Green and Sustainable Manufacture of Ultrapure Engineered Nanomaterials.

Nanomaterials with very specific features (purity, colloidal stability, composition, size, shape, location…) are commonly requested by cutting-edge technologic applications, and hence a sustainable process for the mass-production of tunable/engineered nanomaterials would be desirable. Despite this, tuning nano-scale features when scaling-up the production of nanoparticles/nanomaterials has been considered the main technological barrier for the development of nanotechnology. Aimed at overcoming these challenging frontier, a new gas-phase reactor design providing a shorter residence time, and thus a faster quenching of nanoclusters growth, is proposed for the green, sustainable, versatile, cost-effective, and scalable manufacture of ultrapure engineered nanomaterials (ranging from nanoclusters and nanoalloys to engineered nanostructures) with a tunable degree of agglomeration, composition, size, shape, and location. This method enables: (1) more homogeneous, non-agglomerated ultrapure Au-Ag nanoalloys under 10 nm; (2) 3-nm non-agglomerated ultrapure Au nanoclusters with lower gas flow rates; (3) shape-controlled Ag NPs; and (4) stable Au and Ag engineered nanostructures: nanodisks, nanocrosses, and 3D nanopillars. In conclusion, this new approach paves the way for the green and sustainable mass-production of ultrapure engineered nanomaterials.

Supersymmetry in the time domain and its applications in optics.

Supersymmetry is a conjectured symmetry between bosons and fermions aiming at solving fundamental questions in string and quantum field theory. Its subsequent application to quantum mechanics led to a ground-breaking analysis and design machinery, later fruitfully extrapolated to photonics. In all cases, the algebraic transformations of quantum-mechanical supersymmetry were conceived in the space realm. Here, we demonstrate that Maxwell's equations, as well as the acoustic and elastic wave equations, also possess an underlying supersymmetry in the time domain. We explore the consequences of this property in the field of optics, obtaining a simple analytic relation between the scattering coefficients of numerous time-varying systems, and uncovering a wide class of reflectionless, three dimensional, all-dielectric, isotropic, omnidirectional, polarisation-independent, non-complex media. Temporal supersymmetry is also shown to arise in dispersive media supporting temporal bound states, which allows engineering their momentum spectra and dispersive properties. These unprecedented features may enable the creation of novel reconfigurable devices, including invisible materials, frequency shifters, isolators, and pulse-shape transformers.

High signal-to-noise ratio ultra-compact lab-on-a-chip microflow cytometer enabled by silicon optical antennas.

We experimentally demonstrate an all-silicon nanoantenna-based micro-optofluidic cytometer showing a combination of high signal-to-noise ratio (SNR) > 14 dB and ultra-compact size. Thanks to the ultra-high directivity of the antennas (>150), which enables a state-of-the-art sub-micron resolution, we are able to avoid the use of the bulky devices typically employed to collimate light on chip (such as lenses or fibers). The nm-scale antenna cross section allows a dramatic reduction of the optical system footprint, from the mm-scale of previous approaches to a few µm2, yielding a notable reduction in the fabrication costs. This scheme paves the way to ultra-compact lab-on-a-chip devices that may enable new applications with potential impact on all branches of biological and health science.

Ultra-short pulse propagation model for multi-core fibers based on local modes.

Multi-core fibers (MCFs) have sparked a new paradigm in optical communications and open new possibilities and applications in experimental physics and other fields of science, such as biological and medical imaging. In many of these cases, ultra-short pulse propagation is revealed as a key factor that enables us to exploit the full potential of this technology. Unfortunately, the propagation of such pulses in real MCFs has not yet been modelled considering polarization effects or typical random medium perturbations, which usually give rise to both longitudinal and temporal birefringent effects. Using the concept of local modes, we develop here an accurate ultra-short pulse propagation model that rigorously accounts for these phenomena in single-mode MCFs. Based on this theory, we demonstrate analytically and numerically the intermodal dispersion between different LP01 polarized core modes induced by these random perturbations when propagating femtosecond pulses in the linear and nonlinear fiber regimes. The ever-decreasing core-to-core distance significantly enhances the intermodal dispersion induced by these birefringent effects, which can become the major physical impairment in the single-mode regime. To demonstrate the power of our model, we give explicit strategies to reduce the impact of this optical impairment by increasing the MCF perturbations.

On-chip wireless silicon photonics: from reconfigurable interconnects to lab-on-chip devices.

Photonic integrated circuits are developing as key enabling components for high-performance computing and advanced network-on-chip, as well as other emerging technologies such as lab-on-chip sensors, with relevant applications in areas from medicine and biotechnology to aerospace. These demanding applications will require novel features, such as dynamically reconfigurable light pathways, obtained by properly harnessing on-chip optical radiation. In this paper, we introduce a broadband, high directivity (>150), low loss and reconfigurable silicon photonics nanoantenna that fully enables on-chip radiation control. We propose the use of these nanoantennas as versatile building blocks to develop wireless (unguided) silicon photonic devices, which considerably enhance the range of achievable integrated photonic functionalities. As examples of applications, we demonstrate 160 Gbit s-1 data transmission over mm-scale wireless interconnects, a compact low-crosstalk 12-port crossing and electrically reconfigurable pathways via optical beam steering. Moreover, the realization of a flow micro-cytometer for particle characterization demonstrates the smart system integration potential of our approach as lab-on-chip devices.

Birefringence effects in multi-core fiber: coupled local-mode theory.

In this paper, we evaluate experimentally and model theoretically the intra- and inter-core crosstalk between the polarized core modes in single-mode multi-core fiber media including temporal and longitudinal birefringent effects. Specifically, extensive experimental results on a four-core fiber indicate that the temporal fluctuation of fiber birefringence modifies the intra- and inter-core crosstalk behavior in both linear and nonlinear optical power regimes. To gain theoretical insight into the experimental results, we introduce an accurate multi-core fiber model based on local modes and perturbation theory, which is derived from the Maxwell equations including both longitudinal and temporal birefringent effects. Numerical calculations based on the developed theory are found to be in good agreement with the experimental data.

Magnetic hot spots in closely spaced thick gold nanorings.

Light-matter interaction at optical frequencies is mostly mediated by the electric component of the electromagnetic field, with the magnetic component usually being considered negligible. Recently, it has been shown that properly engineered metallic nanostructures can provide a magnetic response at optical frequencies originated from real or virtual flows of electric current in the structure. In this work, we demonstrate a magnetic plasmonic mode which emerges in closely spaced thick gold nanorings. The plasmonic resonance obtains a magnetic dipole character by sufficiently increasing the height of the nanorings. Numerical simulations show that a virtual current loop appears at resonance for sufficiently thick nanorings, resulting in a strong concentration of the magnetic field in the gap region (magnetic hot spot). We find that there is an optimum thickness that provides the maximum magnetic intensity enhancement (over 200-fold enhancement) and give an explanation of this observation. This strong magnetic resonance, observed both experimentally and theoretically, can be used to build new metamaterials and resonant loop nanoantennas at optical frequencies.

Dual-band double-negative-index fishnet metamaterial at millimeter-waves.

An effective negative refractive index (NRI) is demonstrated and experimentally verified for the first two propagation bands of a fishnet-like metamaterial at millimeter-wave frequencies. The dual-band NRI behavior is achieved by engineering the diffraction order (±1, ±1) associated with the internal mode supported between holey layers to correspond with the second propagation band. In addition to the experimental interferometric technique that accounts for the handedness of the propagation, numerical results are given to predict the dual-band effective NRI and to confirm dual-band negative refraction for a prism composed of the proposed metamaterial.

Engineering antenna radiation patterns via quasi-conformal mappings.

We use a combination of conformal and quasi-conformal mappings to engineer isotropic electromagnetic devices that modify the omnidirectional radiation pattern of a point source. For TE waves, the designed devices are also non-magnetic. The flexibility offered by the proposed method is much higher than that achieved with conformal mappings. As a result, it is shown that complex radiation patterns can be achieved, which can combine high directivity in a desired number of arbitrary directions and isotropic radiation in other specified angular ranges. In addition, this technique enables us to control the power radiated in each direction to a certain extent. The obtained results are valid for any part of the spectrum. The potential of this method is illustrated with some examples. Finally, we study the frequency dependence of the considered devices and propose a practical dielectric implementation.

Low-loss multilayered metamaterial exhibiting a negative index of refraction at visible wavelengths.

We experimentally demonstrate a low-loss multilayered metamaterial exhibiting a double-negative refractive index in the visible spectral range. To this end, we exploit a second-order magnetic resonance of the so-called fishnet structure. The low-loss nature of the employed magnetic resonance, together with the effect of the interacting adjacent layers, results in a figure of merit as high as 3.34. A wide spectral range of negative index is achieved, covering the wavelength region between 620 and 806 nm with only two different designs.