A comprehensive review of viscoelastic polymer flooding in sandstone and carbonate rocks.

Polymer flooding is a proven chemical Enhanced Oil Recovery (cEOR) method that boosts oil production beyond waterflooding. Thorough theoretical and practical knowledge has been obtained for this technique through numerous experimental, simulation, and field works. According to the conventional belief, this technique improves macroscopic sweep efficiency due to high polymer viscosity by producing moveable oil that remains unswept after secondary recovery. However, recent studies show that in addition to viscosity, polymer viscoelasticity can be effectively utilized to increase oil recovery by mobilizing residual oil and improving microscopic displacement efficiency in addition to macroscopic sweep efficiency. The polymer flooding is frequently implemented in sandstones with limited application in carbonates. This limitation is associated with extreme reservoir conditions, such as high concentrations of monovalent and divalent ions in the formation brine and ultimate reservoir temperatures. Other complications include the high heterogeneity of tight carbonates and their mixed-to-oil wettability. To overcome the challenges related to severe reservoir conditions, novel polymers have been introduced. These new polymers have unique monomers protecting them from chemical and thermal degradations. Monomers, such as NVP (N-vinylpyrrolidone) and ATBS (2-acrylamido-2-methylpropane sulfonic acid), enhance the chemical resistance of polymers against hydrolysis, mitigating the risk of viscosity reduction or precipitation in challenging reservoir conditions. However, the viscoelasticity of these novel polymers and their corresponding impact on microscopic displacement efficiency are not well established and require further investigation in this area. In this study, we comprehensively review recent works on viscoelastic polymer flow under various reservoir conditions, including carbonates and sandstones. In addition, the paper defines various mechanisms underlying incremental oil recovery by viscoelastic polymers and extensively describes the means of controlling and improving their viscoelasticity. Furthermore, the polymer screening studies for harsh reservoir conditions are also included. Finally, the impact of viscoelastic synthetic polymers on oil mobilization, the difficulties faced during this cEOR process, and the list of field applications in carbonates and sandstones can also be found in our work. This paper may serve as a guide for commencing or performing laboratory- and field-scale projects related to viscoelastic polymer flooding.

Updated Perceptions on Polymer-Based Enhanced Oil Recovery toward High-Temperature High-Salinity Tolerance for Successful Field Applications in Carbonate Reservoirs.

The aging of the existing reservoirs makes the hydrocarbon extraction shift toward newer reserves, and harsh conditioned carbonates, which possess high temperature and high salinity (HTHS). Conventional polymer-flooding fails in these HTHS carbonates, due to precipitation, viscosity loss, and polymer adsorption. Therefore, to counteract these challenges, novel polymer-based cEOR alternatives employ optimized polymers, polymer-surfactant, and alkali-surfactant-polymer solutions along with hybrid methods, which have shown a potential to target the residual or remaining oils in carbonates. Consequently, we investigate novel polymers, viz., ATBS, Scleroglucan, NVP-based polymers, and hydrophobic associative polymers, along with bio-polymers. These selected polymers have shown low shear sensitivity, low adsorption, and robust thermal/salinity tolerance. Additionally, adding an alkali-surfactant to polymer solution produces a synergy effect of improved mobility control, wettability alteration, and interfacial-tension reduction. Thus, enhancing the displacement and sweep efficiencies. Moreover, low-salinity water can precondition high-salinity reservoirs before polymer flooding (hybrid method), to decrease polymer adsorption and viscosity loss. Thus, this paper is a reference for novel polymers, and their hybrid techniques, to improve polymer-based cEOR field applications under HTHS conditions in carbonates. Additionally, the recommendations can assist in project designs with reasonable costs and minimal environmental impact. The implication of this work will aid in supplementing the oil and gas energy sector growth, making a positive contribution to the Middle Eastern economy.

Interfacial Properties, Wettability Alteration and Emulsification Properties of an Organic Alkali-Surface Active Ionic Liquid System: Implications for Enhanced Oil Recovery.

Combinatory flooding techniques evolved over the years to mitigate various limitations associated with unitary flooding techniques and to enhance their performance as well. This study investigates the potential of a combination of 1-hexadecyl-3-methyl imidazolium bromide (C16mimBr) and monoethanolamine (ETA) as an alkali-surfactant (AS) formulation for enhanced oil recovery. The study is conducted comparative to a conventional combination of cetyltrimethylammonium bromide (CTAB) and sodium metaborate (NaBO2). The study confirmed that C16mimBr and CTAB have similar aggregation behaviors and surface activities. The ETA-C16mimBr system proved to be compatible with brine containing an appreciable concentration of divalent cations. Studies on interfacial properties showed that the ETA-C16mimBr system exhibited an improved IFT reduction capability better than the NaBO2-CTAB system, attaining an ultra-low IFT of 7.6 × 10-3 mN/m. The IFT reduction performance of the ETA-C16mimBr system was improved in the presence of salt, attaining an ultra-low IFT of 2.3 × 10-3 mN/m. The system also maintained an ultra-low IFT even in high salinity conditions of 15 wt% NaCl concentration. Synergism was evident for the ETA-C16mimBr system also in altering the carbonate rock surface, while the wetting power of CTAB was not improved by the addition of NaBO2. Both the ETA-C16mimBr and NaBO2-CTAB systems proved to form stable emulsions even at elevated temperatures. This study, therefore, reveals that a combination of surface-active ionic liquid and organic alkali has excellent potential in enhancing the oil recovery in carbonate reservoirs at high salinity, high-temperature conditions in carbonate formations.

Experimental Investigation and Performance Evaluation of Modified Viscoelastic Surfactant (VES) as a New Thickening Fracturing Fluid.

In hydraulic fracturing, fracturing fluids are used to create fractures in a hydrocarbon reservoir throughout transported proppant into the fractures. The application of many fields proves that conventional fracturing fluid has the disadvantages of residue(s), which causes serious clogging of the reservoir's formations and, thus, leads to reduce the permeability in these hydrocarbon reservoirs. The development of clean (and cost-effective) fracturing fluid is a main driver of the hydraulic fracturing process. Presently, viscoelastic surfactant (VES)-fluid is one of the most widely used fracturing fluids in the hydraulic fracturing development of unconventional reservoirs, due to its non-residue(s) characteristics. However, conventional single-chain VES-fluid has a low temperature and shear resistance. In this study, two modified VES-fluid are developed as new thickening fracturing fluids, which consist of more single-chain coupled by hydrotropes (i.e., ionic organic salts) through non-covalent interaction. This new development is achieved by the formulation of mixing long chain cationic surfactant cetyltrimethylammonium bromide (CTAB) with organic acids, which are citric acid (CA) and maleic acid (MA) at a molar ratio of (3:1) and (2:1), respectively. As an innovative approach CTAB and CA are combined to obtain a solution (i.e., CTAB-based VES-fluid) with optimal properties for fracturing and this behaviour of the CTAB-based VES-fluid is experimentally corroborated. A rheometer was used to evaluate the visco-elasticity and shear rate & temperature resistance, while sand-carrying suspension capability was investigated by measuring the settling velocity of the transported proppant in the fluid. Moreover, the gel breaking capability was investigated by determining the viscosity of broken VES-fluid after mixing with ethanol, and the degree of core damage (i.e., permeability performance) caused by VES-fluid was evaluated while using core-flooding test. The experimental results show that, at pH-value ( 6.17 ), 30 (mM) VES-fluid (i.e., CTAB-CA) possesses the highest visco-elasticity as the apparent viscosity at zero shear-rate reached nearly to 10 6 (mPa·s). Moreover, the apparent viscosity of the 30 (mM) CTAB-CA VES-fluid remains 60 (mPa·s) at (90 ∘ C) and 170 (s - 1 ) after shearing for 2-h, indicating that CTAB-CA fluid has excellent temperature and shear resistance. Furthermore, excellent sand suspension and gel breaking ability of 30 (mM) CTAB-CA VES-fluid at 90 ( ∘ C) was shown; as the sand suspension velocity is 1.67 (mm/s) and complete gel breaking was achieved within 2 h after mixing with the ethanol at the ratio of 10:1. The core flooding experiments indicate that the core damage rate caused by the CTAB-CA VES-fluid is ( 7.99 % ), which indicate that it does not cause much damage. Based on the experimental results, it is expected that CTAB-CA VES-fluid under high-temperature will make the proposed new VES-fluid an attractive thickening fracturing fluid.