RESUMO
Herein, adsorption of Rose Bengal dye (RB) from aqueous solution was investigated. Nano raw orange peel (OP) activated carbon (AC) coated with nano chitosan (Cs) to obtain nano chitosan/activated carbon (AC/Cs) composite which cross-linked with functionalized multi-walled carbon nanotubes (MWCNTs-COOH) to create a novel composite (AC/Cs/MWCNTs) with high surface area (1923 m2/g). The examined parameters such as concentration (1-7 ppm), pH (6.5-9.5) and temperature (295-323 K) were traversed. The maximum removal efficiency was at pH 6.5, increased from 70.4% for nano OP to 94.7% for AC/Cs/MWCNTs nano composite. Langmuir isotherm model was the best fitting to acquired data (R2 ≥ 0.99). Also, the adsorption of RB matched with pseudo-second order model, t0.5 results for pseudo-second order was 4.4672 for nano OP and 1.2813 for AC/Cs/MWCNTs at 303 K. Thermodynamic studies showed that the adsorption of RB dye is exothermic and spontaneous due to the negative value of ΔG and ΔH.
RESUMO
We treated surgically 12 patients with an old dislocation of the lower cervical spine. The time from injury to presentation averaged 3.5 (range 1.5-12) months, and the majority of the dislocations were between C4-5. Treatment started with 1 week of skull traction. If this resulted in reduction the area was stabilised by anterior fusion with plate fixation. If reduction by traction did not succeed a posterior partial facetectomy was performed. If this allowed reduction it was followed by a posterior fusion with plate fixation. If reduction was not achieved the traction was continued for a further week and then followed by anterior discectomy and fusion with plate fixation. The average follow-up was 34 (range 12-54) months, and all patients developed bone fusion and showed neurological improvement.