulated icicle load experiments were carried out to obtain temperature and icicle load characteristics of FBGs. The results showed that temperature sensitivities of FBG strain sensors and FBG temperature compensation sensors were 18.16 pm/°C, and 13.18 pm/°C, respectively. Besides, wavelength shifts were linearly related to icicle loads within the polar angle range of -60° to 60°, and the load coefficient of FBG facing the icicle was -34.6 pm/N. In addition, the wavelength shift generated by several icicles was equal to the sum of wavelength shifts generated by each icicle within the polar angle range of -15° to 15°. Finally, icicles can cause wavelength shifts of FBGs within a big shed spacing. The paper provides a novel icing detection technology for composite insulators in transmission lines.

Microlasers from AIE-Active BODIPY Derivative.

Organic microlasers have attracted much attention due to their unique features such as high mechanical flexibility, facile doping of gain materials, high optical quality, simplicity and low-cost fabrication. However, organic gain materials usually suffer from aggregation-caused quenching (ACQ), preventing further advances of organic microlasers. Here, a new type of microlaser from aggregation-induced emission (AIE) material is successfully demonstrated. By introducing a typical noncrystalline AIE material, a high quality microlaser is obtained via a surface tension-induced self-assembly approach. Distinct from conventional organic microlasers, the organic luminescent material used here is initially nonluminescent but can shine after aggregation under optical pumping. Further investigations demonstrate that AIE-based microlasers exhibit advantages to enable much higher doping concentrations, which provides an alternative way to improved lasing performance including dramatically reduced threshold and favorable lasing stability. It is believed that these results could provide a promising way to extend the content of microlasers and open a new avenue to enable applications ranging from chemical sensing to biology.

Controlled dye release from a metal-organic framework: a new luminescent sensor for water.

By introducing the dye Rhodamine 6G (R6G) into a metal-organic framework (MOF), Mn-sdc-2 (H2sdc = 4,4'-stilbenedicarboxylic acid), with a pore size of 20 × 9.8 Å2, the composite R6G@Mn-sdc-2 was obtained. Subsequently, the MOF Mn-sdc-1 with a smaller pore size of 7.5 × 7.5 Å2 can be formed through a single-crystal to single-crystal transformation from Mn-sdc-2, thus tightly locking the dye R6G within the pores. Compared with R6G@Mn-sdc-2, R6G@Mn-sdc-1 exhibits a stronger fluorescence emission of R6G. Because the MOF Mn-sdc-1 can reversibly transform back to Mn-sdc-2 in the presence of trace water, the dye R6G can be released. This enables R6G@Mn-sdc-1 to be used as a new luminescent sensor for trace water in organic solvents by monitoring the fluorescence intensity of released R6G. The limit of detection can reach 0.035% in ethanol (v : v), which is among the most sensitive fluorescent water probes.

Detection of Glaze Icing Load and Temperature of Composite Insulators Using Fiber Bragg Grating.

Conventional methods for the online monitoring of icing conditions of composite insulators suffer from difficulties. To solve this issue, a novel method is first proposed to detect glaze icing load via embedding three optical fibers with fiber Bragg gratings (FBGs) into a 10 kV composite insulator. Specifically, FBG temperature compensation sensors were packaged in ceramic tubes to solve strain and temperature cross-sensitivity. Temperature effect experiments and simulated glaze icing load experiments were performed to verify the feasibility of the proposed method. The results show that temperature sensitivities of all FBGs are identical (i.e., 10.68 pm/°C), which achieves a simultaneous measurement of temperature and strain. In addition, the proposed method can detect glaze icing load of the composite insulator above 0.5 N (i.e., 15% of icicle bridged degree) in the laboratory.

All-fiber stable orbital angular momentum beam generation and propagation.

An all-fiber scheme for stable orbital angular momentum (OAM) beam generation and propagation is proposed and demonstrated. This scheme is based on a self-designed and manufactured graded-index few mode fiber (GI-FMF) and compatible mode selection coupler (MSC). The MSC, which consists of a conventional single mode fiber (SMF) and the GI-FMF, can effectively couple the fundamental mode in the SMF to the desired OAM mode in the GI-FMF based on phase matching condition. Meanwhile, the GI-FMF breaks the degeneracy between the desired eigenmodes and neighboring vector modes, thereby allowing the preservation and propagation of the selectively excited OAM modes. As a proof-of-principle, we have implemented an all-fiber device operating in stable OAM modes with |l| = 1. The experimental results show stable propagation of OAM beams with the mode purity of ∼95% and bandwidth of 100 nm. This all fiber device could be useful for further development of wide bandwidth OAM mode division multiplexed application.

Transverse mode switchable all-fiber Brillouin laser.

A transverse mode switchable all-fiber Brillouin laser architecture is proposed. This laser architecture consists mainly of an optical switch, a set of cascaded mode selection couplers (MSCs), and a few-mode fiber ring cavity. By switching the output signal of the optical switch, specific transverse modes generated by MSCs can be coupled into the ring cavity to excite the corresponding Brillouin scattering light. Based on the Brillouin nonlinear effect, the desired mode resonant amplification is guaranteed, and a transverse mode switchable laser beam is obtained. As a proof of principle, we have implemented an all-fiber Brillouin laser with switchable output of fundamental transverse (LP01) mode and second-order transverse (LP11) mode at the wavelength of 1550 nm. The slope efficiency and linewidth for LP01 and LP11 modes are 25.1% and 4.9 kHz, 20.9% and 4.96 kHz, respectively. Additionally, the orbital angular momentum laser beam with l=+1, -1, or 0 switchable output is also demonstrated from our all-fiber Brillouin laser system. Owing to the compact all-fiber architecture, this transverse mode switchable Brillouin fiber laser is reliable during long-term operation and thus promising for many practical applications.

15 W high OSNR kHz-linewidth linearly-polarized all-fiber single-frequency MOPA at 1.6 µm.

A 1603 nm high optical signal-to-noise ratio (OSNR) kHz-linewidth linearly-polarized all-fiber single-frequency master-oscillator power amplifier (MOPA) is demonstrated. To suppress the amplified spontaneous emission from Yb3+/Er3+ ions with the customized filters and optimize the length of the double cladding active fiber, an over 15 W stable single-longitudinal-mode laser is achieved with an OSNR of >70 dB. A measured laser linewidth of 4.5 kHz and a polarization-extinction ratio of >23 dB are obtained at the full output power. This L-band high-power single-frequency MOPA is promising for high-resolution molecular spectroscopy and pumping of Tm3+-doped or Tm3+/Ho3+ co-doped laser.

Near quantum-noise limited and absolute frequency stabilized 1083 nm single-frequency fiber laser.

The Earth's magnetic field has significant effects that protect us from cosmic radiation and provide navigation for biological migration. However, slow temporal variations originating in the liquid outer core invariably exist. To understand the working mechanism of the geomagnetic field and improve accuracy of navigation systems, a high-precision magnetometer is essential to measure the absolute magnetic field. A helium optically pumping magnetometer is an advanced approach, but its sensitivity and accuracy are directly limited by the low-frequency relative intensity noise and frequency stability characteristics of a light source. Here, we demonstrate a near quantum-noise limited and absolute frequency stabilized 1083 nm single-frequency fiber laser. The relative intensity noise is only 5 dB higher than the quantum-noise limit, and the root mean square of frequency fluctuation is ∼17 kHz after locked. This fiber laser could suppress the fluctuation of magnetic resonant frequency and improve the signal-to-noise ratio of the magnetic resonance signal detection.

High spatial resolution distributed fiber strain sensor based on phase-OFDR.

A novel method to realize high spatial resolution distributed strain measurement is proposed based on phase demodulation scheme of optical frequency domain reflectometry (OFDR). Strain information can be demodulated directly by analyzing the phase change of Rayleigh backscattered light. Strain location can be obtained with high spatial resolution by cross-correlation method using a wide scanning range of tunable laser source. Based on the above scheme, breakpoint detection with 0.1 mm spatial resolution has been demonstrated, static and dynamic strain up to 100 Hz could be distributedly measured with 10 cm spatial resolution over 200 m sensing fiber, and the minimum measurable strain is about 1 µÎµ.

kHz-order linewidth controllable 1550 nm single-frequency fiber laser for coherent optical communication.

A kHz-order linewidth controllable 1550 nm single-frequency fiber laser (SFFL) is demonstrated for the first time to our best knowledge. The control of the linewidth is realized by using a low-pass filtered white Gaussian noise (WGN) signal applied on a fiber stretcher in an optical feedback loop. Utilizing WGN signals with different signal amplitudes An and different cutoff frequencies fc, the linewidths are availably controlled in a wide range from 0.8 to 353 kHz. The obtained optical signal-to-noise ratio (OSNR) is more than 72.0 dB, and the relative intensity noise (RIN) at frequency greater than 40 MHz reaches -148.5 dB/Hz which approaches the shot noise limit (-152.9 dB/Hz). This kHz-order linewidth controllable SFFL is meaningful and valuable, for optimizing the receiver sensitivity and bit error rate (BER) performance of the coherent optical communication system based on high-order quadrature amplitude modulation (QAM).

Low-crosstalk orbital angular momentum fiber coupler design.

A fiber coupler for low-crosstalk orbital angular momentum mode beam splitter is proposed with the structure of two separate and parallel microfibers. By properly setting the center-to-center distance between microfibers, the crosstalk is less than -20 dB, which means that the purity of the needed OAM mode in output port is higher than 99%. For a fixed overlapping length, high coupling efficiency (>97%) is achieved in 1545-1560 nm. The operating wavelength is tuned to the whole C-band by using the thermosensitive liquid. So the designed coupler can achieve the tunable coupling ratio over the whole C-band, which is a prospective component for the further OAM fiber system.

High-power and near-shot-noise-limited intensity noise all-fiber single-frequency 1.5 µm MOPA laser.

An all-fiber high-power and broad-frequency-band near-shot-noise-limited kHz-linewidth (Δν ~1.7 kHz) single-frequency master-oscillator power amplifier (MOPA) laser at 1.5 µm is demonstrated. To significantly suppress the intensity noise of seed laser and mitigate the detrimental effects of amplified spontaneous emission and stimulated Brillouin scattering in fiber amplifiers, more than 23 W of a stable low noise single-frequency laser output is achieved with a relative intensity noise of < -150 dB/Hz @0.5 mW (near to the shot-noise limit: -152.9 dB/Hz) in the frequency band from 0.1 to 50 MHz. It is believed that the achieved laser performance of ultra-low intensity noise and high-power output make the laser source become a promising candidate in further applications, such as cold atom optical lattice, quantum key distribution, and gravitational wave detection.

Optical fiber design with orbital angular momentum light purity higher than 99.9.

The purity of the synthesized orbital-angular-momentum (OAM) light in the fiber is inversely proportional to channel crosstalk level in the OAM optical fiber communication system. Here the relationship between the fiber structure and the purity is firstly demonstrated in theory. The graded-index optical fiber is proposed and designed for the OAM light propagation with the purity higher than 99.9%. 16 fiber modes (10 OAM modes) have been supported by a specific designed graded-index optical fiber with dispersion less than 35 ps/(km∙nm). Such fiber design has suppressed the intrinsic crosstalk to be lower than -30 dB, and can be potentially used for the long distance OAM optical communication system.

Mechanism of solitary wave breaking phenomenon in dissipative soliton fiber lasers.

We numerically and experimentally investigate the pulse evolution to the edge of destabilization against pumping powers in a strongly dissipative-dispersive laser configuration mode locked by nonlinear polarization evolution (NPE) technique. Two distinct dynamic processes are indicated by numerical results and further evidenced by experimental observations, where one depicts the monotonous increase in peak power and slight narrowing of duration, the other is different in exhibiting obvious broadening in temporal domain. Correspondingly, it is demonstrated in the simulation of cavity dynamics that the artificial saturable absorber plays two opposite roles in pulse shaping, which implies the switch of cavity feedback. Mechanisms with respect to different cavity feedbacks are analyzed based on a newly-proposed theoretical viewpoint, for positive feedback single pulse operation is restricted by the limit of peak power mainly dependent of the gain bandwidth; for negative feedback the breakup is attributed to the limited strength of clamping effect determined by multiple ingredients.

All-optical frequency and intensity noise suppression of single-frequency fiber laser.

An all-optical frequency and intensity noise suppression technique of a single-frequency fiber laser is demonstrated. By exploiting the recursive noise reduction effect of a semiconductor optical amplifier (SOA) in a self-injection locked fiber laser, the frequency and intensity noise of the laser are remarkably suppressed in a significantly wide frequency range. In addition to the linewidth suppression from 3.5 kHz to 700 Hz, the frequency noise has been reduced by ∼25 dB. After suppression, the relative intensity noise (RIN) is within 5 dB of the shot noise limit at frequencies from 1.5 to 3 MHz, and the frequency range of the suppression reaches about 30 MHz. The relaxation oscillation peak is observed to shift to lower frequencies and is reduced by about 35 dB from -90 dB/Hz to -125 dB/Hz. It is believed that the achieved low noise makes the fiber laser a promising candidate in applications such as ultra-long haul coherent optical communication and LIDAR.

All-fiber mode-locked laser based on microfiber polarizer.

A novel all-fiber mode-locked fiber laser based on microfiber polarizer is proposed and demonstrated. The microfiber polarizer is composed of two pieces of microfibers that are finely manipulated to be partly overlapped. Because of the asymmetric cross section, the microfiber polarizer shows a strong birefringence that ultimately induces a high polarization-selective feature. Compared with other polarizers, the microfiber polarizer owns the merits of simpler fabrication, lower cost, broader band, and more compact size. The polarization extinction ratio of the microfiber polarizer is 26 dB, and the stable pulse sequence with the duration of 2.9 ps is generated from this microfiber polarizer based all-fiber mode-locked laser.

Slow/fast light using a very short Er3+/Yb3+ co-doped fiber.

A slow/fast light device with a sealed size of 130 mm×30 mm×3 mm has been demonstrated. Ultraslow propagation and superluminal propagation with group velocity values from 8.4 to -14.7 m/s are observed in a 3.86 cm long Er3+/Yb3+ co-doped single-mode phosphate glass fiber. The dependence of pump power, modulation frequency, and wavelength on the slow/fast light effect in this fiber is investigated in detail. These results suggest that this compact slow/fast device is more suitable for all-fiber applications than those made by traditional methods.