Tracking Carbon and Ammonia Emission Flows of China's Nitrogen Fertilizer System: Implications for Domestic and International Trade.

China is the world's largest producer, consumer, and exporter of synthetic nitrogen (N) fertilizer. To assess the impact of domestic demand and international exports, we quantified the life-cycle CO2eq and ammonia (NH3) emissions by tracking carbon (C) and nitrogen (N) flows from coal/gas mining through ammonia production to N fertilizer production, application, and export. In 2020, China's N fertilizer system emitted 496.04 Tg of CO2eq and 3.74 Tg of NH3, with ammonia production and N fertilizer application processes contributing 36 and 85% of the life-cycle CO2eq and NH3 emissions, respectively. As the largest importers of N fertilizer, India, Myanmar, South Korea, Malaysia, and the Philippines collectively shifted 112.41 Tg of CO2eq. For every ton of N fertilizer produced and used in China, 16 t of CO2eq and 0.18 t of NH3 were emitted, compared to 9.7 t of CO2eq and 0.13 t of NH3 in Europe. By adopting currently available technologies, improving N fertilizer utilization efficiency and employing nitrification inhibitors could synergistically reduce CO2eq emissions by 20% and NH3 emissions by 75%, while energy transformation efforts would primarily reduce CO2eq emissions by 59%. The production of ammonia using green electricity or green hydrogen could significantly enhance the decarbonization of China's N fertilizer system.

Finite-Element Analysis of Noise Preceding the Arrival of S-Wave in Ultrasonic Measurements of Rock Velocities.

For oil and gas seismic exploration, rock velocities are essential parameters to tease out reservoir properties from seismic data. The ultrasonic pulse transmission (UPT) method has been a gold standard to estimate reservoir rock velocities in the laboratory. Regarding the UPT method, accurate determination of the travel time of waves plays a significant role in robustly measuring rock velocities. One of the most conventional ways to obtain the travel time is through the arrival picking. However, unclear noise virtually exists preceding the arrival of S-wave interfering with this arrival picking, which, sometimes, can cause enormous errors to measured S-wave velocity. Herein, we develop a 2-D, three-component (2D-3C) finite-element modeling (FEM) algorithm aiming to interpret the noise by combining with UPT measurements. The proposed 2D-3C FEM not only can efficiently compute ultrasonic wavefield radiated by circular P- or S-wave transducers but also able to obtain synthetic waveforms in the testing of S-wave velocity where polarization directions of S-wave transducers are arranged as nonparallel. To analyze the simulated ultrasonic waveforms, we introduce frequently-used concepts of edge and direct plane waves to build elastodynamic models of the ultrasonic wavefield. Then, we compare numerical results with experimental measurements. Our 2D-3C FEM results show good agreement with experimental waveforms both in P- and S-wave velocity testings. Whereafter, we pinpoint constitutions of the noise preceding the arrival of S-wave. Comparison of numerical and experimental waveforms suggests that the edge P-wave with its reflected and converted modes partially contributes to this noise, while the rest part of the noise may stem from the effects of the compressional dipole, the couplant smeared between a transducer and a sample, and inherently parasitic longitudinal vibrations of S-wave transducers. The interpretations on this noise have the potential to benefit future design of more effective S-wave transducers.

Switchable PDT for reducing skin photosensitization by a NIR dye inducing self-assembled and photo-disassembled nanoparticles.

Photodynamic therapy (PDT) is the combination of light and photosensitizer (PS) to kill tumor cells, which has the potential to meet many currently unmet medical needs. However, the whole body distribution and activatability by sunlight of photosensitizers to induce skin photosensitivity have limited the extensive clinic application of PDT. Herein, a novel strategy is presented to overcome these limitations by using a hydrophobic Near-infared (NIR) dye IR-780 iodide (IR780) to induce the self-assembly of albumin-PS conjugates, as a switchable PDT (Switch-PDT) agent. The PDT effect of PS is effectively inhibited by IR780 and recovered by NIR light irradiation in vitro. This quench/recovery strategy dose not sacrifice the anti-tumor ability in vivo, and the combined PDT and PTT (photothermal) effect contributes a very effective tumor inhibition rate of 100%. More importantly, the PDT effect is significantly suppressed after intravenous administration in mice or subcutaneous administration in rabbits as exhibited by the negligible skin response, while traditional PDT agent arouses severe skin erythema and edema. To the best of our knowledge, the switchable PDT is the first time to be used to eradicate the skin photosensitization of PS in vivo.