A sensitive sensor based on MOFs derived nanoporous carbons for electrochemical detection of 4-aminophenol.

A novel electrochemical sensor based on zinc oxide/nitrogen doped porous carbons (ZnO/NPC) modified electrode has been constructed for detecting 4-aminophenol (4-AP). The ZnO/NPC material was synthesized by one-step carbonization of MOF-5-NH2. The modified glassy carbon electrode (ZnO/NPC/GCE) holds excellent electrocatalytic activity toward 4-AP, with a sensitivity of about 31.02 µA/µM/cm2. Under optimal conditions, its oxidation peak current increases linearly with the increasing concentration of 4-AP (from 5 to 120 µmol/L), and the detection limits is 0.014 µmol/L (S/N = 3). Furthermore, favorable selectivity, superior reproducibility and outstanding stability have been achieved. The ZnO/NPC/GCE has been applied in detecting 4-AP in industrial waste water and achieved positive results with the recovery of 4-AP ranging from 94.02% to 107.7%, which confirms that this sensor is a reliable platform for the detection of 4-AP in waste water.

Self-assembled Ti3C2 /MWCNTs nanocomposites modified glassy carbon electrode for electrochemical simultaneous detection of hydroquinone and catechol.

A versatile electrochemical sensor based on titanium carbide (Ti3C2) and multi-walled carbon nanotubes (MWCNTs) nanocomposite was constructed to detection catechol (CT) and hydroquinone (HQ). To prepare this novel nanocomposite, a self-assembled process was conducted by blending two-dimensional (2D) hierarchical Ti3C2 and MWCNTs under ultrasonic-assisted. X-ray diffraction (XRD), High resolution transmission electron microscopy (HR-TEM) and Scanning electron microscopy (SEM) methods as well as electrochemical technique, such as Electrochemical impedance spectroscopy (EIS), Cyclic voltammetry (CV) and Differential pulse voltammetry (DPV) were performed to characterize the Ti3C2-MWCNTs nanocomposite and illuminate the electrochemical oxidation process. Under the optimum conditions, wide linear range from 2 µM to 150 µM for both HQ and CT and low detection limit of 6.6 nM for HQ and 3.9 nM (S/N = 3) for CT have been achieved. Impressively, the sensor possesses superior selectivity, ultra-stability, and good repeatability, which was successfully applied for detecting CT and HQ in real industrial waste water sample with recovery of 96.9%-104.7% and 93.1%-109.9% for HQ and CT, respectively. Hence, Ti3C2 nanosheeets were proved to be a promising platform to construct electrochemical oxidation sensor in environmental analyses and phenolic isomers detection.

Simultaneous voltammetric determination of hydroquinone and catechol by using a glassy carbon electrode modified with a ternary nanocomposite prepared from oxidized multiwalled carbon nanotubes, manganese dioxide and manganese ferrite.

An electrochemical sensor is described for simultaneous determination of hydroquinone (HQ) and catechol (CT) via differential pulse voltammetry (DPV). It is making use of a ternary composite material prepared from oxidized multiwalled carbon nanotubes, manganese dioxide (MnO2) and manganese ferrite (MnFe2O4). The material was obtained by a one-step hydrothermal reaction and used to modify a glassy carbon electrode (GCE). The composite was characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, thermogravimetric analysis, X-ray photoelectron spectroscopy and scanning electron microscopy. The peak currents for HQ and CT are highest at 172 and 276 mV (vs. Ag/AgCl) at a pH value of 6.0. Response increases linearly in the 1-400 µM HQ and CT concentration ranges, and the detection limits are 0.64 and 0.48 µM, respectively. The modified GCE is highly selective, repeatable and reproducible. A single sensor was used to make 23 subsequent measurements, and the relative standard deviations were 1.8% and 2.3% for HQ and CT, respectively. Graphical abstract Schematic representation of the preparation of ternary nanocomposite and its electrochemical behavior towards hydroquinone and catechol.