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Solution-based inorganic-organic halide perovskites are of great interest to researchers because of their unique optoelectronic properties and easy processing. However, polycrystalline perovskite films often show inhomogeneity due to residual strain induced during the film's post-processing phase. In turn, these strains can impact both their stability and performance. An exhaustive study of residual strains can provide a better understanding and control of how they affect the performance and stability of perovskite films. In this work, we explore this complex interrelationship between residual strains and electrical properties for methylammonium CH3NH3PbI3-xClx films using grazing incidence X-ray diffraction (GIXRD). We correlate their resistivity and carrier mobility using the Hall effect. The sin2(ψ) technique is used to optimize the annealing parameters for the perovskite films. We also establish that temperature-induced relaxation can yield a significant enhancement of the charge carrier transports in perovskite films. Finally, we also use Raman micro-spectroscopy to assess the degradation of perovskite films as a function of their residual strains.
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Emerging flexible optoelectronic devices require multi-material processing capabilities to fully enable the use of temperature-sensitive substrates and materials. This report demonstrates how photonic sintering enables the processing of materials with very different properties. For example, charge carrier transport/blocking metal-oxides, and transparent conductive silver nanowire-based electrodes ought to be compatible with low-energy and high-throughput processing for integration onto flexible low-temperature substrates. Compared to traditional post-processing methods, we show a rapid fabrication route yielding highly-stable hybrid electrode architectures on polyethylene terephthalate (PET). This architecture consists of an interconnected silver nanowire network encapsulated with a thin crystalline photo-sensitive titanium dioxide (TiO2) coating, allowing both layers to be treated using independent photonic post-processing sintering steps. The first step sinters the nanowires, while the second completes the conversion of the top metal-oxide layer from amorphous to crystalline TiO2. This approach improves on the fabrication speed compared to oven processing, while delivering optical and electrical characteristics comparable to the state of the art. Optimized transparency values reach 85% with haze values down-to 7% at 550 nm, while maintaining a sheet resistance of 18.1 Ω sq.-1. However, this hybrid architecture provides a much stronger resilience to degradation, which we demonstrate through exposure to harsh plasma conditions. In summary, this study shows how carefully-optimized photonic curing post-processing can provide more-stable hybrid architectures while using a multi-material processing technique suitable for high-volume manufacturing on low-temperature substrates.
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BACKGROUND: Accurate and portable respiratory parameter measurements are critical for properly managing chronic obstructive pulmonary diseases (COPDs) such as asthma or sleep apnea, as well as controlling ventilation for patients in intensive care units, during surgical procedures, or when using a positive airway pressure device for sleep apnea. OBJECTIVE: The purpose of this research is to develop a new nonprescription portable measurement device that utilizes relative humidity sensors (RHS) to accurately measure key respiratory parameters at a cost that is approximately 10 times less than the industry standard. METHODS: We present the development, implementation, and assessment of a wearable respiratory measurement device using the commercial Bosch BME280 RHS. In the initial stage, the RHS was connected to the pneumotach (PNT) gold standard device via its external connector to gather breathing metrics. Data collection was facilitated using the Arduino platform with a Bluetooth Low Energy connection, and all measurements were taken in real time without any additional data processing. The device's efficacy was tested with 7 participants (5 men and 2 women), all in good health. In the subsequent phase, we specifically focused on comparing breathing cycle and respiratory rate measurements and determining the tidal volume by calculating the region between inhalation and exhalation peaks. Each participant's data were recorded over a span of 15 minutes. After the experiment, detailed statistical analysis was conducted using ANOVA and Bland-Altman to examine the accuracy and efficiency of our wearable device compared with the traditional methods. RESULTS: The perfused air measured with the respiratory monitor enables clinicians to evaluate the absolute value of the tidal volume during ventilation of a patient. In contrast, directly connecting our RHS device to the surgical mask facilitates continuous lung volume monitoring. The results of the 1-way ANOVA showed high P values of .68 for respiratory volume and .89 for respiratory rate, which indicate that the group averages with the PNT standard are equivalent to those with our RHS platform, within the error margins of a typical instrument. Furthermore, analysis utilizing the Bland-Altman statistical method revealed a small bias of 0.03 with limits of agreement (LoAs) of -0.25 and 0.33. The RR bias was 0.018, and the LoAs were -1.89 and 1.89. CONCLUSIONS: Based on the encouraging results, we conclude that our proposed design can be a viable, low-cost wearable medical device for pulmonary parametric measurement to prevent and predict the progression of pulmonary diseases. We believe that this will encourage the research community to investigate the application of RHS for monitoring the pulmonary health of individuals.
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Emerging machine learning techniques can be applied to Raman spectroscopy measurements for the identification of minerals. In this project, we describe a deep learning-based solution for automatic identification of complex polymorph structures from their Raman signatures. We propose a new framework using Convolutional Neural Networks and Long Short-Term Memory networks for compound identification. We train and evaluate our model using the publicly-available RRUFF spectral database. For model validation purposes, we synthesized and identified different TiO2 polymorphs to evaluate the performance and accuracy of the proposed framework. TiO2 is a ubiquitous material playing a crucial role in many industrial applications. Its unique properties are currently used advantageously in several research and industrial fields including energy storage, surface modifications, optical elements, electrical insulation to microelectronic devices such as logic gates and memristors. The results show that our model correctly identifies pure Anatase and Rutile with a high degree of confidence. Moreover, it can also identify defect-rich Anatase and modified Rutile based on their modified Raman Spectra. The model can also correctly identify the key component, Anatase, from the P25 Degussa TiO2. Based on the initial results, we firmly believe that implementing this model for automatically detecting complex polymorph structures will significantly increase the throughput, while dramatically reducing costs.
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In the last decades, titania (or TiO2) particles played a crucial role in the development of photo-catalysis and better environmentally-friendly energy-harvesting techniques. In this work, we engineer a new generation of TiO2 particles rich in oxygen vacancies using a modified sol-gel synthesis. By design, these vacancy-rich particles efficiently absorb visible light to allow carefully-controlled light-induced conversion to the anatase or rutile crystalline phases. FTIR and micro-Raman spectroscopy reveal the formation of oxygen vacancies during conversion and explain this unique laser-assisted crystallization mechanism. We achieve low-energy laser-assisted crystallization in ambient environment using a modified filament 3D printer equipped with a low-power laser printhead. Since the established high-temperature treatment necessary to convert to crystalline TiO2 is ill-suited to additive manufacturing platforms, this work removes a major fundamental hurdle and opens whole new vistas of possibilities towards the additive manufacturing of ceramics, including carefully-engineered crystalline TiO2 substrates with potential applications for new and better photo-catalysis, fuel cells and energy-harvesting technologies.
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On the long road towards low-cost flexible hybrid electronics, integration and printable solar energy harvesting solutions, there is an urgent need for high-performance transparent conductive electrodes produced using manufacturing-ready techniques and equipment. In recent years, randomly-distributed metallic nanowire-based transparent mesh electrodes have proven highly-promising as they offer a superb compromise between high performances and low fabrication costs. Unfortunately, these high figure-of-merit transparent mesh electrodes usually rely heavily on extensive post-deposition processing. While conventional thermal annealing yields good performances, it is especially ill-suited for deposition on low-temperature substrates or for high-throughput manufacturing solutions. Similarly, laser-induced annealing severely limits the processing time for electrodes covering large surfaces. In this paper, we report the fabrication of ultra high-performance silver nanowires-based transparent conductive electrodes fabricated using optimized manufacturing-ready ultrafast photonic curing solutions. Using conventional indium tin oxide (ITO) as our benchmark for transparent electrodes, we demonstrate a 2.6-2.7 [Formula: see text] performance gain using two different figure-of-merit indicators. Based on these results, we believe this research provides an ideal manufacturing-ready approach for the large-scale and low-cost fabrication of ultra high-performance transparent electrodes for flexible hybrid electronics and solar-energy harvesting applications.
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Thermoelectric Bi2Te3 and Sb2Te3 thin films with high power factor were successfully obtained by pulsed laser deposition (PLD). Here, we demonstrate a well-controlled deposition of Bi2Te3/Sb2Te3 structures on glass substrates, through a shadow mask with micrometer-scale features. We establish an optimal growth temperature of 45 °C to attain compounds with suitable stoichiometric composition, as well as structural and electrical properties, to achieve high thermoelectric power factor. These films are produced without additional postannealing treatment or added gases. Indeed, crystalline films with Seebeck coefficients of 624 and -78 µV K-1 are obtained for Sb2Te3 and Bi2Te3, respectively. Microgenerators consisting of four pairs of n-type Bi2Te3 and p-type Sb2Te3 legs connected in series generate a maximum voltage of 50 mV and a power density of around 120 µW cm-2 for a temperature difference of 30 K across the hot and cold ends of the device. This low-temperature and simple PLD-deposited device represents an important step toward practical thermoelectric materials as well as efficient and compact microgenerators for low-temperature energy-harvesting applications.
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Organic-inorganic perovskites have already shown a tremendous potential for low-cost light-harvesting devices. Yet, the relatively low carrier mobilities in bulk perovskites still prevent large-area devices with performances competing with state-of-the-art technologies. Here, we tackle this fundamental challenge by incorporating single-wall carbon nanotubes within a perovskite matrix by means of a simple two-step method in ambient air. Using this nano-engineered hybrid film, we demonstrate large-area photodetectors with responsivities up-to 13.8 A.W-1 and a broad spectral response from 300 to 800 nm, indicating that photocurrent generation arises from the charge transfer from the perovskite matrix to the embedded nanotube network. As the nanotubes facilitate the carrier extraction, these photodetectors also show a fast response time of 10 ms. This is significantly faster than most of previous reports on perovskite-based photodetectors, including devices with much smaller photosensitive areas. This approach is also well-suited for large-scale production of other perovskite-based light-harvesting devices.
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The engineering of quantum dot solids with low defect concentrations and efficient carrier transport through a ligand strategy is crucial to achieve efficient quantum dot (QD) optoelectronic devices. Here, we study the consequences of various surface ligand treatments on the light emission properties of PbS quantum dot films using 1,3-benzenedithiol (1,3-BDT), 1,2-ethanedithiol (EDT), mercaptocarboxylic acids (MPA) and ammonium sulfide ((NH4)2S). We first investigate the influence of different ligand treatments on the inter-dot separation, which mainly determines the conductivity of the QD films. Then, through a combination of photoluminescence and transient photoluminescence characterization, we demonstrate that the radiative and non-radiative recombination mechanisms in the quantum dot films depend critically on the length and chemical structure of the surface ligands.