Remarkable Enhancement of Bismuth Nanosphere Catalyst Activity for the Conversion of Electrocatalytic CO2 to Formate by Bromine Doping.

Driven by renewable energy, using electrocatalysis to reduce carbon dioxide (CO2) to chemicals is a key technology. It could dim global carbon emissions and promote the carbon cycle. Here, we reported an approach to prepare a Br-doped Bi nanosphere (Br-doped Bi NSP) catalyst for the preparation of formate by electrochemical conversion of CO2. The synthesized Br-doped Bi NSP catalyst manifests high selectivity toward HCOOH. At the applied potential of -0.9 V versus reversible hydrogen electrode, it could achieve a maximum FEHCOOH of 98%. It can remain constant, and the degradation is negligible in continuous electrolysis for 9 h. The excellent CO2 reduction performance is due to the electron richness at the surface of Br-doped Bi NSP induced by the electron transfer between Bi and Br. Density functional theory calculations and in situ attenuated total reflectance-Fourier transform infrared measurements were used to predict the underlying catalyst action's pathway. It can be concluded that the introduction of Br is advantageous to the *OCHO formation, which is conducive to the reduction of the determination step. This research could provide a meaningful view into anion-doping effects to enable effiective electrocatalytic material that selectively reduces carbon dioxide into valuable products.

Prosthetic finger for fingertip tactile sensing via flexible chromatic optical waveguides.

Building prosthetics indistinguishable from human limbs to accurately receive and transmit sensory information to users not only promises to radically improve the lives of amputees, but also shows potential in a range of robotic applications. Currently, a mainstream approach is to embed electrical or optical sensors with force/thermal sensing functions on the surface or inside of prosthetic fingers. Compared with electrical sensing technologies, tactile sensors based on stretchable optical waveguides have the advantages of easy fabrication, chemical safety, environmental stability, and compatibility with prosthetic structural materials. However, so far, research has mainly focused on the perception of finger joint motion or external press, and there is still a lack of study on optical sensors with fingertip tactile capabilities (such as texture, hardness, slip detection, etc.). Here we report a 3D printing prosthetic finger with flexible chromatic optical waveguides implanted at the fingertip. The finger achieves distributed displacement/force sensing detection, and exhibits high sensitivity, fast response and good stability. The finger can be used to conduct active sensory experiments, and the detection parameters include object contour, hardness, slip direction and speed, temperature, etc. Finally, exploratory research on identifying and manipulating objects is carried out with this finger. The developed prosthetic finger can artificially recreate touch perception and realize complex functions such as note-writing analysis and braille recognition.

Effects of 2,6-di-tert-butyl-hydroxytotulene and mineral-lubricant base oils on microbial communities during lubricants biodegradation.

2,6-Di-tert-butyl-hydroxytotulene (BHT) is an additive commonly used in the manufacturing of lubricants to improve their antioxidant properties. However, in this study, we found that BHT affects the biodegradation of bio-lubricants by influencing the microbial community during the degradation of bio-lubricants. Specifically, BHT was found to reduce bacterial richness in activated sludge, but it increased the relative abundance of Actinobacteria (from 21.24% to 40.89%), Rhodococcus (from 17.15% to 31.25%), Dietzia (from 0.069% to 6.49%), and Aequorivita (from 0.90% to 1.85%). LEfSe analysis and co-occurrence network analysis suggested that Actinobacteria could be potential biomarkers and keystone taxa in microbial communities. Using the MetaCyc pathway database, the study found that BHT interfered with cellular biosynthetic processes. Additionally, the study also showed that mineral-lubricant base oils, which are difficult to degrade, significantly altered the diversity and composition of the microbiome. Overall, the findings demonstrate that BHT and mineral-lubricant base oils can substantially alter bacterial richness, structure, and function, potentially contributing to the difficulty in degrading lubricants. These findings have implications for the development of more biodegradable lubricants and the management of industrial waste containing lubricants.

Freeze-resistant, rapidly polymerizable, ionic conductive hydrogel induced by Deep Eutectic Solvent (DES) after lignocellulose pretreatment for flexible sensors.

In this paper, ternary DES (choline chloride, glycerol, Lewis acid) was used to pretreat lignocellulose, and the DES solution with dissolved lignin was utilized as the medium of hydrogel to prepare DES-based polyacrylic acid/polyvinyl alcohol (PAA/PVA) double network hydrogels with great mechanical properties, self-adhesion, and high electrochemical sensitivity. The entanglement of PAA with PVA chains, the covalent linkage between Al3+ and PAA chains and the metal phenol network (MPN) formed by Al3+ and lignin improved the mechanical properties of the hydrogels, enabling the prepared hydrogels to achieve a tensile strain of 400 % and an elongation at break of 150 kPa. Secondly, the introduction of DES solution endowed the hydrogel with excellent electrical sensing ability and anti-freezing property, so that the hydrogel still maintains good flexibility and ionic conductivity at -20 °C. It was also found that the above hydrogel can achieve a high gauge factor of 4.19 as a flexible sensor, which provides scientific ideas for the application of the pretreated DES solution in the field of flexible wearable.