1.
Org Lett
; 24(31): 5726-5730, 2022 Aug 12.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35920748
RESUMO
A visible-light-induced four-component reaction of vinylcyclopropanes, N-(acyloxy)phthalimide esters, N,N-dimethylformamide (DMF), and H2O through an oxidative ring opening of cyclopropane is presented. This procedure provides a new and effective way to construct formate esters. DMF is employed as both a solvent and the source of CHO. This difunctionalization of vinylcyclopropanes shows good functional group tolerance under room temperature. A radical pathway is involved, and carbonyl oxygen of ester originated from water in this transformation.
2.
Org Biomol Chem
; 9(21): 7313-7, 2011 Nov 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21922096