Efficient purification of aqueous solutions contaminated with sulfadiazine by coupling electro-Fenton/ultrasound process: optimization, DFT calculation, and innovative study of human health risk assessment.

In the current work, the hybrid process potential of ultrasound (US) and electro-Fenton (EF), named sono-electro-Fenton (SEF), was fully investigated for sulfadiazine (SDZ) degradation. The decontamination in the integration approach was revealed to be greater than in individual procedures, i.e., EF process (roughly 66%) and US process (roughly 15%). The key operating process factors (i.e., applied voltage, H2O2 content, pH, initial concentration of SDZ, and reaction time) affecting SDZ removal were evaluated and optimized using Box-Behnken Design (BBD). In addition, an adaptive neuro-fuzzy inference system (ANFIS) as an efficient predictive model was applied to forecast the decontamination efficiency of SDZ through the SEF process based on the same findings produced from BBD. The results revealed that the predictability of SDZ elimination by the ANFIS and BBD approaches exhibited an excellent agreement (a greater R2 of 0.99%) among the both models. Density functional theory was also employed to forecast the plausible decomposition elucidation by the bond-breaking mechanism of organic substances. Plus, the main side products of SDZ degradation during the SEF process were tracked. Eventually, the non-carcinogenic risk assessment of different samples of natural water containing SDZ that was treated by adopting US, EF, and SEF processes was examined for the first time. The findings indicated that the non-carcinogenic risk (HQ) values of all the purified water sources were computed in the permissible range.

Role of bio-electrochemical technology for enzyme activity stimulation in high-consumption pharmaceuticals biodegradation.

Active pharmaceutical ingredients (APIs) and their intermediate residues have recently been considered a serious concern. Among technologies, bio-electrochemical technologies (BETs) have stimulated the production of bio-electrical energy. This review aims to examine the benefit and mechanism of BETs on the degradation of high-consumption pharmaceutical compounds, including antibiotic, anti-inflammatory, and analgesic drugs, and the stimulation of enzymes induced in a bioreactor. Moreover, intermediates and the proposed pathways of pharmaceutical compound biodegradation in BETs are to be explained in this review. According to studies performed exclusively, the benefit of BETs is using bio-electroactive microbes to mineralize recalcitrant pharmaceutical contaminants by promoting enzyme activity and energy. Since BETs use the electron transfer chain between bio-anode/-cathode and pharmaceuticals, the enzyme activity is essential in the oxidation and reduction of phenolic rings of drugs and the ineffective detoxification of effluent from the treatment plant. This study is suggested a vital and influential role of BETs in mineralizing and enzyme induction in bioreactors. Eventually, a content of future developments or outlooks of BETs are propounded to improve the pharmaceutical industries' wastewater problems.

Statistical modeling optimization for antibiotics decomposition by ultrasound/electro-Fenton integrated process: Non-carcinogenic risk assessment of drinking water.

The present work proposes an ultrasound (US) assisted electro-Fenton (EF) process for eliminating penicillin G (PNG) and ciprofloxacin (CIP) from aqueous solutions and the process was further optimized by response surface methodology (RSM)- Box-Behnken design (BBD). The impact of pH, hydrogen peroxide (H2O2) concentration, applied voltage, initial pollutant concentration, and operating time were studied. The capability application of the electro-Fenton (EF) and US processes was compared separately and in combination under the optimum conditions of pH of 4, a voltage of 15 V, the initial antibiotic concentration of 20.7 mg/L, H2O2 concentration of 0.8 mg/L, and the operating time of 75 min. The removal efficiency of PNG and CIP using the sono-electro-Fenton (SEF) process, as the results revealed, was approximately 96% and 98%, respectively. The experiments on two scavengers demonstrated that ⦁OH contributes significantly to the CIP and PNG degradation by SEF, whereas ⦁O-2 corresponds to only a negligible amount. The total organic carbon (TOC) and chemical oxygen demand (COD) analyses were used to assess the mineralization of CIP and PNG. The efficiency of COD and TOC removal was reached at 73.25% and 62.5% for CIP under optimized operating circumstances, and at 61.52% and 72% for PNG, respectively. These findings indicate that a sufficient rate of mineralization was obtained by SEF treatment for the mentioned pollutants. The reaction kinetics of CIP and PNG degradation by the SEF process were found to follow a pseudo-first-order kinetic model. In addition, the human health risk assessment of natural water containing CIP and PNG that was purified by US, EF, and SEF processes was done for the first time. According to the findings, the non-carcinogenic risk (HQ) caused by drinking purified water by all three systems was calculated in the acceptable range. Thus, SEF is a proper system to remove various antibiotics in potable water and reduces their human health risks.

Electrocatalytic ozonation process supplemented by EDTA-Fe complex for improving the mature landfill leachate treatment.

The present study was to enhance catalytic ozonation process (COP) using ferric (Fe)- ethylenediaminetetraacetic acid (Fe-EDTA) integrated with an electrocoagulation (EC) process for landfill leachate pretreatment. For this purpose, the effect of operating parameters such as ozone and Fe-EDTA concentrations, current, initial pH, and reaction time were investigated. The findings revealed that the EC process and single ozonation process (SOP) could alone reduce chemical oxygen demand (COD) in landfill leachate by 23% and 39%; respectively. Moreover, integration of both processes at 100 mA current, 400 mg h-1 ozone concentration, and 3 h reaction time could significantly improve COD reduction to 70%. As well, current efficiency and ozone consumption in the proposed system could considerably develop compared with EC process and SOP. The integrated electro-catalytic SOP using Fe-EDTA could be operated at neutral pH value, which the COD removal efficiency was obtained 79.7%. Subsequently, biochemical oxygen demand (BOD5)/COD ratio of effluent increased to 0.64. Examining pseudo-first-order and pseudo-second-order kinetics, it was realized that constant rate in the system had augmented. These results also indicated that the modified process using Fe-EDTA was a promising landfill leachate pretreatment technique that could significantly enhance COD removal efficiency and BOD5/COD ratio, and ultimately decrease time and sludge production.

Efficient technologies for carwash wastewater treatment: a systematic review.

Carwash wastewater (CWW) is considered as an important source of either water pollution or water consumption. Therefore, its treatment is critical not only from the prevention of environmental contamination but also from the recycling of such high-volume water source. Unfortunately, the effective treatment of CWW is almost unknown, complex, and expensive. To overcome the former challenge, this study aimed to systematically review different technologies for CWW treatment. For this, a comprehensive literature survey was conducted and 48 research articles were found suitable to be included in the investigation. The included studies were of coagulation and adsorption (n = 5), membrane-based technologies (n = 15), and electrochemical (n = 11) and combined (n = 17) systems. This comprehensive review showed that the treatment methods of advanced filtration membrane techniques, electrical and chemical coagulation, and advanced oxidation processes can be effective in the removal of pollutants from carwash wastewater (CWW). The mining of different studies, however, showed that the combined methods are the most promising option in the remediation of such wastewater.

Electro-catalytic ozonation for improving the biodegradability of mature landfill leachate.

Landfill leachate contains complex, resistant, and diverse compounds that are considered as an environmental health problem. This study aims to investigate the efficacy of integrated homogeneous catalytic ozonation and electrochemical process for improving the biodegradability of landfill. This experimental study was conducted on real landfill leachate on the laboratory scale. The variables were current density (O3/H2O2-42.1 mA/cm2), ozone concentrations (100-400 mg/h), the initial pH (3-9), and the reaction times (1-6 h). The optimum operating condition was obtained at 1.42 mA/m2, 400 mg/h of ozone concentration, initial pH of 3, during 3 h. In the proposed integrated catalytic ozonation-electrochemical process, the chemical oxygen demand (COD) and biochemical oxygen demand (BOD) concentrations were removed to 3381.9 and 1521.8 mg/L, respectively. Under the optimum condition, the biodegradability index increased from 0.27 to 0.45. The results showed that the electro-catalytic ozonation process has a significant effect on the biodegradability index and could improve the removal efficiency of landfill leachate treatments.